Stereoselective Synthesis of (Sulfonimidoyl)cyclopropanes with (R)-PhSO(NTs)CH2Cl and α,β-Unsaturated Weinreb Amides: Tuning the of Selectivity between C-Cl and C-S Bond Cleavage

• Published in: European Journal of Organic Chemistry Vol. 2016; no. 5; pp. 906 - 909
• Main Authors: Shen, Xiao, Liu, Qinghe, Zhang, Wei, Hu, Jinbo
• Format: Book Review
• Language: English
• Published: Weinheim WILEY-VCH Verlag 01.02.2016; WILEY‐VCH Verlag
• Subjects: C-Cl bond cleavage; C-S bond cleavage; Cyclopropanation; Cyclopropane; Sulfoximine

(Sulfonimidoyl)cyclopropanes have become the subject of special interest since they combine the advantages of two chemical leads (cyclopropane and sulfoximine). However, their synthesis is limited, and the stereoselective synthesis of optically enriched (sulfonimidoyl)cyclopropanes still remains an...