A Tetranuclear μ 3 ‐Alkoxo‐bridged Cubane‐like Copper(II) Complex Containing 2‐(Ethylamino)ethanol and Acetate: Synthesis and Structural Characterization
Abstract A tetranuclear cubane‐like complex, [Cu 4 (μ‐Etae) 4 (OAc) 4 ]·H 2 O ( 1 ), with 2‐(ethylamino)ethanol (EtaeH) and acetate (OAc) − ligands has been synthesized and characterized by elemental analysis, IR spectroscopy, and single crystal X‐ray diffraction. Complex 1 crystallizes in the ortho...
Saved in:
Published in | Zeitschrift für anorganische und allgemeine Chemie (1950) Vol. 633; no. 2; pp. 351 - 353 |
---|---|
Main Authors | , , |
Format | Journal Article |
Language | English |
Published |
01.02.2007
|
Online Access | Get full text |
Cover
Loading…
Abstract | Abstract
A tetranuclear cubane‐like complex, [Cu
4
(μ‐Etae)
4
(OAc)
4
]·H
2
O (
1
), with 2‐(ethylamino)ethanol (EtaeH) and acetate (OAc)
−
ligands has been synthesized and characterized by elemental analysis, IR spectroscopy, and single crystal X‐ray diffraction. Complex
1
crystallizes in the orthorhombic space group
Pccn
and consists of a tetranuclear [Cu
4
O
4
]
4+
cubane core in which four copper(II) ions are bridged by μ
3
‐alkoxide oxygen atoms of the Etae
−
anion. The amine N atom of Etae
−
, and one of the O atom OAc also coordinate to the copper(II) ions forming a distorted square‐pyramidal geometry with a CuO
4
N chromophore. The Cu···Cu separations with in the [Cu
4
O
4
]
4+
cubane range from 2.905(2) to 3.377(2) Å, and these short Cu–Cu separations are responsible for the anti‐ferromagnetic coupling between the copper centers. The cubane‐like units are linked by N–H···O hydrogen bonds into one‐dimensional supramolecular chains, which are further arranged in a two‐dimensional array by van der Waal's interactions. |
---|---|
AbstractList | Abstract
A tetranuclear cubane‐like complex, [Cu
4
(μ‐Etae)
4
(OAc)
4
]·H
2
O (
1
), with 2‐(ethylamino)ethanol (EtaeH) and acetate (OAc)
−
ligands has been synthesized and characterized by elemental analysis, IR spectroscopy, and single crystal X‐ray diffraction. Complex
1
crystallizes in the orthorhombic space group
Pccn
and consists of a tetranuclear [Cu
4
O
4
]
4+
cubane core in which four copper(II) ions are bridged by μ
3
‐alkoxide oxygen atoms of the Etae
−
anion. The amine N atom of Etae
−
, and one of the O atom OAc also coordinate to the copper(II) ions forming a distorted square‐pyramidal geometry with a CuO
4
N chromophore. The Cu···Cu separations with in the [Cu
4
O
4
]
4+
cubane range from 2.905(2) to 3.377(2) Å, and these short Cu–Cu separations are responsible for the anti‐ferromagnetic coupling between the copper centers. The cubane‐like units are linked by N–H···O hydrogen bonds into one‐dimensional supramolecular chains, which are further arranged in a two‐dimensional array by van der Waal's interactions. |
