Lattice Parameter and Stoichiometry of TiCx Produced in Alloyed Ti-C Systems by Self-Propagating High-Temperature Synthesis
Compared with the Ti–C system, the additions of metals (Fe, Al, and Cu) can increase the lattice parameter and stoichiometry of TiCx by forming metal–Ti intermediate phases (for C/Ti≤0.8). But for C/Ti>0.8, the Fe addition can decrease the lattice parameter and stoichiometry of TiCx by the format...
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| Published in | Journal of the American Ceramic Society Vol. 91; no. 11; pp. 3813 - 3816 |
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| Main Authors | , , , |
| Format | Journal Article |
| Language | English |
| Published |
Malden, USA
Blackwell Publishing Inc
01.11.2008
Wiley |
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| Abstract | Compared with the Ti–C system, the additions of metals (Fe, Al, and Cu) can increase the lattice parameter and stoichiometry of TiCx by forming metal–Ti intermediate phases (for C/Ti≤0.8). But for C/Ti>0.8, the Fe addition can decrease the lattice parameter and stoichiometry of TiCx by the formation of Fe–C solid solutions due to the hindrance of atom diffusion and the decrease of combustion temperature, while the additions of Al and Cu can increase them by the formation of Al–Ti and Cu–Ti solid solutions due to the dilution of Al and Cu. |
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| AbstractList | Compared with the Ti-C system, the addition of metals (Fe, Al, and Cu) can increase the lattice parameter and stoichiometry of TiCx by forming metal-Ti intermediate phases (for C/Ti up to 0.8). But for C/Ti > 0.8, the Fe addition can decrease the lattice parameter and stoichiometry of TiCx by the formation of Fe-C solid solutions due to the hindrance of atom diffusion and the decrease of combustion temperature, while the additions of Al and Cu can increase them by the formation of Al-Ti and Cu-Ti solid solutions due to the dilution of Al and Cu. Compared with the Ti–C system, the additions of metals (Fe, Al, and Cu) can increase the lattice parameter and stoichiometry of TiCx by forming metal–Ti intermediate phases (for C/Ti≤0.8). But for C/Ti>0.8, the Fe addition can decrease the lattice parameter and stoichiometry of TiCx by the formation of Fe–C solid solutions due to the hindrance of atom diffusion and the decrease of combustion temperature, while the additions of Al and Cu can increase them by the formation of Al–Ti and Cu–Ti solid solutions due to the dilution of Al and Cu. |
| Author | Wang, Jin-Guo Yang, Ya-Feng Wang, Hui-Yuan Jiang, Qi-Chuan |
| Author_xml | – sequence: 1 givenname: Ya-Feng surname: Yang fullname: Yang, Ya-Feng organization: Key Laboratory of Automobile Materials of Ministry of Education and Department of Materials Science and Engineering, Jilin University, Changchun 130025, China – sequence: 2 givenname: Hui-Yuan surname: Wang fullname: Wang, Hui-Yuan organization: Key Laboratory of Automobile Materials of Ministry of Education and Department of Materials Science and Engineering, Jilin University, Changchun 130025, China – sequence: 3 givenname: Jin-Guo surname: Wang fullname: Wang, Jin-Guo organization: Key Laboratory of Automobile Materials of Ministry of Education and Department of Materials Science and Engineering, Jilin University, Changchun 130025, China – sequence: 4 givenname: Qi-Chuan surname: Jiang fullname: Jiang, Qi-Chuan email: jqc@jlu.edu.cn organization: Key Laboratory of Automobile Materials of Ministry of Education and Department of Materials Science and Engineering, Jilin University, Changchun 130025, China |
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| Keywords | Stoichiometry Combustion synthesis Inorganic compounds Copper additions Self propagating high temperature synthesis XRD Experimental study Lattice parameters Structure composition relationship Fabrication Titanium Carbides Aluminium additions Alloying Iron additions Carbides |
| Language | English |
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| Notes | ark:/67375/WNG-MTLQ7MK7-3 istex:DD9EEDDA48ED2B744140709DBD250CE8C4FB6C7A ArticleID:JACE02749 This work is supported by NNSFC (No. 50531030), MSTC (Nos. 2006AA03Z566 and 2005CCA00300) and NCET (No. 06‐0308), as well as The Project 985‐Automotive Engineering of Jilin University. C. L. Yeh—contributing editor ObjectType-Article-2 SourceType-Scholarly Journals-1 ObjectType-Feature-1 content type line 23 |
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Technol A – volume: 46 start-page: 121 issue: [2] year: 2002 end-page: 6 article-title: Carbide Stoichiometry in TiC and Cu–TiC Produced by Self‐Propagating High‐Temperature Synthesis publication-title: Scripta Mater. – volume: 458 start-page: 235 issue: [1–2] year: 2007 end-page: 9 article-title: Thermodynamic and Lattice Parameter Calculation of TiC Produced from Al–Ti–C Powders by Laser Igniting Self‐Propagating High‐Temperature Synthesis publication-title: Mater. Sci. Eng. A |
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| Snippet | Compared with the Ti–C system, the additions of metals (Fe, Al, and Cu) can increase the lattice parameter and stoichiometry of TiCx by forming metal–Ti... Compared with the Ti-C system, the addition of metals (Fe, Al, and Cu) can increase the lattice parameter and stoichiometry of TiCx by forming metal-Ti... |
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| SubjectTerms | Composition and phase identification Condensed matter: structure, mechanical and thermal properties Exact sciences and technology Hydrides, borides, nitrides, etc., and metalloidal compounds Inorganic compounds Physics Structure of solids and liquids; crystallography Structure of specific crystalline solids Surfaces and interfaces; thin films and whiskers (structure and nonelectronic properties) Thin film structure and morphology |
| Title | Lattice Parameter and Stoichiometry of TiCx Produced in Alloyed Ti-C Systems by Self-Propagating High-Temperature Synthesis |
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