Synthesis, Characterization, X-Ray Crystal Structures and Antibacterial Activity of Zinc(II) and Vanadium(V) Complexes Derived from 5-Bromo-2-((2-(methylamino)ethylimino)methyl)phenol
Three new zinc(II) and one vanadium(V) complexes, [Zn2Cl2L2] (1), [Zn2I2L2] (2), [ZnCl2(HL)] (3), and [V2O2(μ-O)2L2] (4), where L is 5-bromo-2-((2-(methylamino)ethylimino)methyl)phenolate, have been synthesized and characterized by elemental analyses, IR and UV-Vis spectra, as well as molar conducti...
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Published in | Acta chimica Slovenica Vol. 69; no. 1; pp. 157 - 166 |
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Main Author | |
Format | Journal Article |
Language | English |
Published |
Slovenia
Slovenian Chemical Society
15.03.2022
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Subjects | |
Online Access | Get full text |
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Summary: | Three new zinc(II) and one vanadium(V) complexes, [Zn2Cl2L2] (1), [Zn2I2L2] (2), [ZnCl2(HL)] (3), and [V2O2(μ-O)2L2] (4), where L is 5-bromo-2-((2-(methylamino)ethylimino)methyl)phenolate, have been synthesized and characterized by elemental analyses, IR and UV-Vis spectra, as well as molar conductivity. Structures of the complexes were confirmed by single crystal X-ray diffraction. Complexes 1 and 2 are isostructural dinuclear zinc compounds, with the Zn atoms in square pyramidal coordination. The Zn atoms in the mononuclear complex 3 are in tetrahedral coordination. Complex 4 is a dinuclear vanadium(V) compound, with the V atoms in octahedral coordination. The complexes were assayed for antibacterial activities by MTT method. |
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Bibliography: | ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23 |
ISSN: | 1318-0207 1580-3155 |
DOI: | 10.17344/acsi.2021.7167 |