Chemistry of the μ-hydridobis(pentacarbonylchromium(0)) species: I. The addition reactions of its salts with N-donor bidentate ligands

• Published in: Journal of organometallic chemistry Vol. 140; no. 2; pp. 161 - 168
• Main Authors: Grillone, M.D, Kedzia, B.B
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 01.11.1977

Reactions of the potassium and tetrabutylammonium derivatives of Cr 2H(CO) 10 −, with N-donor bidentate ligands such as 1,10-phenanthroline (phen) and 2,2′-bipyridine (bpy) have been investigated. A coordination compound of general formula K[Cr 2H(CO) 10(phen) 3] is the most stable product from the...