Microwave hydrothermal synthesis and upconversion properties of BiVO4 nanoparticles
Nanomaterials are the subject of extensive investigations due to their applications in medicine, multimodal imaging, volumetric displays, and photonics. Here, lanthanide-doped bismuth vanadate (BiVO4) upconverting nanoparticles (UCNPs) have been reported. The nanoparticles have been synthesized by a...
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Published in | Nanotechnology Vol. 31; no. 24; pp. 244001 - 244010 |
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Main Authors | , , , , , , |
Format | Journal Article |
Language | English |
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IOP Publishing
27.03.2020
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Abstract | Nanomaterials are the subject of extensive investigations due to their applications in medicine, multimodal imaging, volumetric displays, and photonics. Here, lanthanide-doped bismuth vanadate (BiVO4) upconverting nanoparticles (UCNPs) have been reported. The nanoparticles have been synthesized by a microwave hydrothermal method. As-synthesized nanoparticles are highly crystalline in the tetragonal zircon phase with particles about 200 nm in size. Under 980 nm excitation, intense multicolor visible and near-infrared upconversion emissions are observed. Moreover, broadband infrared downshifting emissions are also observed. Time-resolved emission measurements have been carried out to investigate the involved upconversion and energy transfer mechanism. The BiVO4-based UCNPs may provide a new class of nanomaterials for multifunctional applications. |
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AbstractList | Nanomaterials are the subject of extensive investigations due to their applications in medicine, multimodal imaging, volumetric displays, and photonics. Here, lanthanide-doped bismuth vanadate (BiVO4) upconverting nanoparticles (UCNPs) have been reported. The nanoparticles have been synthesized by a microwave hydrothermal method. As-synthesized nanoparticles are highly crystalline in the tetragonal zircon phase with particles about 200 nm in size. Under 980 nm excitation, intense multicolor visible and near-infrared upconversion emissions are observed. Moreover, broadband infrared downshifting emissions are also observed. Time-resolved emission measurements have been carried out to investigate the involved upconversion and energy transfer mechanism. The BiVO4-based UCNPs may provide a new class of nanomaterials for multifunctional applications.Nanomaterials are the subject of extensive investigations due to their applications in medicine, multimodal imaging, volumetric displays, and photonics. Here, lanthanide-doped bismuth vanadate (BiVO4) upconverting nanoparticles (UCNPs) have been reported. The nanoparticles have been synthesized by a microwave hydrothermal method. As-synthesized nanoparticles are highly crystalline in the tetragonal zircon phase with particles about 200 nm in size. Under 980 nm excitation, intense multicolor visible and near-infrared upconversion emissions are observed. Moreover, broadband infrared downshifting emissions are also observed. Time-resolved emission measurements have been carried out to investigate the involved upconversion and energy transfer mechanism. The BiVO4-based UCNPs may provide a new class of nanomaterials for multifunctional applications. Nanomaterials are the subject of extensive investigations due to their applications in medicine, multimodal imaging, volumetric displays, and photonics. Here, lanthanide-doped bismuth vanadate (BiVO4) upconverting nanoparticles (UCNPs) have been reported. The nanoparticles have been synthesized by a microwave hydrothermal method. As-synthesized nanoparticles are highly crystalline in the tetragonal zircon phase with particles about 200 nm in size. Under 980 nm excitation, intense multicolor visible and near-infrared upconversion emissions are observed. Moreover, broadband infrared downshifting emissions are also observed. Time-resolved emission measurements have been carried out to investigate the involved upconversion and energy transfer mechanism. The BiVO4-based UCNPs may provide a new class of nanomaterials for multifunctional applications. |
Author | Kshetri, Yuwaraj K Kim, Hak-Soo Lee, Soo Wohn Dhakal, Dhani Ram Kim, Tae-Ho Kim, Seung Ho Regmi, Chhabilal |
Author_xml | – sequence: 1 givenname: Yuwaraj K orcidid: 0000-0002-6943-1568 surname: Kshetri fullname: Kshetri, Yuwaraj K email: yuwarajkhatri@gmail.com organization: Sun Moon University Research Center for Eco-Multifunctional Nano Materials, Chungnam 31460, Republic of Korea – sequence: 2 givenname: Chhabilal surname: Regmi fullname: Regmi, Chhabilal organization: Sun Moon University Department of Environmental and Bio-Chemical Engineering, Chungnam 31460, Republic of Korea – sequence: 3 givenname: Dhani Ram orcidid: 0000-0002-4643-546X surname: Dhakal fullname: Dhakal, Dhani Ram organization: Sun Moon University Department of Environmental and Bio-Chemical Engineering, Chungnam 31460, Republic of Korea – sequence: 4 givenname: Tae-Ho orcidid: 0000-0002-4201-7535 surname: Kim fullname: Kim, Tae-Ho organization: Sun Moon University Division of Mechanics and ICT Convergence Engineering, Chungnam 31460, Republic of Korea – sequence: 5 givenname: Seung Ho surname: Kim fullname: Kim, Seung Ho organization: Sun Moon University Research Center for Eco-Multifunctional Nano Materials, Chungnam 31460, Republic of Korea – sequence: 6 givenname: Hak-Soo orcidid: 0000-0001-5876-1441 surname: Kim fullname: Kim, Hak-Soo organization: Sun Moon University Department of Environmental and Bio-Chemical Engineering, Chungnam 31460, Republic of Korea – sequence: 7 givenname: Soo Wohn orcidid: 0000-0002-0285-6959 surname: Lee fullname: Lee, Soo Wohn email: swlee@sunmoon.ac.kr organization: Sun Moon University Department of Environmental and Bio-Chemical Engineering, Chungnam 31460, Republic of Korea |
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