A Tetranuclear μ 3 ‐Alkoxo‐bridged Cubane‐like Copper(II) Complex Containing 2‐(Ethylamino)ethanol and Acetate: Synthesis and Structural Characterization
Abstract A tetranuclear cubane‐like complex, [Cu 4 (μ‐Etae) 4 (OAc) 4 ]·H 2 O ( 1 ), with 2‐(ethylamino)ethanol (EtaeH) and acetate (OAc) − ligands has been synthesized and characterized by elemental analysis, IR spectroscopy, and single crystal X‐ray diffraction. Complex 1 crystallizes in the ortho...
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| Published in | Zeitschrift für anorganische und allgemeine Chemie (1950) Vol. 633; no. 2; pp. 351 - 353 |
|---|---|
| Main Authors | , , |
| Format | Journal Article |
| Language | English |
| Published |
01.02.2007
|
| Online Access | Get full text |
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| Abstract | Abstract
A tetranuclear cubane‐like complex, [Cu
4
(μ‐Etae)
4
(OAc)
4
]·H
2
O (
1
), with 2‐(ethylamino)ethanol (EtaeH) and acetate (OAc)
−
ligands has been synthesized and characterized by elemental analysis, IR spectroscopy, and single crystal X‐ray diffraction. Complex
1
crystallizes in the orthorhombic space group
Pccn
and consists of a tetranuclear [Cu
4
O
4
]
4+
cubane core in which four copper(II) ions are bridged by μ
3
‐alkoxide oxygen atoms of the Etae
−
anion. The amine N atom of Etae
−
, and one of the O atom OAc also coordinate to the copper(II) ions forming a distorted square‐pyramidal geometry with a CuO
4
N chromophore. The Cu···Cu separations with in the [Cu
4
O
4
]
4+
cubane range from 2.905(2) to 3.377(2) Å, and these short Cu–Cu separations are responsible for the anti‐ferromagnetic coupling between the copper centers. The cubane‐like units are linked by N–H···O hydrogen bonds into one‐dimensional supramolecular chains, which are further arranged in a two‐dimensional array by van der Waal's interactions. |
|---|---|
| AbstractList | Abstract
A tetranuclear cubane‐like complex, [Cu
4
(μ‐Etae)
4
(OAc)
4
]·H
2
O (
1
), with 2‐(ethylamino)ethanol (EtaeH) and acetate (OAc)
−
ligands has been synthesized and characterized by elemental analysis, IR spectroscopy, and single crystal X‐ray diffraction. Complex
1
crystallizes in the orthorhombic space group
Pccn
and consists of a tetranuclear [Cu
4
O
4
]
4+
cubane core in which four copper(II) ions are bridged by μ
3
‐alkoxide oxygen atoms of the Etae
−
anion. The amine N atom of Etae
−
, and one of the O atom OAc also coordinate to the copper(II) ions forming a distorted square‐pyramidal geometry with a CuO
4
N chromophore. The Cu···Cu separations with in the [Cu
4
O
4
]
4+
cubane range from 2.905(2) to 3.377(2) Å, and these short Cu–Cu separations are responsible for the anti‐ferromagnetic coupling between the copper centers. The cubane‐like units are linked by N–H···O hydrogen bonds into one‐dimensional supramolecular chains, which are further arranged in a two‐dimensional array by van der Waal's interactions. |
| Author | Kazak, Canan Yilmaz, Veysel T. Kars, Vecdi |
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| CitedBy_id | crossref_primary_10_1002_chem_200701537 crossref_primary_10_1016_j_ccr_2017_06_022 crossref_primary_10_1002_ejic_201301515 crossref_primary_10_1002_zaac_200801321 |
| Cites_doi | 10.1039/cc9960001439 10.1021/ic981237n 10.1021/ic060167e 10.1039/b102008k 10.1016/S0010-8545(00)80455-5 10.1016/0010-8545(88)80024-9 10.1021/ic981145y 10.1039/cc9960001297 10.1002/anie.199411841 10.1016/j.poly.2005.11.002 10.1021/ic00350a010 10.1002/ejic.200400779 10.1002/chem.200401048 10.1002/(SICI)1521-3773(19980202)37:1/2<182::AID-ANIE182>3.0.CO;2-X 10.1002/anie.199300641 10.1002/ange.19931050108 10.1016/0020-1693(96)05064-5 10.1039/dt9960001761 10.1039/a903524i 10.1002/(SICI)1521-3757(19980116)110:1/2<193::AID-ANGE193>3.0.CO;2-K 10.1002/9780470166390.ch1 10.1021/ja974241r 10.1002/ange.19941061112 |
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| References | Hk F. (e_1_2_1_16_2) 1995; 51 e_1_2_1_22_2 e_1_2_1_23_2 e_1_2_1_20_2 e_1_2_1_21_2 e_1_2_1_24_2 e_1_2_1_6_2 e_1_2_1_7_2 Ma Y. (e_1_2_1_14_2) 1998 e_1_2_1_4_2 e_1_2_1_4_3 e_1_2_1_5_2 e_1_2_1_2_2 e_1_2_1_11_2 e_1_2_1_3_2 e_1_2_1_12_2 e_1_2_1_10_2 e_1_2_1_15_2 e_1_2_1_15_3 e_1_2_1_13_2 e_1_2_1_13_3 e_1_2_1_19_2 e_1_2_1_8_2 e_1_2_1_17_2 e_1_2_1_9_2 e_1_2_1_18_2 |
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| Snippet | Abstract
A tetranuclear cubane‐like complex, [Cu
4
(μ‐Etae)
4
(OAc)
4
]·H
2
O (
1
), with 2‐(ethylamino)ethanol (EtaeH) and acetate (OAc)
−
ligands has been... |
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| Title | A Tetranuclear μ 3 ‐Alkoxo‐bridged Cubane‐like Copper(II) Complex Containing 2‐(Ethylamino)ethanol and Acetate: Synthesis and Structural Characterization |
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