分散固相萃取-同位素稀释高分辨质谱法测定植物油中16种邻苯二甲酸酯
目的采用高效液相色谱-四级杆/静电场轨道阱高分辨质谱建立分散固相萃取法(dispersive solid phase extraction,d-SPE)快速分析植物油中16种邻苯二甲酸酯(Phthalate esters,PAEs)的检测方法。方法样品采用正己烷饱和的乙腈提取,经N-丙基乙二胺(primary secondary amine,PSA)和Nano Carb填料分散固相萃取净化,以BEH phenyl色谱柱为分析柱,0.1%甲酸乙腈及0.1%甲酸水溶液作为流动相进行梯度洗脱分离。采用正离子采集模式对植物油样品进行快速筛查,并对16种PAEs进行定量测定。结果 16种PAEs在2~5...
Saved in:
| Published in | 食品安全质量检测学报 no. 9; pp. 2640 - 2648 |
|---|---|
| Main Author | |
| Format | Journal Article |
| Language | Chinese |
| Published |
国家食品安全风险评估中心 卫生部食品安全风险评估重点实验室,北京,100021%北京工业大学生命科学学院,北京,100022
2014
|
| Subjects | |
| Online Access | Get full text |
Cover
Loading…
| Abstract | 目的采用高效液相色谱-四级杆/静电场轨道阱高分辨质谱建立分散固相萃取法(dispersive solid phase extraction,d-SPE)快速分析植物油中16种邻苯二甲酸酯(Phthalate esters,PAEs)的检测方法。方法样品采用正己烷饱和的乙腈提取,经N-丙基乙二胺(primary secondary amine,PSA)和Nano Carb填料分散固相萃取净化,以BEH phenyl色谱柱为分析柱,0.1%甲酸乙腈及0.1%甲酸水溶液作为流动相进行梯度洗脱分离。采用正离子采集模式对植物油样品进行快速筛查,并对16种PAEs进行定量测定。结果 16种PAEs在2~500μg/L范围内呈良好的线性关系,回归系数(r)大于0.995,该方法的定量限为8~10μg/kg。在不同加标水平下的平均回收率为77.9%~115.6%,相对标准偏差为0.3%~8.9%。结论本方法简单、灵敏、准确,适用于植物油中PAEs的快速筛查和定量测定。 |
|---|---|
| AbstractList | 目的采用高效液相色谱-四级杆/静电场轨道阱高分辨质谱建立分散固相萃取法(dispersive solid phase extraction,d-SPE)快速分析植物油中16种邻苯二甲酸酯(Phthalate esters,PAEs)的检测方法。方法样品采用正己烷饱和的乙腈提取,经N-丙基乙二胺(primary secondary amine,PSA)和Nano Carb填料分散固相萃取净化,以BEH phenyl色谱柱为分析柱,0.1%甲酸乙腈及0.1%甲酸水溶液作为流动相进行梯度洗脱分离。采用正离子采集模式对植物油样品进行快速筛查,并对16种PAEs进行定量测定。结果 16种PAEs在2~500μg/L范围内呈良好的线性关系,回归系数(r)大于0.995,该方法的定量限为8~10μg/kg。在不同加标水平下的平均回收率为77.9%~115.6%,相对标准偏差为0.3%~8.9%。结论本方法简单、灵敏、准确,适用于植物油中PAEs的快速筛查和定量测定。 目的：采用高效液相色谱-四级杆/静电场轨道阱高分辨质谱建立分散固相萃取法(dispersive solid phase extraction, d-SPE)快速分析植物油中16种邻苯二甲酸酯(Phthalate esters, PAEs)的检测方法。方法样品采用正己烷饱和的乙腈提取,经N-丙基乙二胺(primary secondary amine, PSA)和Nano Carb填料分散固相萃取净化,以BEH phenyl色谱柱为分析柱,0.1%甲酸乙腈及0.1%甲酸水溶液作为流动相进行梯度洗脱分离。采用正离子采集模式对植物油样品进行快速筛查,并对16种PAEs进行定量测定。结果16种PAEs在2~500μg/L范围内呈良好的线性关系,回归系数(r)大于0.995,该方法的定量限为8~10μg/kg。在不同加标水平下的平均回收率为77.9%~115.6%,相对标准偏差为0.3%~8.9%。结论本方法简单、灵敏、准确,适用于植物油中PAEs的快速筛查和定量测定。 |
| Abstract_FL | Objective To establish a dispersive solid phase extraction (d-SPE)/high-resolution benchtop Q exactive mass spectrometry (HRMS) method for the rapid analysis of 16 phthalate esters (PAEs). Methods The samples were extracted with acetonitrile saturated with hexane, and cleaned up by d-SPE with the N-propyl ethlene diamine (PSA) and Nano Carb as the sorbents. The chromatographic analysis was performed on a BEH phenyl column with 0.1%formic acid in acetonitrile and 0.1%formic acid