Hybrid LiV 3 O 8 /carbon encapsulated Li 1.2 Mn 0.54 Co 0.13 Ni 0.13 O 2 with improved electrochemical properties for lithium ion batteries

A low coulombic efficiency in the first cycle and poor rate capability limit the practical application of a lithium rich manganese-based solid solution (LMSS) in lithium ion batteries. To resolve these problems, a core–shell type of Li 1.2 Mn 0.54 Co 0.13 Ni 0.13 O 2 @LiV 3 O 8 /C (LMSSVC) composite...

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Published inRSC advances Vol. 6; no. 34; pp. 28729 - 28736
Main Authors Sun, Kailing, Peng, Can, Li, Zhaohui, Xiao, Qichang, Lei, Gangtie, Xiao, Qizhen, Ding, Yanhuai, Hu, Zhongliang
Format Journal Article
LanguageEnglish
Published 2016
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Abstract A low coulombic efficiency in the first cycle and poor rate capability limit the practical application of a lithium rich manganese-based solid solution (LMSS) in lithium ion batteries. To resolve these problems, a core–shell type of Li 1.2 Mn 0.54 Co 0.13 Ni 0.13 O 2 @LiV 3 O 8 /C (LMSSVC) composite material was prepared using a sol–gel process, in which NH 4 VO 3 -derived V 2 O 5 chemically leached lithium from the LMSS and formed the LiV 3 O 8 during high temperature annealing. The effect of the hybrid LiV 3 O 8 /C layer on the electrochemical properties of the LMSS is investigated using cyclic voltammetry, electrochemical impedance spectroscopy and galvanostatic charge–discharge measurements. The as-prepared LiV 3 O 8 nanoparticles are embedded within the carbon matrix uniformly, which becomes an outer shell to encapsulate the LMSS nanoparticles. Because of the Li-host nature of LiV 3 O 8 and the electronic conductivity of carbon, the LMSSVC can deliver a capacity of 269 mA h g −1 at a 0.1C rate in the first cycle over the voltage range of 2.0–4.8 V together with a coulombic efficiency of 94%, and retain 94% of the initial capacity after 50 cycles. It can deliver capacities of 258, 245, 229, 207 and 176 mA h g −1 at the rates of 0.2C, 0.5C, 1C, 2C and 5C, respectively. The results indicate that surface coating of the hybrid LiV 3 O 8 /C layer can improve not only the initial coulombic efficiency but also the rate capability of the LMSS material.
AbstractList A low coulombic efficiency in the first cycle and poor rate capability limit the practical application of a lithium rich manganese-based solid solution (LMSS) in lithium ion batteries. To resolve these problems, a core–shell type of Li 1.2 Mn 0.54 Co 0.13 Ni 0.13 O 2 @LiV 3 O 8 /C (LMSSVC) composite material was prepared using a sol–gel process, in which NH 4 VO 3 -derived V 2 O 5 chemically leached lithium from the LMSS and formed the LiV 3 O 8 during high temperature annealing. The effect of the hybrid LiV 3 O 8 /C layer on the electrochemical properties of the LMSS is investigated using cyclic voltammetry, electrochemical impedance spectroscopy and galvanostatic charge–discharge measurements. The as-prepared LiV 3 O 8 nanoparticles are embedded within the carbon matrix uniformly, which becomes an outer shell to encapsulate the LMSS nanoparticles. Because of the Li-host nature of LiV 3 O 8 and the electronic conductivity of carbon, the LMSSVC can deliver a capacity of 269 mA h g −1 at a 0.1C rate in the first cycle over the voltage range of 2.0–4.8 V together with a coulombic efficiency of 94%, and retain 94% of the initial capacity after 50 cycles. It can deliver capacities of 258, 245, 229, 207 and 176 mA h g −1 at the rates of 0.2C, 0.5C, 1C, 2C and 5C, respectively. The results indicate that surface coating of the hybrid LiV 3 O 8 /C layer can improve not only the initial coulombic efficiency but also the rate capability of the LMSS material.
Author Sun, Kailing
Xiao, Qizhen
Xiao, Qichang
Hu, Zhongliang
Lei, Gangtie
Peng, Can
Ding, Yanhuai
Li, Zhaohui
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