Effect of NaCl on the excess enthalpies of binary liquid systems

The excess molar enthalpies hE1+23 of ethanol+(water+NaCl), benzylalcohol+(water+NaCl), and cyclohexane+(methanol+NaCl) were measured at 298.15K, those of methanol+(water+NaCl) at 298.15 and 323.15K. An LKB flow microcalorimeter was used and a special flow-mix cell was developed with regard to the c...

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Published inThermochimica acta Vol. 310; no. 1-2; pp. 87 - 94
Main Authors Friese, T, Schulz, S, Ulbig, P, Wagner, K
Format Journal Article Conference Proceeding
LanguageEnglish
Published Amsterdam Elsevier B.V 27.02.1998
Elsevier Science
Subjects
Alcohol
Chemical thermodynamics
Chemistry
Cyclohexane
Exact sciences and technology
Excess enthalpies
Flow calorimetry
General and physical chemistry
Mixtures
Sodium chloride
Thermodynamic properties
Water
Water
Alcohol
Flow calorimetry
Excess enthalpies
Sodium chloride
Cyclohexane
Ternary system
Salt effect
Ethanol
Hydrocarbon
Calorimetry
Experimental study
Organic compounds
Methanol
Sodium Chlorides
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Abstract The excess molar enthalpies hE1+23 of ethanol+(water+NaCl), benzylalcohol+(water+NaCl), and cyclohexane+(methanol+NaCl) were measured at 298.15K, those of methanol+(water+NaCl) at 298.15 and 323.15K. An LKB flow microcalorimeter was used and a special flow-mix cell was developed with regard to the corrosive electrolyte solutions. Knowing the integral enthalpy of solution and the solution enthalpy at infinite dilution for a salt (3) in a solvent (2), the molar excess enthalpy hE123 can be calculated.
AbstractList The excess molar enthalpies hE1+23 of ethanol+(water+NaCl), benzylalcohol+(water+NaCl), and cyclohexane+(methanol+NaCl) were measured at 298.15K, those of methanol+(water+NaCl) at 298.15 and 323.15K. An LKB flow microcalorimeter was used and a special flow-mix cell was developed with regard to the corrosive electrolyte solutions. Knowing the integral enthalpy of solution and the solution enthalpy at infinite dilution for a salt (3) in a solvent (2), the molar excess enthalpy hE123 can be calculated.
Author Friese, T
Schulz, S
Ulbig, P
Wagner, K
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Issue 1-2
Keywords Water
Alcohol
Flow calorimetry
Excess enthalpies
Sodium chloride
Cyclohexane
Ternary system
Salt effect
Ethanol
Hydrocarbon
Calorimetry
Experimental study
Organic compounds
Methanol
Sodium Chlorides
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References Eckfeldt, Lucasse (BIB13) 1943; 21
Rajendran, Renganarayanan, Madhavan, Srinivasan (BIB4) 1988; 74
Achard, Dussap, Gros (BIB1) 1994; 98
K. Wagner, T. Friese, S. Schulz, P. Ulbig, submitted for publication to J. Chem. Eng. Data
B. Löwen, PhD Thesis, Universität Dortmund, Verlag Shaker Aachen (1995)
Rajendran, Renganarayanan, Srinivasan (BIB5) 1991; 70
Stephenson, Stuart (BIB11) 1986; 31
G.C. Benson, E. Zhao, B.C.-Y. Lu, J. Chem. Eng. Data 40 (1995) 665
Rajendran, Srinivasan (BIB6) 1994; 128
Clarke, Glew (BIB7) 1985; 14
Achard, Dussap, Gros (BIB2) 1994; 40
J.M. Sørensen, W. Arlt, Dechema Data Series 5 (1979)
Boyne, Williamson (BIB8) 1967; 12
References_xml – volume: 31
  start-page: 56
  year: 1986
  ident: BIB11
  publication-title: J. Chem. Eng. Data
  contributor:
    fullname: Stuart
– volume: 98
  start-page: 71
  year: 1994
  ident: BIB1
  publication-title: Fluid Phase Equilibria
  contributor:
    fullname: Gros
– volume: 14
  start-page: 489
  year: 1985
  ident: BIB7
  publication-title: J. Phys. Chem. Ref. Data
  contributor:
    fullname: Glew
– volume: 12
  start-page: 318
  year: 1967
  ident: BIB8
  publication-title: J. Chem. Eng. Data
  contributor:
    fullname: Williamson
– volume: 74
  start-page: 179
  year: 1988
  ident: BIB4
  publication-title: Chem. Eng. Comm.
  contributor:
    fullname: Srinivasan
– volume: 40
  start-page: 1210
  year: 1994
  ident: BIB2
  publication-title: AIChE Journal
  contributor:
    fullname: Gros
– volume: 128
  start-page: 109
  year: 1994
  end-page: 117
  ident: BIB6
  publication-title: Chem. Eng. Comm.
  contributor:
    fullname: Srinivasan
– volume: 21
  start-page: 164
  year: 1943
  ident: BIB13
  publication-title: J. Phys. Chem.
  contributor:
    fullname: Lucasse
– volume: 70
  start-page: 65
  year: 1991
  end-page: 106
  ident: BIB5
  publication-title: Fluid Phase Equilibria
  contributor:
    fullname: Srinivasan
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Snippet The excess molar enthalpies hE1+23 of ethanol+(water+NaCl), benzylalcohol+(water+NaCl), and cyclohexane+(methanol+NaCl) were measured at 298.15K, those of...
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StartPage 87
SubjectTerms Alcohol
Chemical thermodynamics
Chemistry
Cyclohexane
Exact sciences and technology
Excess enthalpies
Flow calorimetry
General and physical chemistry
Mixtures
Sodium chloride
Thermodynamic properties
Water
Title Effect of NaCl on the excess enthalpies of binary liquid systems
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Volume 310
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