Designable Al32‐Oxo Clusters with Hydrotalcite‐like Structures: Snapshots of Boundary Hydrolysis and Optical Limiting

• Published in: Angewandte Chemie International Edition Vol. 60; no. 9; pp. 4849 - 4854
• Main Authors: Liu, Ya‐Jie, Li, Qiao‐Hong, Li, De‐Jing, Zhang, Xue‐Zhen, Fang, Wei‐Hui, Zhang, Jian
• Format: Journal Article
• Language: English
• Published: Weinheim Wiley Subscription Services, Inc 23.02.2021
• Edition: International ed. in English
• Subjects: aluminum; Charge distribution; cluster science; Clusters; Constraining; Environmental chemistry; Geochemistry; Hydrolysis; hydrotalcite; Ions; Layered materials; Mimicry; optical limiting

The hydrolysis of earth‐abundant AlIII has implications in mineral mimicry, geochemistry and environmental chemistry. Third‐order nonlinear optical (NLO) materials are important in modern chemistry due to their extensive optical applications. The assembly of AlIII ions with π‐conjugated carboxylate...