Compounds of molybdenum and tungsten with high specific surface area: I. Nitrides

Temperature-programmed reaction between MoO 3 or WO 3 with NH 3 provides a new way to prepare Mo 2N and W 2N powders with specific surface areas as high as 220 and 91 m 2 g −1, respectively, corresponding to 3- to 4-nm crystallites. The transformation of MoO 3 platelets is topotactic in the sense th...

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Published inJournal of solid state chemistry Vol. 59; no. 3; pp. 332 - 347
Main Authors Volpe, Leo, Boudart, M.
Format Journal Article
LanguageEnglish
Published Elsevier Inc 1985
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Abstract Temperature-programmed reaction between MoO 3 or WO 3 with NH 3 provides a new way to prepare Mo 2N and W 2N powders with specific surface areas as high as 220 and 91 m 2 g −1, respectively, corresponding to 3- to 4-nm crystallites. The transformation of MoO 3 platelets is topotactic in the sense that {100} planes of Mo 2N are parallel to {010} planes of MoO 3. As the MoO 3 reacts with NH 3, it passes through an oxynitride intermediate with changing bulk structure, increasing surface area, and decreasing oxidation state of the metal. The product consists of highly porous nitride platelets, pseudomorphous with the original MoO 3.
AbstractList Temperature-programmed reaction between MoO 3 or WO 3 with NH 3 provides a new way to prepare Mo 2N and W 2N powders with specific surface areas as high as 220 and 91 m 2 g −1, respectively, corresponding to 3- to 4-nm crystallites. The transformation of MoO 3 platelets is topotactic in the sense that {100} planes of Mo 2N are parallel to {010} planes of MoO 3. As the MoO 3 reacts with NH 3, it passes through an oxynitride intermediate with changing bulk structure, increasing surface area, and decreasing oxidation state of the metal. The product consists of highly porous nitride platelets, pseudomorphous with the original MoO 3.
Author Volpe, Leo
Boudart, M.
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Snippet Temperature-programmed reaction between MoO 3 or WO 3 with NH 3 provides a new way to prepare Mo 2N and W 2N powders with specific surface areas as high as 220...
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Title Compounds of molybdenum and tungsten with high specific surface area: I. Nitrides
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