Metal‐Free Cyclocarboamination of ortho‐Formyl Phenylacetylenes with Secondary Amines: Access to 1,3‐Diamino‐1H‐Indenes and 3‐Amino‐1‐Indanones
This work first discloses a new strategy for amine activation to give reactive amine anion by in situ generated iminium cation‐amine anion pair through decomposition of sterically hindered aminals. Utilizing this strategy, a highly regio‐ and chemoselective cyclocarboamination of ortho‐formyl phenyl...
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Published in | Advanced synthesis & catalysis Vol. 361; no. 3; pp. 569 - 577 |
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Main Authors | , , , , , , |
Format | Journal Article |
Language | English |
Published |
WEINHEIM
Wiley
01.02.2019
Wiley Subscription Services, Inc |
Subjects | |
Online Access | Get full text |
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