Investigation of the Kinetic Stabilization of a Ce 4+ ‐based MOF by in‐situ Powder X‐ray Diffraction
We herein investigated the synthesis of the Ce 4+ ‐based metal‐organic framework [Ce 6 (μ 3 ‐O) 4 (μ 3 ‐OH) 4 (PZDC) 4 (OH) 4 (H 2 O) 4 ] denoted as Ce‐DUT‐67‐PZDC (where DUT stands for Dresden University of Technology and PZDC 2– stands for 3,5‐pyrazoledicarboxylate) by in‐situ powder X‐ray diffrac...
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| Published in | Zeitschrift für anorganische und allgemeine Chemie (1950) Vol. 644; no. 24; pp. 1826 - 1831 |
|---|---|
| Main Authors | , , |
| Format | Journal Article |
| Language | English |
| Published |
31.12.2018
|
| Online Access | Get full text |
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| Abstract | We herein investigated the synthesis of the Ce
4+
‐based metal‐organic framework [Ce
6
(μ
3
‐O)
4
(μ
3
‐OH)
4
(PZDC)
4
(OH)
4
(H
2
O)
4
] denoted as Ce‐DUT‐67‐PZDC (where DUT stands for Dresden University of Technology and PZDC
2–
stands for 3,5‐pyrazoledicarboxylate) by in‐situ powder X‐ray diffraction methods under solvothermal conditions using synchrotron radiation. It was observed that the obtained MOF is rapidly formed between 120 and 140 °C, but only as an intermediate product in this preparative system. After prolonged reaction times, Ce
4+
is reduced to Ce
3+
and reacting with formic acid from the reaction mixture to form the final product [Ce(O
2
CH)
3
]. During the formation of trivalent cerium formate, the Ce(IV)‐MOF completely re‐dissolves. Based on the composition of the reaction mixture and the recorded data, a plausible reaction mechanism was established. This mechanistic scheme includes a reversible precipitation of the Ce(IV)‐MOF under the given conditions and the reduction of Ce
4+
by formate anions generated via hydrolysis of the solvent dimethylformamide. |
|---|---|
| AbstractList | We herein investigated the synthesis of the Ce
4+
‐based metal‐organic framework [Ce
6
(μ
3
‐O)
4
(μ
3
‐OH)
4
(PZDC)
4
(OH)
4
(H
2
O)
4
] denoted as Ce‐DUT‐67‐PZDC (where DUT stands for Dresden University of Technology and PZDC
2–
stands for 3,5‐pyrazoledicarboxylate) by in‐situ powder X‐ray diffraction methods under solvothermal conditions using synchrotron radiation. It was observed that the obtained MOF is rapidly formed between 120 and 140 °C, but only as an intermediate product in this preparative system. After prolonged reaction times, Ce
4+
is reduced to Ce
3+
and reacting with formic acid from the reaction mixture to form the final product [Ce(O
2
CH)
3
]. During the formation of trivalent cerium formate, the Ce(IV)‐MOF completely re‐dissolves. Based on the composition of the reaction mixture and the recorded data, a plausible reaction mechanism was established. This mechanistic scheme includes a reversible precipitation of the Ce(IV)‐MOF under the given conditions and the reduction of Ce
4+
by formate anions generated via hydrolysis of the solvent dimethylformamide. |
| Author | Waitschat, Steve Reinsch, Helge Heidenreich, Niclas |
