A Facile and Versatile “Click” Approach Toward Multifunctional Ionic Metal–organic Frameworks for Efficient Conversion of CO2

• Published in: ChemSusChem Vol. 12; no. 10; pp. 2202 - 2210
• Main Authors: Zhou, Li‐Jiao, Sun, Wei, Yang, Ning‐Ning, Li, Peng, Gong, Teng, Sun, Weng‐Jie, Sui, Qi, Gao, En‐Qing
• Format: Journal Article
• Language: English
• Published: Weinheim Wiley Subscription Services, Inc 21.05.2019
• Subjects: Alkylation; Alkynes; Anions; Carbon dioxide; Catalysis; Catalysts; Cation exchanging; Chemical synthesis; click chemistry; CO2 fixation; Conversion; Cycloaddition; Halides; heterogeneous catalysis; Metal-organic frameworks; Organic chemistry

Ionic metal–organic frameworks (IMOFs) that integrate synergistic Lewis‐acid sites (intrinsic metal centers of the frameworks) and nucleophilic anions (halides encapsulated within pores) are intriguing platforms for the design of fully heterogeneous catalytic systems for cycloaddition of CO2 to epox...