Thermal Expansion of Ln 6 WO 12 ( Ln = Y , Ho , Er , Yb ) and Ln 2 WO 6 ( Ln  =  Gd , Dy , Ho ) – an In Situ Synchrotron X‐ray Diffraction Study

The thermal expansion ( TE ) behavior of cubic and rhombohedral Ln 6 WO 12 (Ln = Y, Ho, Er, Yb) and monoclinic Ln 2 WO 6 (Ln = Gd, Dy, Ho) was investigated by synchrotron X‐ray diffraction from room temperature to approximately 1500°C. The volumetric and lattice parameter expansions were measured fo...

Full description

Saved in:
Bibliographic Details
Published inJournal of the American Ceramic Society Vol. 97; no. 8; pp. 2496 - 2505
Main Authors Apostolov, Zlatomir D., Sarin, Pankaj, Hughes, Robert W., Kriven, Waltraud M.
Format Journal Article
LanguageEnglish
Published 01.08.2014
Online AccessGet full text

Cover

Abstract The thermal expansion ( TE ) behavior of cubic and rhombohedral Ln 6 WO 12 (Ln = Y, Ho, Er, Yb) and monoclinic Ln 2 WO 6 (Ln = Gd, Dy, Ho) was investigated by synchrotron X‐ray diffraction from room temperature to approximately 1500°C. The volumetric and lattice parameter expansions were measured for all compositions in both systems, and the respective expansion coefficients were derived and fitted over the observed temperature range with a second‐order polynomial. The relative TE evolution along the unit cell edges in each phase was described from a crystallographic perspective, with the reasons for TE dynamics explained in terms of the fundamental constituent units of the structure. Analysis of the TE ellipsoid of the monoclinic Ln 2 WO 6 revealed a continuous change in both its shape and orientation, with the latter effect strongly manifested in the (010) plane. A noticeable reversal of the relative expansion rates between a , and b and c lattice parameters was attributed to the rotation of the ellipsoid cross section in this plane, bringing the larger of the two eigenvectors closer to a , while the smaller one to c . Investigating the structural dynamics of the constituent layers in Ln 2 WO 6 suggested that the bridging role of the Ln polyhedron centered on the only general position in the unit cell may be the reason for the rotating TE ellipsoid.
AbstractList The thermal expansion ( TE ) behavior of cubic and rhombohedral Ln 6 WO 12 (Ln = Y, Ho, Er, Yb) and monoclinic Ln 2 WO 6 (Ln = Gd, Dy, Ho) was investigated by synchrotron X‐ray diffraction from room temperature to approximately 1500°C. The volumetric and lattice parameter expansions were measured for all compositions in both systems, and the respective expansion coefficients were derived and fitted over the observed temperature range with a second‐order polynomial. The relative TE evolution along the unit cell edges in each phase was described from a crystallographic perspective, with the reasons for TE dynamics explained in terms of the fundamental constituent units of the structure. Analysis of the TE ellipsoid of the monoclinic Ln 2 WO 6 revealed a continuous change in both its shape and orientation, with the latter effect strongly manifested in the (010) plane. A noticeable reversal of the relative expansion rates between a , and b and c lattice parameters was attributed to the rotation of the ellipsoid cross section in this plane, bringing the larger of the two eigenvectors closer to a , while the smaller one to c . Investigating the structural dynamics of the constituent layers in Ln 2 WO 6 suggested that the bridging role of the Ln polyhedron centered on the only general position in the unit cell may be the reason for the rotating TE ellipsoid.