| Author_xml | – sequence: 1 givenname: Niclas surname: Heidenreich fullname: Heidenreich, Niclas organization: Institute of Inorganic Chemistry CAU Kiel Max‐Eyth‐ Straße 2 24118 Kiel Germany, Deutsches Elektronen Synchrotron (DESY) Notkestraße 85 22607 Hamburg Germany – sequence: 2 givenname: Steve surname: Waitschat fullname: Waitschat, Steve organization: Institute of Inorganic Chemistry CAU Kiel Max‐Eyth‐ Straße 2 24118 Kiel Germany – sequence: 3 givenname: Helge surname: Reinsch fullname: Reinsch, Helge organization: Institute of Inorganic Chemistry CAU Kiel Max‐Eyth‐ Straße 2 24118 Kiel Germany |
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| CitedBy_id | crossref_primary_10_1002_chem_201905376 crossref_primary_10_1021_acsami_9b12261 crossref_primary_10_1002_zaac_202000459 crossref_primary_10_1002_chem_202005085 crossref_primary_10_1039_D0DT02455D crossref_primary_10_1039_D0CE01223H crossref_primary_10_1021_acsami_0c18899 crossref_primary_10_1016_j_chempr_2021_07_006 crossref_primary_10_1039_C9QI01218D crossref_primary_10_1021_acsami_1c18201 crossref_primary_10_1039_D0DT02813D crossref_primary_10_1002_advs_201901020 crossref_primary_10_1557_s43577_022_00342_1 crossref_primary_10_1016_j_ica_2022_121236 crossref_primary_10_1002_smll_202307236 crossref_primary_10_1039_D0CS00920B crossref_primary_10_1021_acs_analchem_9b05593 crossref_primary_10_1039_D0CS00635A |
| Cites_doi | 10.1002/anie.200905627 10.1021/acs.cgd.6b01512 10.1039/C7CE00094D 10.1039/C7CE01053B 10.1002/chem.201203914 10.1002/anie.201608463 10.1039/C5DT03359D 10.1021/acs.cgd.5b01421 10.1039/C6DT03998G 10.1002/cber.19971300406 10.1021/ja982441c 10.1039/C6DT03852B 10.1111/j.1151-2916.1972.tb11213.x 10.1007/s002690100197 10.1063/1.4999688 10.1107/S1600577515002222 10.1002/anie.201204806 10.1021/ic400999j 10.1021/acs.chemrev.7b00582 10.1016/j.micromeso.2016.09.034 10.1021/acs.cgd.7b01304 10.1039/C7DT04221C 10.1002/anie.201101757 10.1002/anie.201001180 10.1103/PhysRevB.86.125429 10.1080/08957959608201408 10.1039/C5CC02606G 10.1002/chem.201003708 10.1039/C6CC06287C 10.1039/C8CC03121E 10.1021/ic301976s 10.1021/ja8057953 10.1039/C8CE00949J 10.1021/acs.inorgchem.6b02969 10.1002/cphc.201700967 10.1039/C5CS00837A 10.1021/acs.jpcc.6b00644 10.1021/ic502725y 10.1039/C6CE01704E 10.1039/C0CE00530D 10.1039/C4CS00081A 10.1002/chem.201202107 10.1039/C7CC08200B 10.1002/anie.201600896 |
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| References | e_1_2_6_32_1 e_1_2_6_30_1 Reinsch H. (e_1_2_6_17_1) 2016; 27 e_1_2_6_19_1 e_1_2_6_19_2 e_1_2_6_13_1 Wendt M. (e_1_2_6_22_1) 2016; 34 e_1_2_6_36_1 e_1_2_6_11_1 e_1_2_6_34_1 Kaskel S. (e_1_2_6_2_1) 2016 e_1_2_6_15_1 e_1_2_6_38_1 e_1_2_6_20_1 e_1_2_6_41_1 e_1_2_6_9_1 e_1_2_6_5_1 e_1_2_6_7_1 e_1_2_6_24_1 e_1_2_6_3_1 e_1_2_6_22_2 e_1_2_6_28_1 e_1_2_6_26_1 e_1_2_6_10_1 e_1_2_6_31_1 e_1_2_6_14_8 e_1_2_6_14_6 e_1_2_6_14_7 e_1_2_6_14_1 e_1_2_6_35_1 e_1_2_6_12_1 e_1_2_6_14_4 e_1_2_6_14_5 e_1_2_6_18_1 e_1_2_6_39_1 e_1_2_6_14_2 e_1_2_6_14_3 e_1_2_6_16_1 e_1_2_6_37_1 e_1_2_6_42_1 e_1_2_6_21_1 e_1_2_6_40_1 e_1_2_6_8_1 e_1_2_6_4_1 e_1_2_6_6_1 e_1_2_6_25_1 e_1_2_6_23_1 e_1_2_6_29_1 e_1_2_6_27_1 Köppen M. (e_1_2_6_33_1) 2018; 30 |