solution as the mobile phase and a gradient elution program was used. The PAEs were analyzed in positive mode by Q exactive high-resolution mass spectrometry, which were applied in rapid analysis of PAEs for vegetable oils. 16 PAEs analytes were screened qualitatively in the vegetable oil samples and then quantified by isotope dilution technique. Results All the target 16 PAEs showed a good linearity in the range of 2~500μg/L , and the aver-age recovery rates of the spiked vegetable oil samples were in the range of 77.9%~115.6%with the RSD in the range of 0.3%-8.9%. The limit of quantification (LOQ) for 16 PAEs in vegetable oil were between 8μg/kg and 10μg/kg. Conclusion The method was simple, sensitive and accurate, and was suitable for the rapid analysis of 16 PAEs in vegetable oils. |
| Author | 陈达炜 赵晓雪 赵云峰 苗虹 |
| AuthorAffiliation | 国家食品安全风险评估中心卫生部食品安全风险评估重点实验室 北京工业大学生命科学学院 |
| AuthorAffiliation_xml | – name: 国家食品安全风险评估中心 卫生部食品安全风险评估重点实验室,北京,100021%北京工业大学生命科学学院,北京,100022 |
| Author_FL | CHEN Da-Wei MIAO Hong ZHAO Xiao-Xue ZHAO Yun-Feng |
| Author_FL_xml | – sequence: 1 fullname: CHEN Da-Wei – sequence: 2 fullname: ZHAO Xiao-Xue – sequence: 3 fullname: ZHAO Yun-Feng – sequence: 4 fullname: MIAO Hong |
| Author_xml | – sequence: 1 fullname: 陈达炜 赵晓雪 赵云峰 苗虹 |
| BookMark | eNotzUtLAlEYBuBZGGTlL4mBb86Zc-bMMqQbCG3chhyPZ0yx8TJE1CoKu6nkIiNyExRkRFlmYEb9Guf2L5qwzffywsP7zSkxu2zLmBJHYBIVMNNmlYTjFLIAhoZMimhc2XRPj73Ondsd-91R0D5yL65Ut92cfLf84a3fOwhPzsOn6wgFP71g2Ate37z3jvfRcF9uvPuWf_boDT4no2eN-g-t8PAraPQn46Z_OQjro7DeX1BmLF5yZOI_55X0ynI6uaamNlbXk0spVTAgqmUgqRkUsGQEsJA6klYWA89ZkgPB0hQ6ITkQCMDMEZNSLqghhbA0mqNEEDyvLE5nd7ltcTufKZZ3anb0MONUeHW_VBRFB4Gmgwnwp_FUi62yna8WIl-pFbZ5bS_DMANKDJ2AznSTIJ1FhUVXx78l84ID |
| ContentType | Journal Article |
| Copyright | Copyright © Wanfang Data Co. Ltd. All Rights Reserved. |
| Copyright_xml | – notice: Copyright © Wanfang Data Co. Ltd. All Rights Reserved. |
| DBID | 2RA 92L CQIGP W92 ~WA 2B. 4A8 92I 93N PSX TCJ |
| DatabaseName | 中文科技期刊数据库 中文科技期刊数据库-CALIS站点 中文科技期刊数据库-7.0平台 中文科技期刊数据库-工程技术 中文科技期刊数据库- 镜像站点 Wanfang Data Journals - Hong Kong WANFANG Data Centre Wanfang Data Journals 万方数据期刊 - 香港版 China Online Journals (COJ) China Online Journals (COJ) |
| DatabaseTitleList | |
| DeliveryMethod | fulltext_linktorsrc |
| Discipline | Diet & Clinical Nutrition |
| DocumentTitle_FL | Determination of 16 phthalate esters in vegetable oils by dispersive solid phase extraction-high resolution mass spectrometry with isotope dilution technique |
