Photocatalytic alkene reduction by a B 12 -TiO 2 hybrid catalyst coupled with C-F bond cleavage for gem-difluoroolefin synthesis
Photocatalytic syntheses of gem-difluoroolefins were performed using the B -TiO hybrid catalyst during the C[double bond, length as m-dash]C bond reduction of α-trifluoromethyl styrenes with C-F bond cleavage at room temperature under nitrogen. The gem-difluoroolefins were used as synthetic precurso...
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| Published in | Chemical communications (Cambridge, England) Vol. 53; no. 68; pp. 9478 - 9481 |
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| Main Authors | , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
England
22.08.2017
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| Abstract | Photocatalytic syntheses of gem-difluoroolefins were performed using the B
-TiO
hybrid catalyst during the C[double bond, length as m-dash]C bond reduction of α-trifluoromethyl styrenes with C-F bond cleavage at room temperature under nitrogen. The gem-difluoroolefins were used as synthetic precursors for fluorinated cyclopropanes. |
|---|---|
| AbstractList | Photocatalytic syntheses of
gem
-difluoroolefins were performed using the B
12
–TiO
2
hybrid catalyst during the CC bond reduction of α-trifluoromethyl styrenes with C–F bond cleavage at room temperature under nitrogen. The
gem
-difluoroolefins were used as synthetic precursors for fluorinated cyclopropanes. Photocatalytic syntheses of gem-difluoroolefins were performed using the B -TiO hybrid catalyst during the C[double bond, length as m-dash]C bond reduction of α-trifluoromethyl styrenes with C-F bond cleavage at room temperature under nitrogen. The gem-difluoroolefins were used as synthetic precursors for fluorinated cyclopropanes. |
| Author | Imamura, Kenji Yoshizawa, Kazunari Tian, Hui Shimakoshi, Hisashi Shiota, Yoshihito Hisaeda, Yoshio |
| Author_xml | – sequence: 1 givenname: Hui surname: Tian fullname: Tian, Hui email: shimakoshi@mail.cstm.kyushu-u.ac.jp, yhisatcm@mail.cstm.kyushu-u.ac.jp organization: Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University, Nishi-ku, Motooka, Fukuoka 744, 819-0395, Japan. shimakoshi@mail.cstm.kyushu-u.ac.jp yhisatcm@mail.cstm.kyushu-u.ac.jp – sequence: 2 givenname: Hisashi surname: Shimakoshi fullname: Shimakoshi, Hisashi – sequence: 3 givenname: Kenji surname: Imamura fullname: Imamura, Kenji – sequence: 4 givenname: Yoshihito surname: Shiota fullname: Shiota, Yoshihito – sequence: 5 givenname: Kazunari surname: Yoshizawa fullname: Yoshizawa, Kazunari – sequence: 6 givenname: Yoshio surname: Hisaeda fullname: Hisaeda, Yoshio |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/28795706$$D View this record in MEDLINE/PubMed |
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-TiO
hybrid catalyst during the C[double bond, length as m-dash]C bond reduction of... Photocatalytic syntheses of gem -difluoroolefins were performed using the B 12 –TiO 2 hybrid catalyst during the CC bond reduction of α-trifluoromethyl... |
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