Ni2P Interlayer and Mn Doping Synergistically Expedite the Hydrogen Evolution Reaction Kinetics of Co2P
Transition metal phosphide is regarded as one of the most promising candidates to replace noble‐metal hydrogen evolution reaction (HER) electrocatalysts. Nevertheless, the controllable design and synthesis of transition metal phosphide electrocatalysts with efficient and stable electrochemical perfo...
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Published in | Chemistry : a European journal Vol. 27; no. 10; pp. 3536 - 3541 |
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Abstract | Transition metal phosphide is regarded as one of the most promising candidates to replace noble‐metal hydrogen evolution reaction (HER) electrocatalysts. Nevertheless, the controllable design and synthesis of transition metal phosphide electrocatalysts with efficient and stable electrochemical performance are still very challenging. Herein, a novel hierarchical HER electrocatalyst consisting of three‐dimensional (3D) coral‐like Mn‐doped Co2P@an intermediate layer of Ni2P generated in situ by phosphorization on Ni foam (MnCoP/NiP/NF) is reported. Notably, both the incorporation of Mn and introduction of the Ni2P interlayer promote Co atoms to carry more electrons, which is beneficial to reduce the force of the Co−H bond and optimize the adsorption energy of hydrogen intermediate (|ΔGH*|), thereby making MnCoP/NiP/NF exhibit outstanding HER performance with onset overpotential and Tafel slope as low as 31.2 mV and 61 mV dec−1, respectively, in 1 m KOH electrolyte.
A hierarchical hydrogen evolution reaction (HER) electrocatalyst consisting of three‐dimensional (3D) coral‐like Mn‐doped Co2P@an intermediate layer of Ni2P generated in situ by phosphorization on Ni foam (MnCoP/NiP/NF) is prepared. Note that there is an electron channel between NiP and MnCoP, electrons in Ni transfer to Co and P, which effectively weakens the strong adsorption capacity of H* and expedites the HER kinetics of Co2P. |
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AbstractList | Transition metal phosphide is regarded as one of the most promising candidates to replace noble‐metal hydrogen evolution reaction (HER) electrocatalysts. Nevertheless, the controllable design and synthesis of transition metal phosphide electrocatalysts with efficient and stable electrochemical performance are still very challenging. Herein, a novel hierarchical HER electrocatalyst consisting of three‐dimensional (3D) coral‐like Mn‐doped Co2P@an intermediate layer of Ni2P generated in situ by phosphorization on Ni foam (MnCoP/NiP/NF) is reported. Notably, both the incorporation of Mn and introduction of the Ni2P interlayer promote Co atoms to carry more electrons, which is beneficial to reduce the force of the Co−H bond and optimize the adsorption energy of hydrogen intermediate (|ΔGH*|), thereby making MnCoP/NiP/NF exhibit outstanding HER performance with onset overpotential and Tafel slope as low as 31.2 mV and 61 mV dec−1, respectively, in 1 m KOH electrolyte. Transition metal phosphide is regarded as one of the most promising candidates to replace noble‐metal hydrogen evolution reaction (HER) electrocatalysts. Nevertheless, the controllable design and synthesis of transition metal phosphide electrocatalysts with efficient and stable electrochemical performance are still very challenging. Herein, a novel hierarchical HER electrocatalyst consisting of three‐dimensional (3D) coral‐like Mn‐doped Co2P@an intermediate layer of Ni2P generated in situ by phosphorization on Ni foam (MnCoP/NiP/NF) is reported. Notably, both the incorporation of Mn and introduction of the Ni2P interlayer promote Co atoms to carry more electrons, which is beneficial to reduce the force of the Co−H bond and optimize the adsorption energy of hydrogen intermediate (|ΔGH*|), thereby making MnCoP/NiP/NF exhibit outstanding HER performance with onset overpotential and Tafel slope as low as 31.2 mV and 61 mV dec−1, respectively, in 1 m KOH electrolyte. A hierarchical hydrogen evolution reaction (HER) electrocatalyst consisting of three‐dimensional (3D) coral‐like Mn‐doped Co2P@an intermediate layer of Ni2P generated in situ by phosphorization on Ni foam (MnCoP/NiP/NF) is prepared. Note that there is an electron channel between NiP and MnCoP, electrons in Ni transfer to Co and P, which effectively weakens the strong adsorption capacity of H* and expedites the HER kinetics of Co2P. |
Author | Zhao, Huimin Liu, Bin Du, Yunmei Liu, Yanru Li, Shaoxiang Wang, Lei Wang, Wensi |
