A bi-overlayer type plasmonic photocatalyst consisting of mesoporous Au/TiO 2 and CuO/SnO 2 films separately coated on FTO
The principal purpose of this study is to present a new design for preparing highly active immobilized gold nanoparticle-based plasmonic photocatalysts. Gold nanoparticles were loaded on rutile TiO 2 particles with a mean size of 80 nm (Au/TiO 2 ) by the deposition precipitation method. The surface...
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| Published in | Physical chemistry chemical physics : PCCP Vol. 17; no. 27; pp. 18004 - 18010 |
|---|---|
| Main Authors | , , , |
| Format | Journal Article |
| Language | English |
| Published |
2015
|
| Online Access | Get full text |
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| Abstract | The principal purpose of this study is to present a new design for preparing highly active immobilized gold nanoparticle-based plasmonic photocatalysts. Gold nanoparticles were loaded on rutile TiO
2
particles with a mean size of 80 nm (Au/TiO
2
) by the deposition precipitation method. The surface of SnO
2
particles with a mean size of 100 nm was modified by copper(
ii
) oxide clusters (CuO/SnO
2
) with the loading amount (
Γ
/Cu ions nm
−2
) precisely controlled by the chemisorption–calcination cycle technique. Two mesoporous overlayers of Au/TiO
2
and CuO/SnO
2
were coated side by side on glass substrates with a fluorine-doped tin oxide film (FTO) using the doctor blade method (Au/mp-TiO
2
|FTO|CuO/mp-SnO
2
). As test reactions for assessing the visible-light activity, we carried out gas-phase decomposition of acetaldehyde and liquid-phase oxidation of alcohol. In each reaction, this bi-overlayer type catalyst shows a high level of visible-light activity much exceeding those of Au/TiO
2
particles and a Au/mp-TiO
2
|FTO mono-overlayer type catalyst [
J. Phys. Chem. C
, 2014,
118
, 26887]. To confirm the origin of the striking visible-light activity, we studied the electrocatalytic activity of CuO/mp-SnO
2
|FTO electrodes for the oxygen reduction reaction (ORR). Both the visible-light activity of Au/mp-TiO
2
|FTO|CuO/mp-SnO
2
and the electrocatalytic activity of CuO/mp-SnO
2
|FTO for ORR strongly depend on the
Γ
value. A good positive correlation has been found between the visible-light activities and the electrocatalytic activity for ORR. The striking activity of the present bi-overlayer type catalyst can be attributed to the efficient and long-range charge separation by the vectorial electron transport (Au(oxidation sites) → TiO
2
→ FTO, SnO
2
→ CuO(reduction sites)) and the excellent electrocatalytic activity of the CuO clusters. |
|---|---|
| AbstractList | The principal purpose of this study is to present a new design for preparing highly active immobilized gold nanoparticle-based plasmonic photocatalysts. Gold nanoparticles were loaded on rutile TiO
2
particles with a mean size of 80 nm (Au/TiO
2
) by the deposition precipitation method. The surface of SnO
2
particles with a mean size of 100 nm was modified by copper(
ii
) oxide clusters (CuO/SnO
2
) with the loading amount (
Γ
/Cu ions nm
−2
) precisely controlled by the chemisorption–calcination cycle technique. Two mesoporous overlayers of Au/TiO
2
and CuO/SnO
2
were coated side by side on glass substrates with a fluorine-doped tin oxide film (FTO) using the doctor blade method (Au/mp-TiO
2
|FTO|CuO/mp-SnO
2
). As test reactions for assessing the visible-light activity, we carried out gas-phase decomposition of acetaldehyde and liquid-phase oxidation of alcohol. In each reaction, this bi-overlayer type catalyst shows a high level of visible-light activity much exceeding those of Au/TiO
2
particles and a Au/mp-TiO
2
|FTO mono-overlayer type catalyst [
J. Phys. Chem. C
, 2014,
118
, 26887]. To confirm the origin of the striking visible-light activity, we studied the electrocatalytic activity of CuO/mp-SnO
2
|FTO electrodes for the oxygen reduction reaction (ORR). Both the visible-light activity of Au/mp-TiO
2
|FTO|CuO/mp-SnO
2
and the electrocatalytic activity of CuO/mp-SnO
2
|FTO for ORR strongly depend on the
Γ
value. A good positive correlation has been found between the visible-light activities and the electrocatalytic activity for ORR. The striking activity of the present bi-overlayer type catalyst can be attributed to the efficient and long-range charge separation by the vectorial electron transport (Au(oxidation sites) → TiO
2
→ FTO, SnO
2
→ CuO(reduction sites)) and the excellent electrocatalytic activity of the CuO clusters. |
| Author | Naya, Shin-ichi Kume, Takahiro Tada, Hiroaki Okumura, Nozomi |
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| CitedBy_id | crossref_primary_10_1111_ijac_13467 crossref_primary_10_1021_acs_jpcc_6b04894 crossref_primary_10_1016_j_mtener_2018_10_011 crossref_primary_10_1021_acs_jpcc_6b06854 |
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| Title | A bi-overlayer type plasmonic photocatalyst consisting of mesoporous Au/TiO 2 and CuO/SnO 2 films separately coated on FTO |
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