| References_xml | – ident: e_1_2_6_24_1 doi: 10.1002/anie.200905627 – ident: e_1_2_6_14_3 doi: 10.1021/acs.cgd.6b01512 – volume: 27 start-page: 4490 year: 2016 ident: e_1_2_6_17_1 publication-title: Z. Anorg. Allg. Chem. contributor: fullname: Reinsch H. – ident: e_1_2_6_31_1 doi: 10.1039/C7CE00094D – ident: e_1_2_6_14_7 doi: 10.1039/C7CE01053B – ident: e_1_2_6_12_1 doi: 10.1002/chem.201203914 – ident: e_1_2_6_26_1 doi: 10.1002/anie.201608463 – ident: e_1_2_6_16_1 doi: 10.1039/C5DT03359D – ident: e_1_2_6_19_1 doi: 10.1021/acs.cgd.5b01421 – ident: e_1_2_6_30_1 doi: 10.1039/C6DT03998G – ident: e_1_2_6_4_1 doi: 10.1002/cber.19971300406 – ident: e_1_2_6_20_1 doi: 10.1021/ja982441c – ident: e_1_2_6_14_2 doi: 10.1039/C6DT03852B – ident: e_1_2_6_40_1 doi: 10.1111/j.1151-2916.1972.tb11213.x – ident: e_1_2_6_39_1 doi: 10.1007/s002690100197 – ident: e_1_2_6_37_1 doi: 10.1063/1.4999688 – ident: e_1_2_6_36_1 doi: 10.1107/S1600577515002222 – ident: e_1_2_6_9_1 doi: 10.1002/anie.201204806 – ident: e_1_2_6_35_1 doi: 10.1021/ic400999j – ident: e_1_2_6_23_1 doi: 10.1021/acs.chemrev.7b00582 – ident: e_1_2_6_14_6 doi: 10.1016/j.micromeso.2016.09.034 – ident: e_1_2_6_19_2 doi: 10.1021/acs.cgd.7b01304 – ident: e_1_2_6_27_1 doi: 10.1039/C7DT04221C – ident: e_1_2_6_25_1 doi: 10.1002/anie.201101757 – ident: e_1_2_6_18_1 doi: 10.1002/anie.201001180 – ident: e_1_2_6_10_1 doi: 10.1103/PhysRevB.86.125429 – volume: 34 start-page: 5393 year: 2016 ident: e_1_2_6_22_1 publication-title: Z. Anorg. Allg. Chem. contributor: fullname: Wendt M. – ident: e_1_2_6_41_1 doi: 10.1080/08957959608201408 – ident: e_1_2_6_14_1 doi: 10.1039/C5CC02606G – ident: e_1_2_6_28_1 doi: 10.1002/chem.201003708 – ident: e_1_2_6_34_1 – ident: e_1_2_6_8_1 doi: 10.1039/C6CC06287C – ident: e_1_2_6_13_1 doi: 10.1039/C8CC03121E – ident: e_1_2_6_42_1 – volume: 30 start-page: 3496 year: 2018 ident: e_1_2_6_33_1 publication-title: Z. Anorg. Allg. Chem. contributor: fullname: Köppen M. – ident: e_1_2_6_21_1 doi: 10.1021/ic301976s – ident: e_1_2_6_5_1 doi: 10.1021/ja8057953 – ident: e_1_2_6_7_1 doi: 10.1039/C8CE00949J – ident: e_1_2_6_14_8 doi: 10.1021/acs.inorgchem.6b02969 – ident: e_1_2_6_15_1 doi: 10.1002/cphc.201700967 – ident: e_1_2_6_6_1 doi: 10.1039/C5CS00837A – ident: e_1_2_6_38_1 doi: 10.1021/acs.jpcc.6b00644 – ident: e_1_2_6_11_1 doi: 10.1021/ic502725y – ident: e_1_2_6_14_5 doi: 10.1039/C6CE01704E – ident: e_1_2_6_32_1 doi: 10.1039/C0CE00530D – volume-title: The Chemistry of Metal‐Organic Frameworks Vol. 1&2 year: 2016 ident: e_1_2_6_2_1 contributor: fullname: Kaskel S. – ident: e_1_2_6_3_1 doi: 10.1039/C4CS00081A – ident: e_1_2_6_22_2 doi: 10.1002/chem.201202107 – ident: e_1_2_6_14_4 doi: 10.1039/C7CC08200B – ident: e_1_2_6_29_1 doi: 10.1002/anie.201600896 |
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| Snippet | We herein investigated the synthesis of the Ce
4+
‐based metal‐organic framework [Ce
6
(μ
3
‐O)
4
(μ
3
‐OH)
4
(PZDC)
4
(OH)
4
(H
2
O)
4
] denoted as... |
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| Title | Investigation of the Kinetic Stabilization of a Ce 4+ ‐based MOF by in‐situ Powder X‐ray Diffraction |
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