Author | Kazak, Canan Yilmaz, Veysel T. Kars, Vecdi |
Author_xml | – sequence: 1 givenname: Veysel T. surname: Yilmaz fullname: Yilmaz, Veysel T. – sequence: 2 givenname: Vecdi surname: Kars fullname: Kars, Vecdi – sequence: 3 givenname: Canan surname: Kazak fullname: Kazak, Canan |
BookMark | eNo9kEFOwkAYhScGEwHdup4lLIr_dKYMdUcaVBISF7Bv_k6ndKRMyXRIgJVH8AyewzN4CE9iUePqe3l5eYuvRzq2tpqQWwYjBhDenRDVKAQYA3CAC9JlUcgCLkXcIV0AIYKQM35Fek3zAgAMoqhL3qd0pb1Du1eVRkc_PyinX69v02pTH-o2ZM7ka53TZJ-h1W1RmY2mSb3baTeYz4dt3O4qfWhpPRpr7JqG7Www8-Wxwq2x9VD7Em1dUbQ5nSrt0et7ujxaX-rGND_10ru98nuHFU1KdKi8duaE3tT2mlwWWDX65o99snqYrZKnYPH8OE-mi0BNBAQxxiAngknFxiBkLGLIVD4WUhaoCmC5YmEEKuKCyygLASHkWSskU1IqGSPvk9HvrXJ10zhdpDtntuiOKYP0LDg9C07_BfNv5yp2RA |
CitedBy_id | crossref_primary_10_1002_chem_200701537 crossref_primary_10_1016_j_ccr_2017_06_022 crossref_primary_10_1002_ejic_201301515 crossref_primary_10_1002_zaac_200801321 |
Cites_doi | 10.1039/cc9960001439 10.1021/ic981237n 10.1021/ic060167e 10.1039/b102008k 10.1016/S0010-8545(00)80455-5 10.1016/0010-8545(88)80024-9 10.1021/ic981145y 10.1039/cc9960001297 10.1002/anie.199411841 10.1016/j.poly.2005.11.002 10.1021/ic00350a010 10.1002/ejic.200400779 10.1002/chem.200401048 10.1002/(SICI)1521-3773(19980202)37:1/2<182::AID-ANIE182>3.0.CO;2-X 10.1002/anie.199300641 10.1002/ange.19931050108 10.1016/0020-1693(96)05064-5 10.1039/dt9960001761 10.1039/a903524i 10.1002/(SICI)1521-3757(19980116)110:1/2<193::AID-ANGE193>3.0.CO;2-K 10.1002/9780470166390.ch1 10.1021/ja974241r 10.1002/ange.19941061112 |
ContentType | Journal Article |
DBID | AAYXX CITATION |
DOI | 10.1002/zaac.200600300 |
DatabaseName | CrossRef |
DatabaseTitle | CrossRef |
DatabaseTitleList | CrossRef |
DeliveryMethod | fulltext_linktorsrc |
Discipline | Chemistry |
EISSN | 1521-3749 |
EndPage | 353 |
ExternalDocumentID | 10_1002_zaac_200600300 |
GroupedDBID | -~X .3N .GA .Y3 05W 0R~ 10A 123 1L6 1OB 1OC 1ZS 31~ 33P 3SF 3WU 4.4 4ZD 50Y 50Z 51W 51X 52M 52N 52O 52P 52S 52T 52U 52W 52X 53G 5VS 66C 6TJ 702 7PT 8-0 8-1 8-3 8-4 8-5 8UM 930 A03 AAESR AAEVG AAHHS AANLZ AAONW AASGY AAXRX AAYXX AAZKR ABCQN ABCUV ABDBF ABIJN ABJNI ABLJU ABTAH ACAHQ ACBWZ ACCFJ ACCUC ACCZN ACGFS ACIWK ACNCT ACPOU ACSCC ACXBN ACXQS ADBBV ADEOM ADIZJ ADKYN ADMGS ADOZA ADXAS ADZMN AEEZP AEGXH AEIGN AEIMD AENEX AEQDE AEUQT AEUYR AFBPY AFFPM AFGKR AFPWT AFZJQ AHBTC AITYG AIURR AIWBW AJBDE AJXKR ALAGY ALMA_UNASSIGNED_HOLDINGS ALUQN AMBMR AMYDB ATUGU AUFTA AZBYB AZFZN AZVAB BAFTC BDRZF BFHJK BHBCM BMNLL BMXJE BNHUX BROTX BRXPI BTSUX BY8 CITATION D-E D-F DCZOG DPXWK DR1 DR2 DRFUL DRSTM DU5 EBS EJD F00 F01 F04 FEDTE G-S G.N G8K GNP GODZA H.T H.X HBH HGLYW HHY HHZ HVGLF HZ~ IX1 J0M JPC KQQ LATKE LAW LC2 LC3 LEEKS LH4 LITHE LOXES LP6 LP7 LUTES LW6 LYRES M21 MEWTI MK4 MRFUL MRSTM MSFUL MSSTM MXFUL MXSTM N04 N05 N9A NF~ NNB O66 O9- OHT OIG P2P P2W P2X P4D PALCI Q.N QB0 QRW R.K RIWAO RJQFR RNS ROL RWI RWK RX1 RYL SAMSI SUPJJ TN5 TUS UB1 V2E W8V W99 WBFHL WBKPD WIB WIH WIK WJL WOHZO WQJ WRC WXSBR WYISQ XG1 XV2 YNT ZCG ZY4 ZZTAW ~02 ~IA ~WT |
