Synergistic cooperative effect of CF3SO2Na and bis(2-butoxyethyl)ether towards selective oxygenation of sulfides with molecular oxygen under visible-light irradiation

• Published in: Green chemistry : an international journal and green chemistry resource : GC Vol. 23; no. 1; pp. 496 - 500
• Main Authors: Liu, Kai-Jian, Wang, Zheng, Lu, Ling-Hui, Chen, Jin-Yang, Zeng, Fei, Lin, Ying-Wu, Cao, Zhong, Yu, Xianyong, He, Wei-Min
• Format: Journal Article
• Language: English
• Published: CAMBRIDGE Royal Soc Chemistry 07.01.2021; Royal Society of Chemistry
• Subjects: Additives; Ambient temperature; Chemistry; Chemistry, Multidisciplinary; Green & Sustainable Science & Technology; Green chemistry; Irradiation; light; Light irradiation; Oxygen; Oxygenation; Physical Sciences; Radiation; Science & Technology; Science & Technology - Other Topics; solvents; Sulfides; Sulfones; sulfoxides; Transition metals; OXIDATION; QUINOLINE N-OXIDES; SULFOXIDES; ELECTRON-TRANSFER; INDUCED DEOXYGENATIVE C2-SULFONYLATION; AMBIENT; RADICAL CYCLIZATION; SULFONES; QUINOXALIN-2(1H)-ONES; REDUCTIVE MINISCI REACTION

A safe, practical and eco-friendly method for the switchable synthesis of sulfoxides and sulfones through visible-light-initiated oxygenation of sulfides at ambient temperature under transition-metal-, additives-free and minimal solvent conditions. The synergistic catalytic efforts between CF3SO2Na...