Microwave‐assisted synthesis of the Fe2O3/g‐C3N4 nanocomposites with enhanced photocatalytic activity for degradation of methylene blue

• Published in: Journal of the Chinese Chemical Society (Taipei) Vol. 67; no. 11; pp. 2032 - 2041
• Main Authors: Karimi, Mohammad Ali, Iliyat, Maryam, Atashkadi, Mojdeh, Ranjbar, Mehdi, Habibi‐Yangjeh, Aziz
• Format: Journal Article
• Language: English
• Published: Weinheim Wiley‐VCH Verlag GmbH & Co. KGaA 01.11.2020; Wiley Subscription Services, Inc
• Subjects: Carbon nitride; Catalytic activity; Chemical reactions; Current carriers; Electron microscopy; Fe2O3/g‐C3N4 nanocomposites; Ferric nitrate; Infrared spectroscopy; iron oxide doping; Iron oxides; Light irradiation; Melamine; Methylene blue; Microscopy; microwave‐assisted synthesis; Nanocomposites; Performance enhancement; Photocatalysis; Photodegradation; Redox reactions; Room temperature; Spectrum analysis; Synthesis; UV–Vis spectroscopy; Weight
• ISSN: 0009-4536; 2192-6549
• DOI: 10.1002/jccs.202000068

The preparation and photocatalytic performance of the Fe2O3/g‐C3N4 nanocomposites with different weight percentage of iron was investigated in this study. Samples were successfully synthesized using melamine and ferric nitrate as the precursors via the green and facile microwave‐assisted method. The physicochemical and structural properties of the Fe2O3‐doped g‐C3N4 were characterized by X‐ray diffraction (XRD), Fourier‐transform infrared spectroscopy (FT‐IR), the Brunauer–Emmett–Teller (BET) method, transmission electron microscopy (TEM), scanning electron microscopy (SEM), energy‐dispersive X‐ray spectroscopy (EDS), and ultraviolet–visible spectroscopy (UV–Vis). The photocatalytic activity of the Fe2O3/g‐C3N4 catalysts was evaluated by the degradation of methylene blue (MB) at room temperature under visible light irradiation. As expected, the as‐synthesized samples exhibited considerable improvement in the photodegradation of MB. The Fe2O3/g‐C3N4 (1.0 wt%) nanocomposite had superior photocatalytic activity, with almost 70% degradation efficiency within 90 min of irradiation. The enhanced performance was ascribed to the separation and migration of the photoinduced electron–hole pairs and taking part of the charge carriers in the chemical redox reactions at the surface of the photocatalyst. In this work, the effect of Fe weight percentage on the degradation potential was also studied, and the photocatalytic mechanism was proposed with the main reactive species •OH. The Fe2O3/g‐C3N4 (1.0 wt.%) nanocomposite exhibited considerable improvement in the photodegradation of MB. The photocatalytic efficiency was approximately 3.9 fold higher than that of the pure g‐C3N4. The •OH radicals were recognized as the main reactive species by the radical trapping experiments.