Separation of Enantiomers and CD Spectra of Au40(SCH2CH2Ph)24: Spectroscopic Evidence for Intrinsic Chirality
Chirality unveiled: Thiolate‐protected Au40(SR)24 clusters were enantioenriched using an HPLC approach. CD spectra show strong mirror‐image responses, indicating the intrinsic chirality of a cluster of unknown structure protected with achiral ligands.
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| Published in | Angewandte Chemie International Edition Vol. 51; no. 30; pp. 7589 - 7591 |
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| Main Authors | , , , |
| Format | Journal Article |
| Language | English |
| Published |
Weinheim
WILEY-VCH Verlag
23.07.2012
WILEY‐VCH Verlag Wiley Subscription Services, Inc |
| Edition | International ed. in English |
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| Abstract | Chirality unveiled: Thiolate‐protected Au40(SR)24 clusters were enantioenriched using an HPLC approach. CD spectra show strong mirror‐image responses, indicating the intrinsic chirality of a cluster of unknown structure protected with achiral ligands. |
|---|---|
| AbstractList | Chirality unveiled: Thiolate‐protected Au40(SR)24 clusters were enantioenriched using an HPLC approach. CD spectra show strong mirror‐image responses, indicating the intrinsic chirality of a cluster of unknown structure protected with achiral ligands. |
| Author | Knoppe, Stefan Bürgi, Thomas Dolamic, Igor Dass, Amala |
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| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/22707380$$D View this record in MEDLINE/PubMed |
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| Copyright | Copyright © 2012 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim |
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| DOI | 10.1002/anie.201202369 |
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| Notes | ark:/67375/WNG-CS7HN78V-6 Swiss National Foundation We thank Stefan Matile (University of Geneva) for providing the CD spectrometer. Financial support from the Swiss National Foundation is gratefully acknowledged. ArticleID:ANIE201202369 istex:11141A6E12C66EE974826F25A2177D2DED96E5DE ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 14 content type line 23 |
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| References | C. Gautier, R. Taras, S. Gladiali, T. Bürgi, Chirality 2008, 20, 486-493 S. Si, C. Gautier, J. Boudon, R. Taras, S. Gladiali, T. Bürgi, J. Phys. Chem. C 2009, 113, 12966-12969 M. Walter, J. Akola, O. Lopez-Acevedo, P. D. Jadzinsky, G. Calero, C. J. Ackerson, R. L. Whetten, H. Gronbeck, H. Hakkinen, Proc. Natl. Acad. Sci. USA 2008, 105, 9157-9162. T. G. Schaaff, G. Knight, M. N. Shafigullin, R. F. Borkman, R. L. Whetten, J. Phys. Chem. B 1998, 102, 10643-10646 R. B. Wyrwas, M. M. Alvarez, J. T. Khoury, R. C. Price, T. G. Schaaff, R. L. Whetten, Eur. Phys. J. D 2007, 43, 91-95. A. G. Mark, M. Forster, R. Raval, ChemPhysChem 2011, 12, 1474-1480 T. G. Schaaff, R. L. Whetten, J. Phys. Chem. B 2000, 104, 2630-2641. H. Qian, Y. Zhu, R. Jin, J. Am. Chem. Soc. 2010, 132, 4583-4585 O. Voznyy, J. J. Dubowski, J. T. Yates, P. Maksymovych, J. Am. Chem. Soc. 2009, 131, 12989-12993 C. Gautier, T. Bürgi, ChemPhysChem 2009, 10, 483-492. M. Zhu, W. T. Eckenhoff, T. Pintauer, R. Jin, J. Phys. Chem. C 2008, 112, 14221-14224. M. W. Heaven, A. Dass, P. S. White, K. M. Holt, R. W. Murray, J. Am. Chem. Soc. 2008, 130, 3754-3755 S. Sengupta, X. Shi, ChemCatChem 2010, 2, 609-619 S. Knoppe, N. Kothalawala, V. R. Jupally, A. Dass, T. Bürgi, Chem. Commun. 