An investigation of the dissociation of complexes of triethylene tetramine with first-row transition-metal dications by electrospray ionization tandem mass spectrometry: Remote C C bond activation

• Published in: International journal of mass spectrometry Vol. 267; no. 1; pp. 256 - 262
• Main Authors: Anichina, Janna, Bohme, Diethard K.
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 01.11.2007
• Subjects: C [sbnd]C bond activation; Collision-induced dissociation (CID); Electrospray ionization; Transition-metal dications; Triethylene tetramine; Triethylene tetramine; C C bond activation; Collision-induced dissociation (CID); Transition-metal dications; Electrospray ionization

Electrospray ionization mass spectrometry is employed to probe the complexation and dissociation of the first-row transition-metal dications with triethylene tetramine that originate in water/methanol solutions of the corresponding metal salts and the ligand. The major complex ions emerging from the...