Synergistic cooperative effect of CF3SO2Na and bis(2-butoxyethyl)ether towards selective oxygenation of sulfides with molecular oxygen under visible-light irradiation

A safe, practical and eco-friendly method for the switchable synthesis of sulfoxides and sulfones through visible-light-initiated oxygenation of sulfides at ambient temperature under transition-metal-, additives-free and minimal solvent conditions. The synergistic catalytic efforts between CF3SO2Na...

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Published inGreen chemistry : an international journal and green chemistry resource : GC Vol. 23; no. 1; pp. 496 - 500
Main Authors Liu, Kai-Jian, Wang, Zheng, Lu, Ling-Hui, Chen, Jin-Yang, Zeng, Fei, Lin, Ying-Wu, Cao, Zhong, Yu, Xianyong, He, Wei-Min
Format Journal Article
LanguageEnglish
Published CAMBRIDGE Royal Soc Chemistry 07.01.2021
Royal Society of Chemistry
Subjects
Additives
Ambient temperature
Chemistry
Chemistry, Multidisciplinary
Green & Sustainable Science & Technology
Green chemistry
Irradiation
light
Light irradiation
Oxygen
Oxygenation
Physical Sciences
Radiation
Science & Technology
Science & Technology - Other Topics
solvents
Sulfides
Sulfones
sulfoxides
Transition metals
OXIDATION
QUINOLINE N-OXIDES
SULFOXIDES
ELECTRON-TRANSFER
INDUCED DEOXYGENATIVE C2-SULFONYLATION
AMBIENT
RADICAL CYCLIZATION
SULFONES
QUINOXALIN-2(1H)-ONES
REDUCTIVE MINISCI REACTION
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Summary:A safe, practical and eco-friendly method for the switchable synthesis of sulfoxides and sulfones through visible-light-initiated oxygenation of sulfides at ambient temperature under transition-metal-, additives-free and minimal solvent conditions. The synergistic catalytic efforts between CF3SO2Na and 2-butoxyethyl ether represents the key promoting factor for the reaction.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
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ISSN:1463-9262
1463-9270
1463-9270
DOI:10.1039/d0gc02663h