An in situ derived MOF@In 2 S 3 heterojunction stabilizes Co( ii )-salicylaldimine for efficient photocatalytic formic acid dehydrogenation
We report here the hierarchical construction of a molecular Co( ii )-salicylaldimine catalyst and an in situ derived In 2 S 3 semiconductor in a MOF@In 2 S 3 heterojunction through sequentially controllable in situ etching and post-synthetic modification for photocatalytic hydrogen production from f...
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| Published in | Chemical communications (Cambridge, England) Vol. 58; no. 51; pp. 7140 - 7143 |
|---|---|
| Main Authors | , , , , |
| Format | Journal Article |
| Language | English |
| Published |
England
23.06.2022
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| Online Access | Get full text |
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| Abstract | We report here the hierarchical construction of a molecular Co(
ii
)-salicylaldimine catalyst and an
in situ
derived In
2
S
3
semiconductor in a MOF@In
2
S
3
heterojunction through sequentially controllable
in situ
etching and post-synthetic modification for photocatalytic hydrogen production from formic acid. The enhanced catalyst stability and facilitated charge carrier mobility between the In
2
S
3
photosensitizers and Co catalyst realize a superior H
2
production rate of 18 746 μmol g
−1
h
−1
(selectivity > 99.9%) with a turnover number (TON) of up to 6146 in 24 h (apparent quantum efficiency of 3.8% at 420 nm), indicating a 165-fold enhancement over that of the pristine MOF. This work highlights a powerful strategy for synergistic Earth-abundant metal-based MOF photocatalysis in promoting H
2
production from FA. |
|---|---|
| AbstractList | We report here the hierarchical construction of a molecular Co(II)-salicylaldimine catalyst and an
derived In
S
semiconductor in a MOF@In
S
heterojunction through sequentially controllable
etching and post-synthetic modification for photocatalytic hydrogen production from formic acid. The enhanced catalyst stability and facilitated charge carrier mobility between the In
S
photosensitizers and Co catalyst realize a superior H
production rate of 18 746 μmol g
h
(selectivity > 99.9%) with a turnover number (TON) of up to 6146 in 24 h (apparent quantum efficiency of 3.8% at 420 nm), indicating a 165-fold enhancement over that of the pristine MOF. This work highlights a powerful strategy for synergistic Earth-abundant metal-based MOF photocatalysis in promoting H
production from FA. We report here the hierarchical construction of a molecular Co( ii )-salicylaldimine catalyst and an in situ derived In 2 S 3 semiconductor in a MOF@In 2 S 3 heterojunction through sequentially controllable in situ etching and post-synthetic modification for photocatalytic hydrogen production from formic acid. The enhanced catalyst stability and facilitated charge carrier mobility between the In 2 S 3 photosensitizers and Co catalyst realize a superior H 2 production rate of 18 746 μmol g −1 h −1 (selectivity > 99.9%) with a turnover number (TON) of up to 6146 in 24 h (apparent quantum efficiency of 3.8% at 420 nm), indicating a 165-fold enhancement over that of the pristine MOF. This work highlights a powerful strategy for synergistic Earth-abundant metal-based MOF photocatalysis in promoting H 2 production from FA. |
| Author | Ma, Liang Lin, Wenting Zhang, Meijin Pi, Yunhong Wang, Tiejun |
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| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/35666225$$D View this record in MEDLINE/PubMed |
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| Snippet | We report here the hierarchical construction of a molecular Co(
ii
)-salicylaldimine catalyst and an
in situ
derived In
2
S
3
semiconductor in a MOF@In
2
S
3... We report here the hierarchical construction of a molecular Co(II)-salicylaldimine catalyst and an derived In S semiconductor in a MOF@In S heterojunction... |
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| Title | An in situ derived MOF@In 2 S 3 heterojunction stabilizes Co( ii )-salicylaldimine for efficient photocatalytic formic acid dehydrogenation |
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