An organic cation as a silver( i ) analogue for the arylation of sp 2 and sp 3 C–H bonds with iodoarenes

Reactions promoted by stoichiometric amounts of silver salts suffer from high cost, limited availability and raise environmental concerns. This manuscript describes studies leading to the discovery of a general replacement for silver with an inexpensive and convenient organic salt in palladium catal...

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Published inChemical science (Cambridge) Vol. 5; no. 9; pp. 3509 - 3514
Main Authors Arroniz, Carlos, Denis, J. Gabriel, Ironmonger, Alan, Rassias, Gerasimos, Larrosa, Igor
Format Journal Article
LanguageEnglish
Published 2014
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Summary:Reactions promoted by stoichiometric amounts of silver salts suffer from high cost, limited availability and raise environmental concerns. This manuscript describes studies leading to the discovery of a general replacement for silver with an inexpensive and convenient organic salt in palladium catalyzed direct C(sp 2 )–H and C(sp 3 )–H arylation reactions.
ISSN:2041-6520
2041-6539
DOI:10.1039/C4SC01215A