Author Hughes, Robert W.
Apostolov, Zlatomir D.
Sarin, Pankaj
Kriven, Waltraud M.
Author_xml – sequence: 1
  givenname: Zlatomir D.
  surname: Apostolov
  fullname: Apostolov, Zlatomir D.
  organization: Department of Material Science and Engineering University of Illinois at Urbana‐Champaign Urbana Illinois 61801
– sequence: 2
  givenname: Pankaj
  surname: Sarin
  fullname: Sarin, Pankaj
  organization: Department of Material Science and Engineering University of Illinois at Urbana‐Champaign Urbana Illinois 61801
– sequence: 3
  givenname: Robert W.
  surname: Hughes
  fullname: Hughes, Robert W.
  organization: Department of Material Science and Engineering University of Illinois at Urbana‐Champaign Urbana Illinois 61801
– sequence: 4
  givenname: Waltraud M.
  surname: Kriven
  fullname: Kriven, Waltraud M.
  organization: Department of Material Science and Engineering University of Illinois at Urbana‐Champaign Urbana Illinois 61801
BookMark eNotkMFqwkAQhpfSQtX20ieYYy2N3d24u8nBQ1GrguAhQusprJtdjOhGNhGam49QKPTss_goPkmT2jn8wzDfzA9_E13bzGqEHgjukKpe1lLpDqEhp1eoQRgjHg0Jv0YNjDH1REDxLWrm-boaSRh0G-hnvtJuKzcw_NxJm6eZhczA1AKH9xkQCo_10IMFPMM4q2ToKlksoQ3SJvWO1iC_cKdj73SEUVIhg_Jy0Ybz4btiYWIhSos9RKVVK5cVrrL6OB--nCxhkBrjpCpq-6jYJ-UdujFyk-v7_95C0dtw3h9709lo0n-dekpw6nG1NL4RRugw8IOAdSlLmMJSGJ4YudRJIjCjQmnia9VVhnEcMBkkPjUm5MJvoafLV-WyPHfaxDuXbqUrY4LjOs-4zjP-y9P_BThXZrs
CitedBy_id crossref_primary_10_1016_j_ceramint_2023_06_158
crossref_primary_10_1021_acs_chemmater_0c01405
crossref_primary_10_1021_acs_inorgchem_6b02710
crossref_primary_10_1016_j_jmmm_2020_167539
crossref_primary_10_1021_acsami_5b01776
crossref_primary_10_1007_s12598_018_1039_5
Cites_doi 10.1006/jssc.1999.8502
10.1016/j.solidstatesciences.2004.07.023
10.1063/1.2349600
10.1021/jp2015066
10.1107/S0567739476001551
10.1557/JMR.1999.0462
10.1016/0025-5408(71)90008-0
10.1017/S088571560001112X
10.1016/j.matchemphys.2010.07.028
10.1038/425674a
10.1021/ic50005a043
10.1016/0022-4596(78)90071-3
10.1016/j.ssi.2007.01.004
10.1246/bcsj.50.2932
10.1111/j.1151-2916.1980.tb09853.x
10.1016/0025-5408(78)90107-1
10.1016/j.jlumin.2009.11.026
10.1016/0022-4596(73)90170-9
10.1016/j.physb.2009.06.007
10.1021/ic980253h
10.1016/j.jallcom.2012.01.010
10.1016/j.mseb.2004.08.015
10.1021/ic50017a005
10.1111/jace.12119
10.1006/jssc.1998.7744
10.1006/jssc.1998.7967
10.1126/science.272.5258.90
10.1063/1.1734285
10.1021/cm900650c
10.1002/zaac.19020320122
10.1039/jr9490002501
10.1111/j.1151-2916.1998.tb02684.x
10.1021/cm900067k
10.1016/0025-5408(78)90220-9
10.1021/ic50039a012
10.1016/j.physb.2009.04.016
10.1149/1.2374948
10.1107/S0021889813002938
ContentType Journal Article
DBID AAYXX
CITATION
DOI 10.1111/jace.12962
DatabaseName CrossRef
DatabaseTitle CrossRef
DatabaseTitleList CrossRef
DeliveryMethod fulltext_linktorsrc
Discipline Visual Arts
Engineering
EISSN 1551-2916
Editor Wong‐Ng, W. K.
Editor_xml – sequence: 1
  givenname: W. K.
  surname: Wong‐Ng
  fullname: Wong‐Ng, W. K.
EndPage 2505
ExternalDocumentID 10_1111_jace_12962
GroupedDBID .3N
.4S
.DC
.GA
.Y3
05W
0R~
10A
1OB
1OC
29L
31~
33P
3SF
4.4
50Y
50Z
51W
51X
52M
52N
52O
52P
52S
52T
52U
52W
52X
5GY
5HH
5LA
5VS
66C
6TJ
702
7PT
8-0
8-1
8-3
8-4
8-5
8UM
8WZ
930
A03
A6W
AAESR
AAEVG
AAHHS
AANLZ
AAONW
AASGY
AAXRX
AAYXX