ID | FETCH-LOGICAL-c840-9a9078417c160479490bcd6477facf01dc1250c534375b20a023b231bc77c79a3 |
ISSN | 0044-2313 |
IngestDate | Thu Sep 26 17:58:42 EDT 2024 |
IsPeerReviewed | true |
IsScholarly | true |
Issue | 2 |
Language | English |
LinkModel | OpenURL |
MergedId | FETCHMERGED-LOGICAL-c840-9a9078417c160479490bcd6477facf01dc1250c534375b20a023b231bc77c79a3 |
PageCount | 3 |
ParticipantIDs | crossref_primary_10_1002_zaac_200600300 |
PublicationCentury | 2000 |
PublicationDate | 2007-02-00 |
PublicationDateYYYYMMDD | 2007-02-01 |
PublicationDate_xml | – month: 02 year: 2007 text: 2007-02-00 |
PublicationDecade | 2000 |
PublicationTitle | Zeitschrift für anorganische und allgemeine Chemie (1950) |
PublicationYear | 2007 |
References | Hk F. (e_1_2_1_16_2) 1995; 51 e_1_2_1_22_2 e_1_2_1_23_2 e_1_2_1_20_2 e_1_2_1_21_2 e_1_2_1_24_2 e_1_2_1_6_2 e_1_2_1_7_2 Ma Y. (e_1_2_1_14_2) 1998 e_1_2_1_4_2 e_1_2_1_4_3 e_1_2_1_5_2 e_1_2_1_2_2 e_1_2_1_11_2 e_1_2_1_3_2 e_1_2_1_12_2 e_1_2_1_10_2 e_1_2_1_15_2 e_1_2_1_15_3 e_1_2_1_13_2 e_1_2_1_13_3 e_1_2_1_19_2 e_1_2_1_8_2 e_1_2_1_17_2 e_1_2_1_9_2 e_1_2_1_18_2 |
References_xml | – ident: e_1_2_1_5_2 doi: 10.1039/cc9960001439 – ident: e_1_2_1_12_2 doi: 10.1021/ic981237n – ident: e_1_2_1_21_2 doi: 10.1021/ic060167e – ident: e_1_2_1_7_2 doi: 10.1039/b102008k – start-page: 2941 year: 1998 ident: e_1_2_1_14_2 publication-title: Chem. Commun. contributor: fullname: Ma Y. – ident: e_1_2_1_23_2 doi: 10.1016/S0010-8545(00)80455-5 – ident: e_1_2_1_3_2 doi: 10.1016/0010-8545(88)80024-9 – ident: e_1_2_1_6_2 doi: 10.1021/ic981145y – ident: e_1_2_1_10_2 doi: 10.1039/cc9960001297 – ident: e_1_2_1_15_3 doi: 10.1002/anie.199411841 – ident: e_1_2_1_22_2 doi: 10.1016/j.poly.2005.11.002 – ident: e_1_2_1_8_2 doi: 10.1021/ic00350a010 – ident: e_1_2_1_19_2 doi: 10.1002/ejic.200400779 – ident: e_1_2_1_20_2 doi: 10.1002/chem.200401048 – volume: 51 start-page: 1980 year: 1995 ident: e_1_2_1_16_2 publication-title: Acta Crystallogr. contributor: fullname: Hk F. – ident: e_1_2_1_13_3 doi: 10.1002/(SICI)1521-3773(19980202)37:1/2<182::AID-ANIE182>3.0.CO;2-X – ident: e_1_2_1_24_2 – ident: e_1_2_1_4_3 doi: 10.1002/anie.199300641 – ident: e_1_2_1_4_2 doi: 10.1002/ange.19931050108 – ident: e_1_2_1_9_2 doi: 10.1016/0020-1693(96)05064-5 – ident: e_1_2_1_17_2 doi: 10.1039/dt9960001761 – ident: e_1_2_1_18_2 doi: 10.1039/a903524i – ident: e_1_2_1_13_2 doi: 10.1002/(SICI)1521-3757(19980116)110:1/2<193::AID-ANGE193>3.0.CO;2-K – ident: e_1_2_1_2_2 doi: 10.1002/9780470166390.ch1 – ident: e_1_2_1_11_2 doi: 10.1021/ja974241r – ident: e_1_2_1_15_2 doi: 10.1002/ange.19941061112 |
