Rational Construction of an Exceptionally Stable MOF Catalyst with Metal‐Adeninate Vertices toward CO2 Cycloaddition under Mild and Cocatalyst‐Free Conditions

• Published in: Chemistry : a European journal Vol. 25; no. 49; pp. 11474 - 11480
• Main Authors: He, Hongming, Zhu, Qian‐Qian, Zhao, Jia‐Nan, Sun, Hongming, Chen, Jing, Li, Cheng‐Peng, Du, Miao
• Format: Journal Article
• Language: English
• Published: Weinheim Wiley Subscription Services, Inc 02.09.2019
• Subjects: Apexes; Carbon dioxide; Carbon sequestration; Carbonates; Catalysis; Catalysts; Chemistry; CO2 cycloaddition; Construction materials; Cycloaddition; Epoxides; Greenhouse effect; Greenhouse gases; heterogeneous catalysis; Metal-organic frameworks; microporous materials; Recyclability

CO2 is considered as the primary greenhouse gas, resulting in a series of serious environmental problems that affect people's life and health. Carbon capture and sequestration has been implemented as one of the most appealing pathways to control and use CO2. Here, we rationally integrate variou...