Author_xml | – sequence: 1 givenname: Yunmei surname: Du fullname: Du, Yunmei organization: Qingdao University of Science and Technology – sequence: 2 givenname: Wensi surname: Wang fullname: Wang, Wensi organization: Qingdao University of Science and Technology – sequence: 3 givenname: Huimin surname: Zhao fullname: Zhao, Huimin organization: Qingdao University of Science and Technology – sequence: 4 givenname: Yanru surname: Liu fullname: Liu, Yanru email: liuyanru@qust.edu.cn organization: Qingdao University of Science and Technology – sequence: 5 givenname: Shaoxiang surname: Li fullname: Li, Shaoxiang organization: Qingdao University of Science and Technology – sequence: 6 givenname: Lei orcidid: 0000-0001-7275-4846 surname: Wang fullname: Wang, Lei email: inorchemwl@126.com organization: Qingdao University of Science and Technology – sequence: 7 givenname: Bin surname: Liu fullname: Liu, Bin organization: Nanyang Technological University |
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References_xml | – volume: 10 year: 2020 publication-title: Adv. Energy Mater. – volume: 27 year: 2017 publication-title: Adv. Funct. Mater. – volume: 58 131 start-page: 11796 11922 year: 2019 2019 end-page: 11800 11926 publication-title: Angew. Chem. Int. Ed. Angew. Chem. – volume: 360 start-page: 707 year: 2018 end-page: 708 publication-title: Science – volume: 8 start-page: 1184 year: 2020 end-page: 1192 publication-title: J. Mater. Chem. A – volume: 10 start-page: 788 year: 2017 end-page: 798 publication-title: Energy Environ. Sci. – volume: 1 start-page: 77 year: 2017 end-page: 107 publication-title: Joule – volume: 58 131 start-page: 16289 16435 year: 2019 2019 end-page: 16296 16442 publication-title: Angew. Chem. Int. Ed. Angew. Chem. – volume: 7 start-page: 8602 year: 2019 end-page: 8608 publication-title: J. Mater. Chem. A – volume: 7 start-page: 14842 year: 2019 end-page: 14848 publication-title: J. Mater. Chem. A – volume: 416 start-page: 95 year: 2019 end-page: 103 publication-title: J. Power Sources – volume: 14 start-page: 4141 year: 2020 end-page: 4152 publication-title: ACS Nano – volume: 7 start-page: 98 year: 2017 end-page: 102 publication-title: ACS Catal. – volume: 8 start-page: 27850 year: 2016 end-page: 27858 publication-title: ACS Appl. Mater. Interfaces – volume: 8 start-page: 10425 year: 2016 end-page: 10432 publication-title: Nanoscale – volume: 138 start-page: 14686 year: 2016 end-page: 14693 publication-title: J. Am. Chem. Soc. – volume: 574 start-page: 81 year: 2019 end-page: 85 publication-title: Nature – volume: 22 start-page: 15540 year: 2012 end-page: 15548 publication-title: J. Mater. Chem. – volume: 31 year: 2019 publication-title: Adv. Mater. – volume: 9 year: 2019 publication-title: Adv. Energy Mater. – volume: 26 start-page: 738 year: 2016 end-page: 744 publication-title: Adv. Funct. Mater. – volume: 23 start-page: 4128 year: 2017 end-page: 4136 publication-title: Chem. Eur. J. – volume: 55 128 start-page: 2230 2270 year: 2016 2016 end-page: 2234 2274 publication-title: Angew. Chem. Int. Ed. Angew. Chem. – volume: 12 start-page: 2443 year: 2019 end-page: 2454 publication-title: Energy Environ. Sci. – volume: 29 year: 2019 publication-title: Adv. Funct. Mater. – volume: 30 year: 2018 publication-title: Adv. Mater. – volume: 258 year: 2019 publication-title: Appl. Catal. B Environ. – volume: 139 start-page: 8320 year: 2017 end-page: 8328 publication-title: J. Am. Chem. Soc. – volume: 24 start-page: 2938 year: 2014 end-page: 2946 publication-title: Adv. Funct. Mater. – volume: 28 start-page: 9006 year: 2016 end-page: 9011 publication-title: Adv. Mater. – volume: 2 start-page: 11472 year: 2014 end-page: 11479 publication-title: J. Mater. Chem. A – volume: 61 start-page: 611 year: 2019 end-page: 616 publication-title: Nano Energy – volume: 5 start-page: 7068 year: 2015 publication-title: ACS Catal. – volume: 142 start-page: 3980 year: 2020 end-page: 3988 publication-title: J. Am. Chem. Soc. – volume: 5 year: 2019 publication-title: Sci. Adv. – volume: 6 start-page: 6506 year: 2014 end-page: 6510 publication-title: Nanoscale – volume: 242 start-page: 186 year: 2019 end-page: 193 publication-title: Appl. Catal. B Environ. – volume: 11 start-page: 872 year: 2018 end-page: 880 publication-title: Energy Environ. Sci. – volume: 56 129 start-page: 2386 2426 year: 2017 2017 end-page: 2389 2429 publication-title: Angew. Chem. Int. Ed. Angew. Chem. |
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Snippet | Transition metal phosphide is regarded as one of the most promising candidates to replace noble‐metal hydrogen evolution reaction (HER) electrocatalysts.... |
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SubjectTerms | Chemistry coral-like structures doping Electrocatalysts Electrochemical analysis Electrochemistry hybrid structures Hydrogen Hydrogen bonds hydrogen evolution reaction (HER) kinetics Hydrogen evolution reactions Hydrogen-based energy Interlayers Metal foams Phosphating (coating) Phosphides Reaction kinetics Transition metals |
Title | Ni2P Interlayer and Mn Doping Synergistically Expedite the Hydrogen Evolution Reaction Kinetics of Co2P |
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