Substituent Effects on 31P NMR Chemical Shifts and 1JP-Se of triarylselenophosphates
The effect of electron-withdrawing (EW) and electron-releasing (ER) substituents on the 31 P NMR chemical shifts and the structural parameters of a series of tris-(p-X-aryl)selenophosphates is reported in this article. Similarly to O-aryl phosphates and O-aryl thiophosphates, EW groups attached to a...
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Published in | Phosphorus, sulfur, and silicon and the related elements Vol. 185; no. 4; pp. 772 - 784 |
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Main Authors | , , , , , |
Format | Journal Article |
Language | English |
Published |
ABINGDON
Taylor & Francis Group
01.04.2010
Taylor & Francis Taylor & Francis Ltd |
Subjects | |
Online Access | Get full text |
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Summary: | The effect of electron-withdrawing (EW) and electron-releasing (ER) substituents on the
31
P NMR chemical shifts and the structural parameters of a series of tris-(p-X-aryl)selenophosphates is reported in this article. Similarly to O-aryl phosphates and O-aryl thiophosphates, EW groups attached to aromatic rings induce a shielding effect on the
31
P NMR signal. After a detailed experimental and theoretical analysis, we confirmed that the selenium atom is the main part responsible for the charge density transfer toward phosphorus through a back-bonding effect. The obtained
1
J
P-Se
values for the complete series agree with this observation.
Supplemental materials are available for this article. Go to the publisher's online edition of Phosphorus, Sulfur, and Silicon and the Related Elements to view the free supplemental file. |
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ISSN: | 1042-6507 1563-5325 |
DOI: | 10.1080/10426500902953979 |