Cu3(hexaiminotriphenylene)2: An Electrically Conductive 2D Metal-Organic Framework for Chemiresistive Sensing
The utility of metal–organic frameworks (MOFs) as functional materials in electronic devices has been limited to date by a lack of MOFs that display high electrical conductivity. Here, we report the synthesis of a new electrically conductive 2D MOF, Cu3(HITP)2 (HITP=2,3,6,7,10,11‐hexaiminotriphenyle...
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| Published in | Angewandte Chemie International Edition Vol. 54; no. 14; pp. 4349 - 4352 |
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| Main Authors | , , , , |
| Format | Journal Article |
| Language | English |
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Weinheim
WILEY-VCH Verlag
27.03.2015
WILEY‐VCH Verlag Wiley Subscription Services, Inc |
| Edition | International ed. in English |
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| Abstract | The utility of metal–organic frameworks (MOFs) as functional materials in electronic devices has been limited to date by a lack of MOFs that display high electrical conductivity. Here, we report the synthesis of a new electrically conductive 2D MOF, Cu3(HITP)2 (HITP=2,3,6,7,10,11‐hexaiminotriphenylene), which displays a bulk conductivity of 0.2 S cm−1 (pellet, two‐point‐probe). Devices synthesized by simple drop casting of Cu3(HITP)2 dispersions function as reversible chemiresistive sensors, capable of detecting sub‐ppm levels of ammonia vapor. Comparison with the isostructural 2D MOF Ni3(HITP)2 shows that the copper sites are critical for ammonia sensing, indicating that rational design/synthesis can be used to tune the functional properties of conductive MOFs.
A MOF with a nose: Previous efforts to use metal–organic frameworks (MOFs) for chemical sensing have been hindered by poor signal transduction due to a lack of electrical conductivity. A new conductive 2D MOF can be used for the chemiresistive sensing of ammonia. It is shown that the sensing response can be varied by the choice of the metal node. |
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| AbstractList | The utility of metal-organic frameworks (MOFs) as functional materials in electronic devices has been limited to date by a lack of MOFs that display high electrical conductivity. Here, we report the synthesis of a new electrically conductive 2D MOF, Cu3(HITP)2 (HITP=2,3,6,7,10,11-hexaiminotriphenylene), which displays a bulk conductivity of 0.2 S cm(-1) (pellet, two-point-probe). Devices synthesized by simple drop casting of Cu3(HITP)2 dispersions function as reversible chemiresistive sensors, capable of detecting sub-ppm levels of ammonia vapor. Comparison with the isostructural 2D MOF Ni3(HITP)2 shows that the copper sites are critical for ammonia sensing, indicating that rational design/synthesis can be used to tune the functional properties of conductive MOFs. The utility of metal-organic frameworks (MOFs) as functional materials in electronic devices has been limited to date by a lack of MOFs that display high electrical conductivity. Here, we report the synthesis of a new electrically conductive 2D MOF, Cu3(HITP)2 (HITP=2,3,6,7,10,11-hexaiminotriphenylene), which displays a bulk conductivity of 0.2Scm-1 (pellet, two-point-probe). Devices synthesized by simple drop casting of Cu3(HITP)2 dispersions function as reversible chemiresistive sensors, capable of detecting sub-ppm levels of ammonia vapor. Comparison with the isostructural 2D MOF Ni3(HITP)2 shows that the copper sites are critical for ammonia sensing, indicating that rational design/synthesis can be used to tune the functional properties of conductive MOFs. The utility of metal-organic frameworks (MOFs) as functional materials in electronic devices has been limited to date by a lack of MOFs that display high electrical conductivity. Here, we report the synthesis of a new electrically conductive 2D MOF, Cu3(HITP)2 (HITP=2,3,6,7,10,11-hexaiminotriphenylene), which displays a bulk conductivity of 0.2 S cm(-1) (pellet, two-point-probe). Devices synthesized by simple drop casting of Cu3(HITP)2 dispersions function as reversible chemiresistive sensors, capable of detecting sub-ppm levels of ammonia vapor. Comparison with the isostructural 2D MOF Ni3(HITP)2 shows that the copper sites are critical for ammonia sensing, indicating that rational design/synthesis can be used to tune the functional properties of conductive MOFs.The utility of metal-organic frameworks (MOFs) as functional materials in electronic devices has been limited to date by a lack of MOFs that display high electrical conductivity. Here, we report the synthesis of a new electrically conductive 2D MOF, Cu3(HITP)2 (HITP=2,3,6,7,10,11-hexaiminotriphenylene), which displays a bulk conductivity of 0.2 S cm(-1) (pellet, two-point-probe). Devices synthesized by simple drop casting of Cu3(HITP)2 dispersions function as reversible chemiresistive