kLa determination: comparative study for a gas mass balance method
The determination of k(L) a by a gas balance method coupled with sulphite oxidation is compared for three kinds of processes (stirred tank, bubble column and fixed-bed column reactors) with a gassing-in and with a classical chemical sulphite oxidation method. The mathematical relations required for...
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| Published in | Bioprocess and biosystems engineering Vol. 25; no. 6; pp. 341 - 348 |
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| Main Authors | , , , |
| Format | Journal Article |
| Language | English |
| Published |
Germany
Springer Nature B.V
01.07.2003
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| Subjects | |
| Online Access | Get full text |
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| Abstract | The determination of k(L) a by a gas balance method coupled with sulphite oxidation is compared for three kinds of processes (stirred tank, bubble column and fixed-bed column reactors) with a gassing-in and with a classical chemical sulphite oxidation method. The mathematical relations required for the determination of the k(L) a value are detailed. In coalescing gas-liquid conditions, the values calculated by the three methods are shown to be comparable. The gas balance method is more rapid than either the steady-state gassing-in or the chemical sulphite reaction rate measurement methods. It is also well adapted for three-phase systems (gas-liquid-solid) in which the non-coalescing effects of sulphite solution are reduced by solid interferences. |
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| AbstractList | The determination of k(L) a by a gas balance method coupled with sulphite oxidation is compared for three kinds of processes (stirred tank, bubble column and fixed-bed column reactors) with a gassing-in and with a classical chemical sulphite oxidation method. The mathematical relations required for the determination of the k(L) a value are detailed. In coalescing gas-liquid conditions, the values calculated by the three methods are shown to be comparable. The gas balance method is more rapid than either the steady-state gassing-in or the chemical sulphite reaction rate measurement methods. It is also well adapted for three-phase systems (gas-liquid-solid) in which the non-coalescing effects of sulphite solution are reduced by solid interferences. The determination of k^sub L^ a by a gas balance method coupled with sulphite oxidation is compared for three kinds of processes (stirred tank, bubble column and fixed-bed column reactors) with a gassing-in and with a classical chemical sulphite oxidation method. The mathematical relations required for the determination of the k^sub L^ a value are detailed. In coalescing gas-liquid conditions, the values calculated by the three methods are shown to be comparable. The gas balance method is more rapid than either the steady-state gassing-in or the chemical sulphite reaction rate measurement methods. It is also well adapted for three-phase systems (gas-liquid-solid) in which the non-coalescing effects of sulphite solution are reduced by solid interferences.[PUBLICATION ABSTRACT] |
| Author | Duchez, D Dussap, C G Poughon, L Cornet, J F |
| Author_xml | – sequence: 1 givenname: L surname: Poughon fullname: Poughon, L email: laurent.poughon@univ-bpclermont.fr organization: Laboratoire de Génie Chimique et Biochimique, Université Blaise Pascal, CUST, 24 avenue des Landais, BP 206, 63174 Aubière-Cédex, France. laurent.poughon@univ-bpclermont.fr – sequence: 2 givenname: D surname: Duchez fullname: Duchez, D – sequence: 3 givenname: J F surname: Cornet fullname: Cornet, J F – sequence: 4 givenname: C G surname: Dussap fullname: Dussap, C G |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/13680342$$D View this record in MEDLINE/PubMed |
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| DOI | 10.1007/s00449-003-0321-5 |
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| Snippet | The determination of k(L) a by a gas balance method coupled with sulphite oxidation is compared for three kinds of processes (stirred tank, bubble column and... The determination of k^sub L^ a by a gas balance method coupled with sulphite oxidation is compared for three kinds of processes (stirred tank, bubble column... |
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| SubjectTerms | Comparative studies Gases Oxidation |
| Title | kLa determination: comparative study for a gas mass balance method |
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