2012, 48, 4630-4632. S. M. Barlow, R. Raval, Surf. Sci. Rep. 2003, 50, 201-341 H. Yao, K. Miki, N. Nishida, A. Sasaki, K. Kimura, J. Am. Chem. Soc. 2005, 127, 15536-15543 O. Lopez-Acevedo, J. Akola, R. L. Whetten, H. Gronbeck, H. Hakkinen, J. Phys. Chem. C 2009, 113, 5035-5038. P. D. Jadzinsky, G. Calero, C. J. Ackerson, D. A. Bushnell, R. D. Kornberg, Science 2007, 318, 430-433 I. L. Garzón, M. R. Beltrán, G. González, I. Gutíerrez-González, K. Michaelian, J. A. Reyes-Nava, J. I. Rodríguez-Hernández, Eur. Phys. J. D 2003, 24, 105-109. I. L. Garzón, J. A. Reyes-Nava, J. I. Rodríguez-Hernández, I. Sigal, M. R. Beltrán, K. Michaelian, Phys. Rev. B 2002, 66, 073403 A. Kuzyk, R. Schreiber, Z. Fan, G. Pardatscher, E.-M. Roller, A. Hogele, F. C. Simmel, A. O. Govorov, T. Liedl, Nature 2012, 483, 311-314. C. F. McFadden, P. S. Cremer, A. J. Gellman, Langmuir, 1996, 12, 2483-2487. K. T. Wan, M. E. Davis, Nature 1994, 370, 449-450 H. Yao, T. Fukui, K. Kimura, J. Phys. Chem. C 2007, 111, 14968-14976 R. L. Whetten, R. C. Price, Science 2007, 318, 407-408. A. Dass, A. Stevenson, G. R. Dubay, J. B. Tracy, R. W. Murray, J. Am. Chem. Soc. 2008, 130, 5940-5946. Y. Zhu, Z. Wu, C. Gayathri, H. Qian, R. R. Gil, R. Jin, J. Catal. 2010, 271, 155-160. S. Knoppe, J. Boudon, I. Dolamic, A. Dass, T. Bürgi, Anal. Chem. 2011, 83, 5056-5061. C. Gautier, T. Bürgi, J. Am. Chem. Soc. 2006, 128, 11079-11087 S. Knoppe, A. C. Dharmaratne, E. Schreiner, A. Dass, T. Bürgi, J Am Chem. Soc 2010, 132, 16783-16789 M. Zhu, H. Qian, X. Meng, S. Jin, Z. Wu, R. Jin, Nano Lett. 2011, 11, 3963-3969. H. Qian, W. T. Eckenhoff, Y. Zhu, T. Pintauer, R. Jin, J. Am. Chem. Soc. 2010, 132, 8280-8281. O. Lopez-Acevedo, H. Tsunoyama, T. Tsukuda, H. Hakkinen, C. M. Aikens, J. Am. Chem. Soc. 2010, 132, 8210-8218. C. Gautier, T. Bürgi, Chem. Commun. 2005, 5393-5395 I. Dolamic, S. Knoppe, A. Dass, T. Bürgi, Nat. Commun. 2012, 3, 798. 2012; 483 2009 1996; 131 12 1994; 370 2011; 83 2011; 11 2009; 113 2005 2008; 105 2011; 12 2003; 50 2012; 3 2009; 10 2000; 104 2007; 111 2005; 127 2002; 66 2010; 132 2003; 24 2010; 271 2008; 20 2012; 48 2008; 112 2010; 2 2007; 43 1998; 102 2007; 318 2006; 128 2008; 130 |
| References_xml | – reference: A. G. Mark, M. Forster, R. Raval, ChemPhysChem 2011, 12, 1474-1480; – reference: C. Gautier, R. Taras, S. Gladiali, T. Bürgi, Chirality 2008, 20, 486-493; – reference: I. L. Garzón, J. A. Reyes-Nava, J. I. Rodríguez-Hernández, I. Sigal, M. R. Beltrán, K. Michaelian, Phys. Rev. B 2002, 66, 073403; – reference: S. M. Barlow, R. Raval, Surf. Sci. Rep. 2003, 50, 201-341; – reference: A. Dass, A. Stevenson, G. R. Dubay, J. B. Tracy, R. W. Murray, J. Am. Chem. Soc. 2008, 130, 5940-5946. – reference: Y. Zhu, Z. Wu, C. Gayathri, H. Qian, R. R. Gil, R. Jin, J. Catal. 2010, 271, 155-160. – reference: T. G. Schaaff, R. L. Whetten, J. Phys. Chem. B 2000, 104, 2630-2641. – reference: S. Sengupta, X. Shi, ChemCatChem 2010, 2, 609-619; – reference: R. B. Wyrwas, M. M. Alvarez, J. T. Khoury, R. C. Price, T. G. Schaaff, R. L. Whetten, Eur. Phys. J. D 2007, 43, 91-95. – reference: I. Dolamic, S. Knoppe, A. Dass, T. Bürgi, Nat. Commun. 