Hydrothermal conversion of cerium oxalate to CeO 2 : a parade of oxalate and water coordination modes

Hydrothemal conversion of lanthanide/actinide oxalate salts to nanocrystalline oxide has gained technological importance in the chemistry of f -elements. Herein, we present a study describing the mechanism behind the hydrothermal recrystallization and decomposition of cerium (and Ce-Gd) oxalate to o...

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Published inNew journal of chemistry Vol. 48; no. 3; pp. 1071 - 1075
Main Authors Assi, Navid, Lahoud, Christophe, Brázda, Petr, Zákutná, Dominika, Rainer, Daniel N., Hraníček, Jakub, Rohlíček, Jan, Tyrpekl, Václav
Format Journal Article
LanguageEnglish
Published 15.01.2024
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Abstract Hydrothemal conversion of lanthanide/actinide oxalate salts to nanocrystalline oxide has gained technological importance in the chemistry of f -elements. Herein, we present a study describing the mechanism behind the hydrothermal recrystallization and decomposition of cerium (and Ce-Gd) oxalate to oxide. Structural determination of all intermediate nanocrystalline products was possible thanks to three-dimensional electron diffraction. This work reveals the enormous structural abilities of simple oxalate ligands.
AbstractList Hydrothemal conversion of lanthanide/actinide oxalate salts to nanocrystalline oxide has gained technological importance in the chemistry of f -elements. Herein, we present a study describing the mechanism behind the hydrothermal recrystallization and decomposition of cerium (and Ce-Gd) oxalate to oxide. Structural determination of all intermediate nanocrystalline products was possible thanks to three-dimensional electron diffraction. This work reveals the enormous structural abilities of simple oxalate ligands.
Author Lahoud, Christophe
Brázda, Petr
Zákutná, Dominika
Rainer, Daniel N.
Hraníček, Jakub
Assi, Navid
Rohlíček, Jan
Tyrpekl, Václav
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