Development of high-performance Na/NiCl/sub 2/ cell
The performance of the Ni/NiCl/sub 2/ positive electrode for the Na/NiCl/sub 2/ battery has been significantly improved by lowering the impedance and increasing the usable capacity through the use of chemical additives and a tailored electrode morphology. The improved electrode has excellent perform...
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Published in | IEEE 35th International Power Sources Symposium pp. 343 - 345 |
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Main Authors | , , , |
Format | Conference Proceeding |
Language | English |
Published |
IEEE
1992
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Subjects | |
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Abstract | The performance of the Ni/NiCl/sub 2/ positive electrode for the Na/NiCl/sub 2/ battery has been significantly improved by lowering the impedance and increasing the usable capacity through the use of chemical additives and a tailored electrode morphology. The improved electrode has excellent performance even below 200 degrees C and can be recharged within one hour. The performance of this new electrode was measured by a conventional galvanostatic method and by a newly developed power dynamic method. These measurements were used to project the performance of 40- to 60-kWh batteries built with this new electrode combined with the already highly developed sodium/ beta "-alumina negative electrode. These calculated results yielded a specific power of 150-400 W/kg and a specific energy of 110-200 Wh/kg for batteries with single-tube and bipolar cell designs. This high performance, along with the high cell voltage, mid-temperature operation, fast recharge capability, and short-circuited failure mode of the electrode couple, makes the Na/NiCl/sub 2/ battery attractive for electric vehicle applications.< > |
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AbstractList | The performance of the Ni/NiCl/sub 2/ positive electrode for the Na/NiCl/sub 2/ battery has been significantly improved by lowering the impedance and increasing the usable capacity through the use of chemical additives and a tailored electrode morphology. The improved electrode has excellent performance even below 200 degrees C and can be recharged within one hour. The performance of this new electrode was measured by a conventional galvanostatic method and by a newly developed power dynamic method. These measurements were used to project the performance of 40- to 60-kWh batteries built with this new electrode combined with the already highly developed sodium/ beta "-alumina negative electrode. These calculated results yielded a specific power of 150-400 W/kg and a specific energy of 110-200 Wh/kg for batteries with single-tube and bipolar cell designs. This high performance, along with the high cell voltage, mid-temperature operation, fast recharge capability, and short-circuited failure mode of the electrode couple, makes the Na/NiCl/sub 2/ battery attractive for electric vehicle applications.< > |
Author | Vissers, D.R. Redey, L. Myles, K.M. Prakash, J. |
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Snippet | The performance of the Ni/NiCl/sub 2/ positive electrode for the Na/NiCl/sub 2/ battery has been significantly improved by lowering the impedance and... |
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StartPage | 343 |
SubjectTerms | Battery charge measurement Current density Current measurement Density measurement Electrodes Impedance Nickel Power measurement Temperature Vehicle dynamics |
Title | Development of high-performance Na/NiCl/sub 2/ cell |
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