2012, 3, 798. – reference: T. G. Schaaff, G. Knight, M. N. Shafigullin, R. F. Borkman, R. L. Whetten, J. Phys. Chem. B 1998, 102, 10643-10646; – reference: O. Lopez-Acevedo, J. Akola, R. L. Whetten, H. Gronbeck, H. Hakkinen, J. Phys. Chem. C 2009, 113, 5035-5038. – reference: C. Gautier, T. Bürgi, J. Am. Chem. Soc. 2006, 128, 11079-11087; – reference: H. Yao, K. Miki, N. Nishida, A. Sasaki, K. Kimura, J. Am. Chem. Soc. 2005, 127, 15536-15543; – reference: C. F. McFadden, P. S. Cremer, A. J. Gellman, Langmuir, 1996, 12, 2483-2487. – reference: C. Gautier, T. Bürgi, ChemPhysChem 2009, 10, 483-492. – reference: S. Knoppe, J. Boudon, I. Dolamic, A. Dass, T. Bürgi, Anal. Chem. 2011, 83, 5056-5061. – reference: C. Gautier, T. Bürgi, Chem. Commun. 2005, 5393-5395; – reference: M. Zhu, H. Qian, X. Meng, S. Jin, Z. Wu, R. Jin, Nano Lett. 2011, 11, 3963-3969. – reference: M. Walter, J. Akola, O. Lopez-Acevedo, P. D. Jadzinsky, G. Calero, C. J. Ackerson, R. L. Whetten, H. Gronbeck, H. Hakkinen, Proc. Natl. Acad. Sci. USA 2008, 105, 9157-9162. – reference: S. Si, C. Gautier, J. Boudon, R. Taras, S. Gladiali, T. Bürgi, J. Phys. Chem. C 2009, 113, 12966-12969; – reference: M. Zhu, W. T. Eckenhoff, T. Pintauer, R. Jin, J. Phys. Chem. C 2008, 112, 14221-14224. – reference: A. Kuzyk, R. Schreiber, Z. Fan, G. Pardatscher, E.-M. Roller, A. Hogele, F. C. Simmel, A. O. Govorov, T. Liedl, Nature 2012, 483, 311-314. – reference: S. Knoppe, N. Kothalawala, V. R. Jupally, A. Dass, T. Bürgi, Chem. Commun. 2012, 48, 4630-4632. – reference: P. D. Jadzinsky, G. Calero, C. J. Ackerson, D. A. Bushnell, R. D. Kornberg, Science 2007, 318, 430-433; – reference: R. L. Whetten, R. C. Price, Science 2007, 318, 407-408. – reference: H. Qian, W. T. Eckenhoff, Y. Zhu, T. Pintauer, R. Jin, J. Am. Chem. Soc. 2010, 132, 8280-8281. – reference: H. Yao, T. Fukui, K. Kimura, J. Phys. Chem. C 2007, 111, 14968-14976; – reference: M. W. Heaven, A. Dass, P. S. White, K. M. Holt, R. W. Murray, J. Am. Chem. Soc. 2008, 130, 3754-3755; – reference: S. Knoppe, A. C. Dharmaratne, E. Schreiner, A. Dass, T. Bürgi, J Am Chem. Soc 2010, 132, 16783-16789; – reference: H. Qian, Y. Zhu, R. Jin, J. Am. Chem. Soc. 2010, 132, 4583-4585; – reference: O. Voznyy, J. J. Dubowski, J. T. Yates, P. Maksymovych, J. Am. Chem. Soc. 2009, 131, 12989-12993; – reference: I. L. Garzón, M. R. Beltrán, G. González, I. Gutíerrez-González, K. Michaelian, J. A. Reyes-Nava, J. I. Rodríguez-Hernández, Eur. Phys. J. D 2003, 24, 105-109. – reference: O. Lopez-Acevedo, H. Tsunoyama, T. Tsukuda, H. Hakkinen, C. M. Aikens, J. Am. Chem. Soc. 2010, 132, 8210-8218. – reference: K. T. Wan, M. E. Davis, Nature 1994, 370, 449-450; – volume: 130 start-page: 3754 year: 2008 end-page: 3755 publication-title: J. Am. Chem. Soc. – start-page: 5393 year: 2005 end-page: 5395 publication-title: Chem. Commun. – volume: 113 start-page: 12966 year: 2009 end-page: 12969 publication-title: J. Phys. Chem. C – volume: 83 start-page: 5056 year: 2011 end-page: 5061 publication-title: Anal. Chem. – volume: 2 start-page: 609 year: 2010 end-page: 619 publication-title: ChemCatChem – volume: 20 start-page: 486 year: 2008 end-page: 493 publication-title: