Fabrication and characterization of CH 3 NH 3 PbI 3 solar cells with added guanidinium and inserted with decaphenylpentasilane
Abstract In this work we investigated the effects of the addition of guanidinium [C(NH 2 ) 3 ; GA] on CH 3 NH 3 PbI 3 perovskite solar cells fabricated at a high temperature of 190°C in atmospheric air. The addition of GA iodide and the insertion of decaphenylpentasilane between the perovskite and h...
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Published in | Japanese Journal of Applied Physics Vol. 61; no. SB; p. SB1024 |
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Main Authors | , , , , , , , |
Format | Journal Article |
Language | English |
Published |
01.02.2022
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Abstract | Abstract
In this work we investigated the effects of the addition of guanidinium [C(NH
2
)
3
; GA] on CH
3
NH
3
PbI
3
perovskite solar cells fabricated at a high temperature of 190°C in atmospheric air. The addition of GA iodide and the insertion of decaphenylpentasilane between the perovskite and hole transport layer improved the external quantum efficiency and short-circuit current density, and the conversion efficiencies were stable after 1 month. X-ray diffraction showed that the lattice constant of the perovskite crystals was increased by the addition of GA, and addition of GA also improved the surface morphology. First-principles calculations on the density of states and band structures showed reduction of the total energy by the addition of GA and the effectiveness of the nitrogen atoms in GA. |
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AbstractList | Abstract
In this work we investigated the effects of the addition of guanidinium [C(NH
2
)
3
; GA] on CH
3
NH
3
PbI
3
perovskite solar cells fabricated at a high temperature of 190°C in atmospheric air. The addition of GA iodide and the insertion of decaphenylpentasilane between the perovskite and hole transport layer improved the external quantum efficiency and short-circuit current density, and the conversion efficiencies were stable after 1 month. X-ray diffraction showed that the lattice constant of the perovskite crystals was increased by the addition of GA, and addition of GA also improved the surface morphology. First-principles calculations on the density of states and band structures showed reduction of the total energy by the addition of GA and the effectiveness of the nitrogen atoms in GA. |
Author | Tachikawa, Tomoharu Oku, Takeo Suzuki, Atsushi Asakawa, Yugo Fukunishi, Sakiko Terada, Shuhei Okita, Masanobu Ono, Iori |
Author_xml | – sequence: 1 givenname: Iori surname: Ono fullname: Ono, Iori – sequence: 2 givenname: Takeo orcidid: 0000-0003-2290-1216 surname: Oku fullname: Oku, Takeo – sequence: 3 givenname: Atsushi surname: Suzuki fullname: Suzuki, Atsushi – sequence: 4 givenname: Yugo surname: Asakawa fullname: Asakawa, Yugo – sequence: 5 givenname: Shuhei surname: Terada fullname: Terada, Shuhei – sequence: 6 givenname: Masanobu surname: Okita fullname: Okita, Masanobu – sequence: 7 givenname: Sakiko surname: Fukunishi fullname: Fukunishi, Sakiko – sequence: 8 givenname: Tomoharu surname: Tachikawa fullname: Tachikawa, Tomoharu |
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CitedBy_id | crossref_primary_10_1016_j_nwnano_2024_100030 crossref_primary_10_1016_j_hybadv_2024_100174 crossref_primary_10_1007_s10854_023_10001_z crossref_primary_10_1016_j_oceram_2023_100476 crossref_primary_10_35848_1347_4065_acbec0 crossref_primary_10_1016_j_mtcomm_2023_107623 crossref_primary_10_35848_1347_4065_accaef crossref_primary_10_3390_app12031710 crossref_primary_10_3390_photonics9110791 crossref_primary_10_3390_technologies10060112 crossref_primary_10_35848_1347_4065_acc6d8 crossref_primary_10_3390_inorganics11070273 crossref_primary_10_1007_s11664_022_09688_3 |
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Snippet | Abstract
In this work we investigated the effects of the addition of guanidinium [C(NH
2
)
3
; GA] on CH
3
NH
3
PbI
3
perovskite solar cells fabricated at a... |
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Title | Fabrication and characterization of CH 3 NH 3 PbI 3 solar cells with added guanidinium and inserted with decaphenylpentasilane |
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