Structural and magnetic properties of Fe2P-type R6TTe2 compounds (R = Tb, Dy, Ho, Er, T = Fe, Co, Ru): Magnetic properties and specific features of magnetic entropy change
The magnetic properties and magnetic entropy changes of the Fe2P-type Ho6FeTe2, Ho6CoTe2, Er6CoTe2, Tb6RuTe2, Dy6RuTe2 and Ho6RuTe2 (space group P-62m, N 189, hP9) have been studied by means of bulk magnetization and heat capacity measurements. Also, the tentative magnetic entropy change ΔSm* = (∂M...
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Published in | Journal of solid state chemistry Vol. 258; pp. 201 - 211 |
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Abstract | The magnetic properties and magnetic entropy changes of the Fe2P-type Ho6FeTe2, Ho6CoTe2, Er6CoTe2, Tb6RuTe2, Dy6RuTe2 and Ho6RuTe2 (space group P-62m, N 189, hP9) have been studied by means of bulk magnetization and heat capacity measurements. Also, the tentative magnetic entropy change ΔSm* = (∂M / ∂T) × H was used for characterization of magnetic ordering.
Ho6FeTe2, Ho6CoTe2, Er6CoTe2, Tb6RuTe2, Dy6RuTe2 and Ho6RuTe2 exhibit complex field sensitive ferro-antiferromagnetic ordering. The correlation between the isothermal magnetic entropy change and the magnetic ordering of these compounds have been studied.
The magnetic properties and magnetic entropy changes of the Fe2P-type Ho6FeTe2, Ho6CoTe2, Er6CoTe2, Tb6RuTe2, Dy6RuTe2 and Ho6RuTe2 (space group P-62m, N 189, hP9) have been studied by means of bulk magnetization and heat capacity measurements. Also, tentative magnetic entropy change ΔSm* = (∂M / ∂T) × H was used for characterization of magnetic ordering. Ho6FeTe2, Ho6CoTe2, Er6CoTe2, Tb6RuTe2, Dy6RuTe2 and Ho6RuTe2 exhibit complex field sensitive ferro-antiferromagnetic ordering. The correlationship of magnetic entropy change with magnetic ordering of these compounds was investigated and discussed. [Display omitted]
•The bulk magnetization and heat capacity used for {Ho, Er}6CoTe2 and {Tb, Dy, Ho}6RuTe.•The tentative magnetic entropy change ΔSm* = (∂M / ∂T) × H used for magnetic ordering.•This permits to establish magnetic ordering in width interval of magnetic field.•{Ho, Er}6CoTe2 and {Tb, Dy, Ho}6RuTe exhibit field sensitive F-AF ordering. |
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AbstractList | The magnetic properties and magnetic entropy changes of the Fe2P-type Ho6FeTe2, Ho6CoTe2, Er6CoTe2, Tb6RuTe2, Dy6RuTe2 and Ho6RuTe2 (space group P-62m, N 189, hP9) have been studied by means of bulk magnetization and heat capacity measurements. Also, the tentative magnetic entropy change ΔSm* = (∂M / ∂T) × H was used for characterization of magnetic ordering.
Ho6FeTe2, Ho6CoTe2, Er6CoTe2, Tb6RuTe2, Dy6RuTe2 and Ho6RuTe2 exhibit complex field sensitive ferro-antiferromagnetic ordering. The correlation between the isothermal magnetic entropy change and the magnetic ordering of these compounds have been studied.
The magnetic properties and magnetic entropy changes of the Fe2P-type Ho6FeTe2, Ho6CoTe2, Er6CoTe2, Tb6RuTe2, Dy6RuTe2 and Ho6RuTe2 (space group P-62m, N 189, hP9) have been studied by means of bulk magnetization and heat capacity measurements. Also, tentative magnetic entropy change ΔSm* = (∂M / ∂T) × H was used for characterization of magnetic ordering. Ho6FeTe2, Ho6CoTe2, Er6CoTe2, Tb6RuTe2, Dy6RuTe2 and Ho6RuTe2 exhibit complex field sensitive ferro-antiferromagnetic ordering. The correlationship of magnetic entropy change with magnetic ordering of these compounds was investigated and discussed. [Display omitted]
•The bulk magnetization and heat capacity used for {Ho, Er}6CoTe2 and {Tb, Dy, Ho}6RuTe.•The tentative magnetic entropy change ΔSm* = (∂M / ∂T) × H used for magnetic ordering.•This permits to establish magnetic ordering in width interval of magnetic field.•{Ho, Er}6CoTe2 and {Tb, Dy, Ho}6RuTe exhibit field sensitive F-AF ordering. |
Author | Yapaskurt, V.O. Yao, Jinlei Genchel, V.K. Knotko, A.V. Morozkin, A.V. Quezado, S. Malik, S.K. |
Author_xml | – sequence: 1 givenname: A.V. surname: Morozkin fullname: Morozkin, A.V. email: morozkin@tech.chem.msu.ru organization: Department of Chemistry, Moscow State University, Leninskie Gory, House 1, Building 3, GSP-2, Moscow 119992, Russia – sequence: 2 givenname: V.K. surname: Genchel fullname: Genchel, V.K. organization: Department of Chemistry, Moscow State University, Leninskie Gory, House 1, Building 3, GSP-2, Moscow 119992, Russia – sequence: 3 givenname: A.V. surname: Knotko fullname: Knotko, A.V. organization: Department of Chemistry, Moscow State University, Leninskie Gory, House 1, Building 3, GSP-2, Moscow 119992, Russia – sequence: 4 givenname: V.O. surname: Yapaskurt fullname: Yapaskurt, V.O. organization: Department of Petrology, Geological Faculty Moscow State University, Leninskie Gory, Moscow 119992, Russia – sequence: 5 givenname: Jinlei surname: Yao fullname: Yao, Jinlei organization: Jiangsu Key Laboratory of Micro and Nano Heat Fluid Flow Technology and Energy Application, School of Mathematics and Physics, Suzhou University of Science and Technology, Suzhou 215009, China – sequence: 6 givenname: S. surname: Quezado fullname: Quezado, S. organization: Departamento de Física, Universidade Federal do Rio Grande do Norte, Natal 59082-970, Brazil – sequence: 7 givenname: S.K. surname: Malik fullname: Malik, S.K. organization: Departamento de Física, Universidade Federal do Rio Grande do Norte, Natal 59082-970, Brazil |
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Snippet | The magnetic properties and magnetic entropy changes of the Fe2P-type Ho6FeTe2, Ho6CoTe2, Er6CoTe2, Tb6RuTe2, Dy6RuTe2 and Ho6RuTe2 (space group P-62m, N 189,... |
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SubjectTerms | Heat capacity Magnetic entropy change Magnetic properties Magnetocaloric effect Rare earth compounds |
Title | Structural and magnetic properties of Fe2P-type R6TTe2 compounds (R = Tb, Dy, Ho, Er, T = Fe, Co, Ru): Magnetic properties and specific features of magnetic entropy change |
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