Chirality – volume: 11 start-page: 3963 year: 2011 end-page: 3969 publication-title: Nano Lett. – volume: 132 start-page: 8210 year: 2010 end-page: 8218 publication-title: J. Am. Chem. Soc. – volume: 12 start-page: 1474 year: 2011 end-page: 1480 publication-title: ChemPhysChem – volume: 112 start-page: 14221 year: 2008 end-page: 14224 publication-title: J. Phys. Chem. C – volume: 43 start-page: 91 year: 2007 end-page: 95 publication-title: Eur. Phys. J. D – volume: 370 start-page: 449 year: 1994 end-page: 450 publication-title: Nature – volume: 127 start-page: 15536 year: 2005 end-page: 15543 publication-title: J. Am. Chem. Soc. – volume: 318 start-page: 430 year: 2007 end-page: 433 publication-title: Science – volume: 3 start-page: 798 year: 2012 publication-title: Nat. Commun. – volume: 483 start-page: 311 year: 2012 end-page: 314 publication-title: Nature – volume: 132 start-page: 16783 year: 2010 end-page: 16789 publication-title: J Am Chem. Soc – volume: 50 start-page: 201 year: 2003 end-page: 341 publication-title: Surf. Sci. Rep. – volume: 111 start-page: 14968 year: 2007 end-page: 14976 publication-title: J. Phys. Chem. C – volume: 318 start-page: 407 year: 2007 end-page: 408 publication-title: Science – volume: 24 start-page: 105 year: 2003 end-page: 109 publication-title: Eur. Phys. J. D – volume: 66 start-page: 073403 year: 2002 publication-title: Phys. Rev. B – volume: 132 start-page: 8280 year: 2010 end-page: 8281 publication-title: J. Am. Chem. Soc. – volume: 128 start-page: 11079 year: 2006 end-page: 11087 publication-title: J. Am. Chem. Soc. – volume: 48 start-page: 4630 year: 2012 end-page: 4632 publication-title: Chem. Commun. – volume: 10 start-page: 483 year: 2009 end-page: 492 publication-title: ChemPhysChem – volume: 271 start-page: 155 year: 2010 end-page: 160 publication-title: J. Catal. – volume: 102 start-page: 10643 year: 1998 end-page: 10646 publication-title: J. Phys. Chem. B – volume: 113 start-page: 5035 year: 2009 end-page: 5038 publication-title: J. Phys. Chem. C – volume: 130 start-page: 5940 year: 2008 end-page: 5946 publication-title: J. Am. Chem. Soc. – volume: 132 start-page: 4583 year: 2010 end-page: 4585 publication-title: J. Am. Chem. Soc. – volume: 131 12 start-page: 12989 2483 year: 2009 1996 end-page: 12993 2487 publication-title: J. Am. Chem. Soc. Langmuir – volume: 104 start-page: 2630 year: 2000 end-page: 2641 publication-title: J. Phys. Chem. B – volume: 105 start-page: 9157 year: 2008 end-page: 9162 publication-title: Proc. Natl. Acad. Sci. USA |
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| Snippet | Chirality unveiled: Thiolate‐protected Au40(SR)24 clusters were enantioenriched using an HPLC approach. CD spectra show strong mirror‐image responses,... |
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| SubjectTerms | chirality chromatography Chromatography, High Pressure Liquid Circular Dichroism gold clusters gold nanoparticles Nanoparticles - chemistry Organogold Compounds - chemistry Organogold Compounds - isolation & purification stereochemistry Stereoisomerism Sulfhydryl Compounds - chemistry |
| Title | Separation of Enantiomers and CD Spectra of Au40(SCH2CH2Ph)24: Spectroscopic Evidence for Intrinsic Chirality |
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