| EndPage | 2648 |
| ExternalDocumentID | spaqzljcjs201409005 83806574504849524857484854 |
| GrantInformation_xml | – fundername: 国家质量监督检验检疫总局公益性行业科研专项(2012104003)Fund:Supported by the Special public Welfare Industry Research of the State Administration of Quality Supervision, Inspection and Quarantine funderid: (2012104003) |
| GroupedDBID | -02 2B. 2C0 2RA 92H 92I 92L ALMA_UNASSIGNED_HOLDINGS CCEZO CDRFL CQIGP C~G DYU OK1 OZF TCJ TGT U1G U5L W92 ~WA 4A8 93N PSX |
| ID | FETCH-LOGICAL-c805-f72e17603e8503ce42efb30adfea053e9c455d0c2009d5966ac67eccf16d65c53 |
| ISSN | 2095-0381 |
| IngestDate | Wed Nov 06 04:36:30 EST 2024 Wed Feb 14 10:27:34 EST 2024 |
| IsPeerReviewed | true |
| IsScholarly | true |
| Issue | 9 |
| Keywords | 高分辨质谱法 high-resolution mass spectrometry phthalate esters 植物油 邻苯二甲酸酯 vegetable oils dispersive solid phase extraction 分散固相萃取 |
| Language | Chinese |
| LinkModel | OpenURL |
| MergedId | FETCHMERGED-LOGICAL-c805-f72e17603e8503ce42efb30adfea053e9c455d0c2009d5966ac67eccf16d65c53 |
| Notes | CHEN Da-Wei;ZHAO Xiao-Xue;ZHAO Yun-Feng;MIAO Hong;China National Centre for Food Safety Risk Assessment,Key Laboratory of Food Safety Risk Assessment,Ministry of Health;School of Life Science,Beijing University of Technology 11-5956/TS |
| PageCount | 9 |
| ParticipantIDs | wanfang_journals_spaqzljcjs201409005 chongqing_primary_83806574504849524857484854 |
| PublicationCentury | 2000 |
| PublicationDate | 2014 |
| PublicationDateYYYYMMDD | 2014-01-01 |
| PublicationDate_xml | – year: 2014 text: 2014 |
| PublicationDecade | 2010 |
| PublicationTitle | 食品安全质量检测学报 |
| PublicationTitleAlternate | Journal of Food Safety and Quality |
| PublicationTitle_FL | Journal of Food Safety & Quality |
| PublicationYear | 2014 |
| Publisher | 国家食品安全风险评估中心 卫生部食品安全风险评估重点实验室,北京,100021%北京工业大学生命科学学院,北京,100022 |
| Publisher_xml | – name: 国家食品安全风险评估中心 卫生部食品安全风险评估重点实验室,北京,100021%北京工业大学生命科学学院,北京,100022 |
| SSID | ssib007129626 ssib017479571 ssib051376490 ssib007891667 ssj0001257730 |
| Score | 1.9811327 |
| Snippet | 目的采用高效液相色谱-四级杆/静电场轨道阱高分辨质谱建立分散固相萃取法(dispersive solid phase extraction,d-SPE)快速分析植物油中16种邻苯二甲酸酯(Phthalate esters,PAEs)的检测方法。方法样品采用正己烷饱和的乙腈提取,经N-丙基乙二胺(primary... 目的：采用高效液相色谱-四级杆/静电场轨道阱高分辨质谱建立分散固相萃取法(dispersive solid phase extraction, d-SPE)快速分析植物油中16种邻苯二甲酸酯(Phthalate esters, PAEs)的检测方法。方法样品采用正己烷饱和的乙腈提取,经N-丙基乙二胺(primary... |
| SourceID | wanfang chongqing |
| SourceType | Aggregation Database Publisher |
| StartPage | 2640 |