sensors, capable of detecting sub-ppm levels of ammonia vapor. Comparison with the isostructural 2D MOF Ni3(HITP)2 shows that the copper sites are critical for ammonia sensing, indicating that rational design/synthesis can be used to tune the functional properties of conductive MOFs. The utility of metal–organic frameworks (MOFs) as functional materials in electronic devices has been limited to date by a lack of MOFs that display high electrical conductivity. Here, we report the synthesis of a new electrically conductive 2D MOF, Cu3(HITP)2 (HITP=2,3,6,7,10,11‐hexaiminotriphenylene), which displays a bulk conductivity of 0.2 S cm−1 (pellet, two‐point‐probe). Devices synthesized by simple drop casting of Cu3(HITP)2 dispersions function as reversible chemiresistive sensors, capable of detecting sub‐ppm levels of ammonia vapor. Comparison with the isostructural 2D MOF Ni3(HITP)2 shows that the copper sites are critical for ammonia sensing, indicating that rational design/synthesis can be used to tune the functional properties of conductive MOFs. A MOF with a nose: Previous efforts to use metal–organic frameworks (MOFs) for chemical sensing have been hindered by poor signal transduction due to a lack of electrical conductivity. A new conductive 2D MOF can be used for the chemiresistive sensing of ammonia. It is shown that the sensing response can be varied by the choice of the metal node. |
| Author | Liu, Sophie F. Dincă, Mircea Campbell, Michael G. Sheberla, Dennis Swager, Timothy M. |
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| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/25678397$$D View this record in MEDLINE/PubMed |
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| Copyright | 2015 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim |
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| Keywords | ammonia copper sensors conductivity metal-organic frameworks |
| Language | English |
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| Notes | Sloan Foundation istex:CC9A77CBA1C5ADDE766362BF4DBD24327AA38C0E Research Corporation for Science Advancement U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences - No. DE-SC0001088 ArticleID:ANIE201411854 NSF - No. ECS-0335765 Synthetic and characterization work (excluding vapor sensing experiments) was supported as part of the Center for Excitonics, an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences under award number DE-SC0001088 (MIT). M.D. thanks the Camille and Henry Dreyfus Postdoctoral Program in Environmental Chemistry for support of M.G.C. We thank Miller Li for assistance with acquiring SEM images and Lei Sun for helpful discussions. M.D. gratefully acknowledges early career support from the Sloan Foundation, the Research Corporation for Science Advancement (Cottrell Scholar), and 3M. S.F.L. and T.M.S. acknowledge support from a Graduate Research Fellowship under Grant No. 1122374, as well as the Army Research Office through the Institute for Soldier Nanotechnologies (sensing experiments). The SEM and XPS characterization data were obtained at the Harvard Center for Nanoscale Systems, which is supported by NSF Grant ECS-0335765. Army Research Office ark:/67375/WNG-G4Z7GM2X-C Synthetic and characterization work (excluding vapor sensing experiments) was supported as part of the Center for Excitonics, an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences under award number DE‐SC0001088 (MIT). M.D. thanks the Camille and Henry Dreyfus Postdoctoral Program in Environmental Chemistry for support of M.G.C. We thank Miller Li for assistance with acquiring SEM images and Lei Sun for helpful discussions. M.D. gratefully acknowledges early career support from the Sloan Foundation, the Research Corporation for Science Advancement (Cottrell Scholar), and 3M. S.F.L. and T.M.S. acknowledge support from a Graduate Research Fellowship under Grant No. 1122374, as well as the Army Research Office through the Institute for Soldier Nanotechnologies (sensing experiments). The SEM and XPS characterization data were obtained at the Harvard Center for Nanoscale Systems, which is supported by NSF Grant ECS‐0335765. ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 14 content type line 23 |
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| Snippet | The utility of metal–organic frameworks (MOFs) as functional materials in electronic devices has been limited to date by a lack of MOFs that display high... The utility of metal-organic frameworks (MOFs) as functional materials in electronic devices has been limited to date by a lack of MOFs that display high... |
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| SubjectTerms | Ammonia conductivity copper metal-organic frameworks sensors |
| Title | Cu3(hexaiminotriphenylene)2: An Electrically Conductive 2D Metal-Organic Framework for Chemiresistive Sensing |
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