Modification of Carbon Nanotubes via Birch Reaction for Enhanced HER Catalyst by Constructing Pearl Necklace‐Like NiCo2P2–CNT Composite

• Published in: Small (Weinheim an der Bergstrasse, Germany) Vol. 14; no. 51
• Main Authors: Gao, Saisai, Zhang, Yin, Zhang, Yanjun, Wang, Bin, Yang, Shengchun
• Format: Journal Article
• Language: English
• Published: Weinheim Wiley Subscription Services, Inc 20.12.2018
• Subjects: Alkylation; Birch reaction; Carbon nanotubes; Composite materials; Electrical resistivity; Electrocatalysts; Electrons; Fourier transforms; Functional groups; hydrogen evolution reaction; Hydrogen evolution reactions; Nanotechnology; NiCo2P2 nanoparticles; Oxidation; pearl necklace‐like structure; Phosphides; Photoelectrons; Reaction kinetics; Spectrum analysis; Stability; Structural integrity; Transition metals
• DOI: 10.1002/smll.201804388
• ISSN: 1613-6810

Combining transition metal phosphides (TMPs) with carbon nanotubes (CNTs) is a promising and proven approach to enhance their performance in the electrochemical hydrogen evolution reaction (HER), due to the excellent conductivity and stability of CNTs. Generally, the deep oxidation of CNTs to form oxygen‐containing groups on their surface is indispensable before combining them with TMPs. However, such approaches inevitably introduce a large number of defects to CNTs and apparently decrease their stability and electrical conductivity. Hence, fabricating TMP–CNT composites which does not come at the expense of CNTs' high electrical conductivity is quite desirable. In this work, alkylated CNTs (named as ACNT) functionalized via the Birch reaction are used to prepare the pearl necklace‐like NiCo2P2–ACNT composites for electrocatalysts toward HER in acidic and alkaline conditions, respectively. The X‐ray photoelectron spectroscopy, transmission electron microscope, and Fourier transform infrared spectroscopy characterizations indicate that the ACNTs are well modified with functional groups and keep their structural integrity, thereby maximizing their excellent conductivity. Compared to bare NiCo2P2 and the NiCo2P2–CNT composites prepared with mildly oxidized CNTs and deeply oxidized CNTs, the NiCo2P2–ACNTs show far better HER performance and much faster kinetics. Alkylated carbon nanotubes (ACNTs) are obtained by modifying CNTs via the Birch reaction. The ACNTs preserve integrated tubular structures as well as high conductivities, which leads to enhanced hydrogen evolution reaction activity by constructing a pearl necklace‐like NiCo2P2–ACNT composite.