| SubjectTerms | 分散固相萃取 植物油 邻苯二甲酸酯 高分辨质谱法 |
| Title | 分散固相萃取-同位素稀释高分辨质谱法测定植物油中16种邻苯二甲酸酯 |
| URI | http://lib.cqvip.com/qk/71822X/201409/83806574504849524857484854.html https://d.wanfangdata.com.cn/periodical/spaqzljcjs201409005 |
| hasFullText | 1 |
| inHoldings | 1 |
| isFullTextHit | |
| isPrint | |
| link | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwnR3LThRBcIKcvBifEV_ZA-0FxszOdPd0H3vY2RATOUGCB7PZeYGELCLLhZPR4AuIHMQYuZhoIsYoipggRr-Gff2FVT3DMiSaiMlkUump7q5HT3f1o6oNox-GtDimTmI6LIpMyiLHlIIlZjFOGDQP9L5EB-cbI3x4jF4fZ-M9xwZzp5bm68G1cOGPfiX_o1VIA72il-wRNNstFBIABv3CGzQM73_SMfEZEYIITnxOJCPKwRTpEU8R39WAIL4g0iJCfxJlIrmpkSBpiPiUeCUiSojtUaIsBJTA4w--JMIlQiGgPCJFrjJBPB_REKD7gEW8ItLhOUgKAoDvYS7lE6kwRdGsLgFlSo1jE09qMgRRJZjhY_2uxoL64aOHZUMxqqyxlKYaWKOYFXGY5lED6tAZRU040FLW7DpgMme0QOXICjvMQcpuWZPpaAHkOSgRpYUM8lBsv5FiJilRKKlE4EHebCKHBnQSwwdVI5EAxAZGVP6bZklqykBunjWQsStdrTcJ0smvy6SesGnHbVvo9e6kV9Fk_4_MDxI8jVCVGRx4xvBgNO6ekRQO7nm7lEEfC7NYDD2HcV8Fw-C3FPpinAHcHOt2ni5YbjxnS7sCLP8D2xJmnq5kB7Y_K8LQQrMt0nRBkrmuvpunSz_GG5mcqU3MghWlndpqSbU2kbO_Rk8aJ7KJU0Glf8Epo2dh8rTRV7od1wtXC1l02-nCyP7lEmeMW43HD5trbxrru631nfbqg8azF2ZjdXnv50pr-3Vr417n0dPOh5eA1P610d7eaH_-0vy61vy21Pj0qvl2pfXkfXPr-97OxyJvvVvp3P_RXtrc211uPd_qLO50FjfPGqNlf3Ro2MwuEzFDYTEzce246HLLiQWznDCmdpwEjlWNkrgK41AsQ8pYZIW4WRgxyXk15C50b0mRR5yFzDln9NZmavF5o0CZbdlBEslqNaCxsMHgdmGawWkcBYEtWJ8x2JVa5U4aM6byd232Gf2ZYCtZ1zJXgXYyuzA9FU7NYcuyJAyVF45W6kXjOGZNFwsvGb31u_PxZTCf68EV3Wx-A_g6nSw |
| link.rule.ids | 315,783,787,4031 |
| linkProvider | CAB International |
| openUrl | ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=%E5%88%86%E6%95%A3%E5%9B%BA%E7%9B%B8%E8%90%83%E5%8F%96-%E5%90%8C%E4%BD%8D%E7%B4%A0%E7%A8%80%E9%87%8A%E9%AB%98%E5%88%86%E8%BE%A8%E8%B4%A8%E8%B0%B1%E6%B3%95%E6%B5%8B%E5%AE%9A%E6%A4%8D%E7%89%A9%E6%B2%B9%E4%B8%AD16%E7%A7%8D%E9%82%BB%E8%8B%AF%E4%BA%8C%E7%94%B2%E9%85%B8%E9%85%AF&rft.jtitle=%E9%A3%9F%E5%93%81%E5%AE%89%E5%85%A8%E8%B4%A8%E9%87%8F%E6%A3%80%E6%B5%8B%E5%AD%A6%E6%8A%A5&rft.au=%E9%99%88%E8%BE%BE%E7%82%9C+%E8%B5%B5%E6%99%93%E9%9B%AA+%E8%B5%B5%E4%BA%91%E5%B3%B0+%E8%8B%97%E8%99%B9&rft.date=2014&rft.issn=2095-0381&rft.issue=9&rft.spage=2640&rft.epage=2648&rft.externalDocID=83806574504849524857484854 |
| thumbnail_s | http://utb.summon.serialssolutions.com/2.0.0/image/custom?url=http%3A%2F%2Fimage.cqvip.com%2Fvip1000%2Fqk%2F71822X%2F71822X.jpg http://utb.summon.serialssolutions.com/2.0.0/image/custom?url=http%3A%2F%2Fwww.wanfangdata.com.cn%2Fimages%2FPeriodicalImages%2Fspaqzljcjs%2Fspaqzljcjs.jpg |