Boosting CO2 Photoreduction to Formate or CO with High Selectivity over a Covalent Organic Framework Covalently Anchored on Graphene Oxide

• Published in: Angewandte Chemie International Edition Vol. 63; no. 10; pp. e202318735 - n/a
• Main Authors: Gong, Yun‐Nan, Mei, Jian‐Hua, Shi, Wen‐Jie, Liu, Jin‐Wang, Zhong, Di‐Chang, Lu, Tong‐Bu
• Format: Journal Article
• Language: English
• Published: Germany Wiley Subscription Services, Inc 04.03.2024
• Edition: International ed. in English
• Subjects: Acetonitrile; Carbon dioxide; Catalytic activity; Charge transfer; Chemical reduction; CO2 Reduction; Covalence; Covalent-Organic Frameworks; Fourier transforms; Graphene; Graphene Oxide; Hydrogen bonding; Hydrogen Bonds; Infrared spectroscopy; Photocatalysis; Photoreduction; graphene oxide; Covalent-organic frameworks; CO2 reduction; hydrogen bonds; Photocatalysis

Covalent organic frameworks (COFs) have been widely studied in photocatalytic CO2 reduction reaction (CO2RR). However, pristine COFs usually exhibit low catalytic efficiency owing to the fast recombination of photogenerated electrons and holes. In this study, we fabricated a stable COF‐based composi...