Darstellung von SCl 2 F + MF 6 ~ (M = As, Sb) und zusammenfassende Betrachtung der Kationen SCl n F 3-n + (n = 0-3) [1] / Preparation of SCl 2 F + MF 6 ~ (M = As, Sb) and a Comprehensive Discussion of the Cations SCl n F 3-n + (n = 0-3) [1]
The preparations and characterizations of compounds SCl 2 F + MF 6 ~ (M = As, Sb) are reported. They are yellowish hydrolysable solids, with a strong tendency towards symmetrization in solution. The mass spectra data indicate the formation of SCl 2 F 2 on thermolysis. The series of SCl n F 3-n + -ca...
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| Published in | Zeitschrift für Naturforschung. B, A journal of chemical sciences Vol. 44; no. 11; pp. 1343 - 1347 |
|---|---|
| Main Authors | , |
| Format | Journal Article |
| Language | English |
| Published |
01.11.1989
|
| Online Access | Get full text |
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| Summary: | The preparations and characterizations of compounds SCl
2
F
+
MF
6
~ (M = As, Sb) are reported. They are yellowish hydrolysable solids, with a strong tendency towards symmetrization in solution. The mass spectra data indicate the formation of SCl
2
F
2
on thermolysis. The series of SCl
n
F
3-n
+
-cations (n = 0—3) is now complete, and a comprehensive discussion of the spectroscopic data is given. |
|---|---|
| ISSN: | 0932-0776 1865-7117 |
| DOI: | 10.1515/znb-1989-1102 |