Concerted Rattling in CsAg5Te3 Leading to Ultralow Thermal Conductivity and High Thermoelectric Performance
Thermoelectric (TE) materials convert heat energy directly into electricity, and introducing new materials with high conversion efficiency is a great challenge because of the rare combination of interdependent electrical and thermal transport properties required to be present in a single material. T...
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| Published in | Angewandte Chemie International Edition Vol. 55; no. 38; pp. 11431 - 11436 |
|---|---|
| Main Authors | , , , , , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Weinheim
Blackwell Publishing Ltd
12.09.2016
Wiley Subscription Services, Inc |
| Edition | International ed. in English |
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| Abstract | Thermoelectric (TE) materials convert heat energy directly into electricity, and introducing new materials with high conversion efficiency is a great challenge because of the rare combination of interdependent electrical and thermal transport properties required to be present in a single material. The TE efficiency is defined by the figure of merit ZT=(S2σ) T/κ, where S is the Seebeck coefficient, σ is the electrical conductivity, κ is the total thermal conductivity, and T is the absolute temperature. A new p‐type thermoelectric material, CsAg5Te3, is presented that exhibits ultralow lattice thermal conductivity (ca. 0.18 Wm−1 K−1) and a high figure of merit of about 1.5 at 727 K. The lattice thermal conductivity is the lowest among state‐of‐the‐art thermoelectrics; it is attributed to a previously unrecognized phonon scattering mechanism that involves the concerted rattling of a group of Ag ions that strongly raises the Grüneisen parameters of the material.
A p‐type thermoelectric material, CsAg5Te3, is presented. It exhibits ultralow thermal conductivity (ϰtol≈0.18 Wm−1 K−1) and a high figure of merit (ZT≈1.5 at 727 K). The low thermal conductivity is attributed to a previously unrecognized phonon scattering mechanism that involves the rattling of Ag ions, strongly raising the Grüneisen parameters of the material. |
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| AbstractList | Thermoelectric (TE) materials convert heat energy directly into electricity, and introducing new materials with high conversion efficiency is a great challenge because of the rare combination of interdependent electrical and thermal transport properties required to be present in a single material. The TE efficiency is defined by the figure of merit ZT=(S2σ) T/[kappa], where S is the Seebeck coefficient, σ is the electrical conductivity, [kappa] is the total thermal conductivity, and T is the absolute temperature. A new p-type thermoelectric material, CsAg5Te3, is presented that exhibits ultralow lattice thermal conductivity (ca. 0.18Wm-1K-1) and a high figure of merit of about 1.5 at 727K. The lattice thermal conductivity is the lowest among state-of-the-art thermoelectrics; it is attributed to a previously unrecognized phonon scattering mechanism that involves the concerted rattling of a group of Ag ions that strongly raises the Gruneisen parameters of the material. Thermoelectric (TE) materials convert heat energy directly into electricity, and introducing new materials with high conversion efficiency is a great challenge because of the rare combination of interdependent electrical and thermal transport properties required to be present in a single material. The TE efficiency is defined by the figure of merit ZT=(S2σ) T/κ, where S is the Seebeck coefficient, σ is the electrical conductivity, κ is the total thermal conductivity, and T is the absolute temperature. A new p‐type thermoelectric material, CsAg5Te3, is presented that exhibits ultralow lattice thermal conductivity (ca. 0.18 Wm−1 K−1) and a high figure of merit of about 1.5 at 727 K. The lattice thermal conductivity is the lowest among state‐of‐the‐art thermoelectrics; it is attributed to a previously unrecognized phonon scattering mechanism that involves the concerted rattling of a group of Ag ions that strongly raises the Grüneisen parameters of the material. A p‐type thermoelectric material, CsAg5Te3, is presented. It exhibits ultralow thermal conductivity (ϰtol≈0.18 Wm−1 K−1) and a high figure of merit (ZT≈1.5 at 727 K). The low thermal conductivity is attributed to a previously unrecognized phonon scattering mechanism that involves the rattling of Ag ions, strongly raising the Grüneisen parameters of the material. |
| Author | Wolverton, Christopher Wu, Li-Ming Shen, Jin-Ni Kanatzidis, Mercouri G. Tan, Gangjian Calta, Nicholas Lin, Hua Hao, Shiqiang Wang, Si Uher, Ctirad Malliakas, Christos |
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| Copyright | 2016 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim |
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| Notes | ArticleID:ANIE201605015 ark:/67375/WNG-T9MHZXG8-W istex:8631F9DA7E9FFC5FAF4E7D150D0B032935659D64 National Natural Science Foundation of China - No. 21571020; No. 20973175; No. 21233009; No. 21301175; No. 21225104; No. 91422303 Department of Energy - No. DE-SC0014520 NSF of Fujian Province - No. 2015J01071 These authors contributed equally to this work. ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 14 |
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| SubjectTerms | Coefficients concerted rattling Conductivity CsAg5Te3 Direct power generation Electrical conductivity Electrical resistivity Electricity Energy Energy conversion efficiency Energy management Figure of merit Heat Heat conductivity Heat transfer Ions Scattering State of the art Temperature Temperature effects Thermal conductivity Thermoelectric materials Transport properties tunnel structure ultralow thermal conductivity |
| Title | Concerted Rattling in CsAg5Te3 Leading to Ultralow Thermal Conductivity and High Thermoelectric Performance |
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