Tailor-made Polymeric Membranes based on Segmented Block Copolymers for CO2 Separation
This paper reports the design of a tailor made polymeric membrane by using poly(ethylene oxide)–poly(butylene terephthalate) (PEO‐PBT) multi‐block copolymers. Their properties are controlled by the fraction of the PEO phase and its molecular weight. To explain the effect of structural changes in cop...
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| Published in | Advanced functional materials Vol. 18; no. 18; pp. 2815 - 2823 |
|---|---|
| Main Authors | , , , |
| Format | Journal Article |
| Language | English |
| Published |
Weinheim
WILEY-VCH Verlag
23.09.2008
WILEY‐VCH Verlag |
| Subjects | |
| Online Access | Get full text |
| ISSN | 1616-301X 1616-3028 |
| DOI | 10.1002/adfm.200800436 |
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| Abstract | This paper reports the design of a tailor made polymeric membrane by using poly(ethylene oxide)–poly(butylene terephthalate) (PEO‐PBT) multi‐block copolymers. Their properties are controlled by the fraction of the PEO phase and its molecular weight. To explain the effect of structural changes in copolymer membranes, transport properties of four gases (CO2, H2, N2, and CH4) are discussed. After characterization, the two best copolymers are selected in order to prepare tailor made blends by adding poly(ethylene glycol) (PEG). The best selected copolymer that contained 55 wt. % of 4000 g mol−1 PEO produced a blend with high CO2 permeability (∼190 barrer), which is twice the permeability of the pure copolymer. At the same time, an enhancement of CO2/H2 selectivity is observed (∼13). These results suggest that the morphology of PEO‐PBT can be well controlled by the addition of low‐molecular‐weight PEG, and consequently the gas transport properties can be tuned.
Different PEO‐PBT multiblock copolymers are used to prepare carbon dioxide selective membranes. The carbon dioxide permeability runs through a maximum when plotted versus the molecular weight of the PEO block. |
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| AbstractList | This paper reports the design of a tailor made polymeric membrane by using poly(ethylene oxide)–poly(butylene terephthalate) (PEO‐PBT) multi‐block copolymers. Their properties are controlled by the fraction of the PEO phase and its molecular weight. To explain the effect of structural changes in copolymer membranes, transport properties of four gases (CO2, H2, N2, and CH4) are discussed. After characterization, the two best copolymers are selected in order to prepare tailor made blends by adding poly(ethylene glycol) (PEG). The best selected copolymer that contained 55 wt. % of 4000 g mol−1 PEO produced a blend with high CO2 permeability (∼190 barrer), which is twice the permeability of the pure copolymer. At the same time, an enhancement of CO2/H2 selectivity is observed (∼13). These results suggest that the morphology of PEO‐PBT can be well controlled by the addition of low‐molecular‐weight PEG, and consequently the gas transport properties can be tuned.
Different PEO‐PBT multiblock copolymers are used to prepare carbon dioxide selective membranes. The carbon dioxide permeability runs through a maximum when plotted versus the molecular weight of the PEO block. This paper reports the design of a tailor made polymeric membrane by using poly(ethylene oxide)-poly(butylene terephthalate) (PEO-PBT) multi-block copolymers. Their properties are controlled by the fraction of the PEO phase and its molecular weight. To explain the effect of structural changes in copolymer membranes, transport properties of four gases (CO2, H2, N2, and CH4) are discussed. After characterization, the two best copolymers are selected in order to prepare tailor made blends by adding poly(ethylene glycol) (PEG). The best selected copolymer that contained 55wt. % of 4000g mol-1 PEO produced a blend with high CO2 permeability (190 barrer), which is twice the permeability of the pure copolymer. At the same time, an enhancement of CO2/H2 selectivity is observed (13). These results suggest that the morphology of PEO-PBT can be well controlled by the addition of low-molecular-weight PEG, and consequently the gas transport properties can be tuned. |
| Author | Stropnik, Chrtomir Yave, Wilfredo Car, Anja Peinemann, Klaus-Viktor |
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| Copyright | Copyright © 2008 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim |
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| Notes | DAAD (Deutscher Akademischer Austauschdienst) Ministry of Higher Education, Science and Technology, Slovenia ark:/67375/WNG-WNMQL520-6 istex:B0A32FA31CB142A0FDAFFAE566D57FFEA0C1E7E1 The authors thank Dr. Jeroen Pieper for providing polymers (IsoTis OrthoBiologics, USA) and S. Nowak for DSC measurements. A. Car thanks the Ministry of Higher Education, Science and Technology, Slovenia and the DAAD (Deutscher Akademischer Austauschdienst) for financial support. Part of the work was supported by the Helmholtz-Alliance MemBrain (Gas Separation Membranes for Zero-Emission Fossil Power Plants). ArticleID:ADFM200800436 The authors thank Dr. Jeroen Pieper for providing polymers (IsoTis OrthoBiologics, USA) and S. Nowak for DSC measurements. A. Car thanks the Ministry of Higher Education, Science and Technology, Slovenia and the DAAD (Deutscher Akademischer Austauschdienst) for financial support. Part of the work was supported by the Helmholtz‐Alliance MemBrain (Gas Separation Membranes for Zero‐Emission Fossil Power Plants). ObjectType-Article-2 SourceType-Scholarly Journals-1 ObjectType-Feature-1 content type line 23 |
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| Snippet | This paper reports the design of a tailor made polymeric membrane by using poly(ethylene oxide)–poly(butylene terephthalate) (PEO‐PBT) multi‐block copolymers.... This paper reports the design of a tailor made polymeric membrane by using poly(ethylene oxide)-poly(butylene terephthalate) (PEO-PBT) multi-block copolymers.... |
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| SubjectTerms | block copolymers gas separation membranes: polymer permeability |
| Title | Tailor-made Polymeric Membranes based on Segmented Block Copolymers for CO2 Separation |
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