Symmetry forbidden vibronic transitions near the S K edge excitation of the SF6 molecule
Synopsis Near sulfur K edge photoionization of the SF6, molecule has been studied for X-ray photons. Total and partial photoion yields for the fragmentation products have been recorded as a function of the incident photon energy. The atomic fluorine ion, F+, dominates the mass spectra in the energy...
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Published in | Journal of physics. Conference series Vol. 635; no. 11 |
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Main Authors | , , , , , , |
Format | Journal Article |
Language | English |
Published |
Bristol
IOP Publishing
07.09.2015
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Abstract | Synopsis Near sulfur K edge photoionization of the SF6, molecule has been studied for X-ray photons. Total and partial photoion yields for the fragmentation products have been recorded as a function of the incident photon energy. The atomic fluorine ion, F+, dominates the mass spectra in the energy range studied in this paper. The intensity of absorption for the dipole-forbidden but vibronically allowed transition S K (1a1g→6a1g) was calculated for the first time. This transition is shown to play a part in the fragmentation profile. |
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AbstractList | Near sulfur K edge photoionization of the SF6, molecule has been studied for X-ray photons. Total and partial photoion yields for the fragmentation products have been recorded as a function of the incident photon energy. The atomic fluorine ion, F+, dominates the mass spectra in the energy range studied in this paper. The intensity of absorption for the dipole-forbidden but vibronically allowed transition S K (1a1g→6a1g) was calculated for the first time. This transition is shown to play a part in the fragmentation profile. Synopsis Near sulfur K edge photoionization of the SF6, molecule has been studied for X-ray photons. Total and partial photoion yields for the fragmentation products have been recorded as a function of the incident photon energy. The atomic fluorine ion, F+, dominates the mass spectra in the energy range studied in this paper. The intensity of absorption for the dipole-forbidden but vibronically allowed transition S K (1a1g→6a1g) was calculated for the first time. This transition is shown to play a part in the fragmentation profile. |
Author | Rocha, A B Alcantara, K F Santos, A C F Gomes, A H A Oliveira, R R Sigaud, G M Wolff, W |
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Copyright | Published under licence by IOP Publishing Ltd 2015. This work is published under http://creativecommons.org/licenses/by/3.0/ (the “License”). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License. |
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DOI | 10.1088/1742-6596/635/11/112026 |
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Snippet | Synopsis Near sulfur K edge photoionization of the SF6, molecule has been studied for X-ray photons. Total and partial photoion yields for the fragmentation... Near sulfur K edge photoionization of the SF6, molecule has been studied for X-ray photons. Total and partial photoion yields for the fragmentation products... |
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SubjectTerms | Atomic properties Dipoles Fluorine Fragmentation Mass spectra Photoionization Photons Physics Sulfur hexafluoride |
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Title | Symmetry forbidden vibronic transitions near the S K edge excitation of the SF6 molecule |
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