Mechanochemically prepared SrFCl nanophosphor co-doped with Yb 3+ and Er 3+ for detecting ionizing radiation by upconversion luminescence

• Published in: Nanoscale Vol. 9; no. 41; pp. 15958 - 15966
• Main Authors: Zhang, Jun, Riesen, Nicolas, Riesen, Hans
• Format: Journal Article
• Language: English
• Published: England 26.10.2017
• ISSN: 2040-3364; 2040-3372
• DOI: 10.1039/C7NR05108E

We report a novel method for detecting ionizing radiation by employing the phenomenon of upconversion luminescence. Nanocrystalline SrFCl:Yb 3+ /Er 3+ was prepared by ball-milling and characterized by powder X-ray diffraction (XRD), transmission electron microscopy (TEM), and X-ray photoelectron spectroscopy (XPS). The photoluminescence properties of nanocrystalline SrFCl:Yb 3+ , SrFCl:Er 3+ and SrFCl:Yb 3+ /Er 3+ before and after X-irradiation were investigated. The results demonstrate that both Yb 3+ and Er 3+ ions in the SrFCl host are reduced to their divalent state upon X-ray exposure. Under 980 nm infrared excitation, SrFCl:Yb 3+ /Er 3+ nanocrystals displayed efficient upconversion luminescence. The upconversion luminescence intensity gradually decreased with increasing X-irradiation in a double exponential fashion with rate constants of k 1 = 0.08 Gy −1 and k 2 = 0.01 Gy −1 . In comparison with other X-ray storage phosphors, the present system shows a much higher stability of stored information since it is not subject to photobleaching in the read-out process. This is the first report on detecting ionizing radiation by upconversion luminescence, with the potential for improved read-out performance over traditional storage phosphors. Possible applications of the present phosphor include bioimaging and in vivo cell-level X-ray dose monitoring.