SSID | ssj0001055 |
Score | 1.7761958 |
Snippet | Abstract
A tetranuclear cubane‐like complex, [Cu
4
(μ‐Etae)
4
(OAc)
4
]·H
2
O (
1
), with 2‐(ethylamino)ethanol (EtaeH) and acetate (OAc)
−
ligands has been... |
SourceID | crossref |
SourceType | Aggregation Database |
StartPage | 351 |
Title | A Tetranuclear μ 3 ‐Alkoxo‐bridged Cubane‐like Copper(II) Complex Containing 2‐(Ethylamino)ethanol and Acetate: Synthesis and Structural Characterization |
Volume | 633 |
hasFullText | 1 |
inHoldings | 1 |
isFullTextHit | |
isPrint | |
link | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwnV3NbtQwELbaggQXxK_4lw9UtIpSss4_tzQs6iLBAZaqcFnZjiNFG3ZXVSqVPfEIPAPPwTPwEDwJM7bzQ7WHwiVKZp2skvkyHk9mviHkmZSxGHHPc7ELjhtwFrhJkUg3FEEo41KmSYHVyG_fRUcfgzcn4cnW9tVB1tJZIw7kemNdyf9oFWSgV6yS_QfNdhcFAeyDfmELGobtpXSMkfEGJhvkJOanzm4-3j3MHd_pMhiyer48X3aHpjqrcPIzgSmurbiu5ti8brVC9SWTCUYK0E7U6hwrAhvTRMJh3QkwagwKBjBV2Lk7VRh_XxrSgUwqzYbhZ86HrwtwL5HxROeHaqZazfKRdyzR6x4Y1kP-rKoGVtynVdk4JX7GP8wxzdN0n4IfFHbudXhdY9IOusia8kB7ythrdhDZ-FTVX7iOjx8DXFXtTA-66YWbznDHShZVL1zzuUmCWdh3pg2HxG0GdW_ig8AFp9VYTWWtOuDQjw03amv2I0PAYfHNBkbctxS4yh75G6caQ1275lwTYUZoLb1-Um0TCS7MtV0GpGGLZjM8f9adv02usDgNMTX11fueBg2bmJpMCXNrLfmox178_f8D52rgJU1vkht2eUMzg9VbZEstbpNredtV8A75kdEhZumvn9Snv799N0iFHYtRajAKAkQnNejcm0z2qUUm7ZFJGQzb6xG5b_FIAXbU4vEl7dCoxT0a6UU03iXT1-NpfuTaPiGuTALPTXnq4dfzWI4i3TABXidZYIF1yWXpjQoJTrwnQz_w41Awj4ObKuAxChnHMk65f4_sLJYLdZ9QyRIuCxZKASuZKEpTMGVFIEVYMFiIq_IBed4-39nKsMHMNmvy4aVHPiLXexw_Jjtw--oJOLqNeKpR8AcwcabB |
link.rule.ids | 315,786,790,27955,27956 |
linkProvider | Wiley-Blackwell |
openUrl | ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=A+Tetranuclear+%CE%BC+3+%E2%80%90Alkoxo%E2%80%90bridged+Cubane%E2%80%90like+Copper%28II%29+Complex+Containing+2%E2%80%90%28Ethylamino%29ethanol+and+Acetate%3A+Synthesis+and+Structural+Characterization&rft.jtitle=Zeitschrift+f%C3%BCr+anorganische+und+allgemeine+Chemie+%281950%29&rft.au=Yilmaz%2C+Veysel+T.&rft.au=Kars%2C+Vecdi&rft.au=Kazak%2C+Canan&rft.date=2007-02-01&rft.issn=0044-2313&rft.eissn=1521-3749&rft.volume=633&rft.issue=2&rft.spage=351&rft.epage=353&rft_id=info:doi/10.1002%2Fzaac.200600300&rft.externalDBID=n%2Fa&rft.externalDocID=10_1002_zaac_200600300 |
thumbnail_l | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=0044-2313&client=summon |
thumbnail_m | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=0044-2313&client=summon |
thumbnail_s | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=0044-2313&client=summon |