5-Chloro-N-{4-oxo-2-[4-(trifluoro-meth-yl)phen-yl]-1,3-thia-zolidin-3-yl}-3-phenyl-1H-indole-2-carboxamide

• Published in: Acta crystallographica. Section E, Structure reports online Vol. 68; no. Pt 10; pp. o2969 - o2970
• Main Authors: Akkurt, Mehmet, Celik, Ismail, Gürbüzel, Füsun Kazan, Ozkırımlı, Sumru, Büyükgüngör, Orhan
• Format: Journal Article
• Language: English
• Published: United States International Union of Crystallography 01.10.2012
• Subjects: Organic Papers
• ISSN: 1600-5368; 1600-5368
• DOI: 10.1107/S1600536812039347

In the title compound, C(25)H(17)ClF(3)N(3)O(2)S, the five-membered 1,3-thia-zolidine ring adopts a twist conformation. The three F atoms of the CF(3) group are disordered over two sets of sites with refined occupancies of 0.542 (18) and 0.458 (18). In the nine-membered 1H-indoline ring system, the 1H-pyrrole ring forms a dihedral angle of 4.7 (2)° with the benzene ring, while it is twisted at an angle of 46.5 (2)° with respect to the attached phenyl ring. The dihedral angle between the phenyl and trifluoro-methyl-substituted benzene rings is 56.0 (2)°. In the crystal, N-H⋯O hydrogen bonds connect the mol-ecules into a three-dimensional network. In addition, weak C-H⋯O hydrogen bonds and weak C-H⋯π inter-actions are observed.