AAZKR
ABCQN
ABCUV
ABDBF
ABEFU
ABEML
ABJNI
ABPVW
ABTAH
ACAHQ
ACBEA
ACBWZ
ACCFJ
ACCZN
ACGFO
ACGFS
ACGOD
ACIWK
ACKIV
ACNCT
ACPOU
ACSCC
ACXBN
ACXQS
ADBBV
ADEOM
ADIZJ
ADKYN
ADMGS
ADOZA
ADXAS
ADZMN
AEEZP
AEGXH
AEIGN
AEIMD
AENEX
AEQDE
AEUQT
AEUYR
AFBPY
AFEBI
AFFNX
AFFPM
AFGKR
AFPWT
AFZJQ
AHBTC
AHEFC
AI.
AIAGR
AITYG
AIURR
AIWBW
AJBDE
AJXKR
ALAGY
ALMA_UNASSIGNED_HOLDINGS
ALUQN
AMBMR
AMYDB
ARCSS
ASPBG
ATUGU
AUFTA
AVWKF
AZBYB
AZFZN
AZVAB
BAFTC
BDRZF
BFHJK
BHBCM
BMNLL
BMXJE
BNHUX
BROTX
BRXPI
BY8
CAG
CITATION
CO8
COF
CS3
D-E
D-F
DC6
DCZOG
DPXWK
DR2
DRFUL
DRSTM
DU5
EAD
EAP
EBO
EBS
EDO
EJD
EMK
ESX
F00
F01
F04
FEDTE
FOJGT
FZ0
G-S
G.N
G8K
GODZA
H.T
H.X
HF~
HGLYW
HVGLF
HZI
HZ~
H~9
I-F
IRD
ITF
ITG
ITH
IX1
J0M
K48
LATKE
LC2
LC3
LEEKS
LH4
LITHE
LOXES
LP6
LP7
LUTES
LW6
LYRES
MEWTI
MK4
MRFUL
MRSTM
MSFUL
MSSTM
MXFUL
MXSTM
N04
N05
NDZJH
NF~
O66
O9-
OIG
P2P
P2W
P2X
P4D
PALCI
PQQKQ
Q.N
Q11
QB0
QF4
QM1
QN7
QO4
R.K
RAX
RIWAO
RJQFR
ROL
RX1
SAMSI
SJN
SUPJJ
TAE
TH9
TN5
TUS
UB1
UPT
V8K
VH1
W8V
W99
WBKPD
WFSAM
WH7
WIH
WIK
WOHZO
WQJ
WRC
WTY
WXSBR
WYISQ
XG1
YQT
ZCG
ZE2
ZY4
ZZTAW
~02
~IA
~WT
ID FETCH-LOGICAL-c762-6cbf3f7f7e983885425d5c0a7f6dfabedd70527ce13ec4cf56085a8d32ff9673
ISSN 0002-7820
IngestDate Fri Aug 23 02:33:11 EDT 2024
IsPeerReviewed true
IsScholarly true
Issue 8
Language English
LinkModel OpenURL
MergedId FETCHMERGED-LOGICAL-c762-6cbf3f7f7e983885425d5c0a7f6dfabedd70527ce13ec4cf56085a8d32ff9673
PageCount 10
ParticipantIDs crossref_primary_10_1111_jace_12962
PublicationCentury 2000
PublicationDate 2014-08-00
PublicationDateYYYYMMDD 2014-08-01
PublicationDate_xml – month: 08
  year: 2014
  text: 2014-08-00
PublicationDecade 2010
PublicationTitle Journal of the American Ceramic Society
PublicationYear 2014
References e_1_2_6_32_1
e_1_2_6_10_1
e_1_2_6_31_1
e_1_2_6_30_1
Sarin P. (e_1_2_6_43_1) 2006
Tyulin A. V. (e_1_2_6_29_1) 1987; 32
e_1_2_6_19_1
Efremov V. A. (e_1_2_6_27_1) 1984; 29
Hazen R. M. (e_1_2_6_46_1) 1977; 62
Tyulin A. V. (e_1_2_6_28_1) 1987; 32
e_1_2_6_13_1
e_1_2_6_36_1
e_1_2_6_14_1
e_1_2_6_35_1
e_1_2_6_11_1
e_1_2_6_34_1
e_1_2_6_12_1
e_1_2_6_33_1
e_1_2_6_17_1
e_1_2_6_18_1
Pokrovskii A. N. (e_1_2_6_26_1) 1969; 14
e_1_2_6_39_1
e_1_2_6_15_1
e_1_2_6_38_1
e_1_2_6_16_1
e_1_2_6_37_1
e_1_2_6_42_1
e_1_2_6_21_1
e_1_2_6_20_1
e_1_2_6_41_1
e_1_2_6_40_1
e_1_2_6_9_1
e_1_2_6_8_1
e_1_2_6_5_1
e_1_2_6_4_1
e_1_2_6_7_1
e_1_2_6_6_1
e_1_2_6_25_1
e_1_2_6_48_1
e_1_2_6_24_1
e_1_2_6_3_1
e_1_2_6_23_1
e_1_2_6_2_1
e_1_2_6_22_1
e_1_2_6_44_1
e_1_2_6_45_1
e_1_2_6_47_1
References_xml – ident: e_1_2_6_14_1
  doi: 10.1006/jssc.1999.8502
– ident: e_1_2_6_16_1
  doi: 10.1016/j.solidstatesciences.2004.07.023
– volume: 29
  start-page: 534
  year: 1984
  ident: e_1_2_6_27_1
  article-title: Crystal Structure of Monoclinic Y2WO6 and Yb2WO6
  publication-title: Sov. Phys. Crystallogr. (Engl. Transl.)
  contributor:
    fullname: Efremov V. A.
– ident: e_1_2_6_42_1
  doi: 10.1063/1.2349600
– ident: e_1_2_6_19_1
  doi: 10.1021/jp2015066
– ident: e_1_2_6_45_1
  doi: 10.1107/S0567739476001551
– ident: e_1_2_6_39_1
  doi: 10.1557/JMR.1999.0462
– ident: e_1_2_6_35_1
  doi: 10.1016/0025-5408(71)90008-0
– ident: e_1_2_6_40_1
– ident: e_1_2_6_37_1
  doi: 10.1017/S088571560001112X
– ident: e_1_2_6_5_1
  doi: 10.1016/j.matchemphys.2010.07.028
– ident: e_1_2_6_9_1
  doi: 10.1038/425674a
– volume: 14
  start-page: 1233
  year: 1969
  ident: e_1_2_6_26_1
  article-title: X‐Ray Diffraction Investigation of Oxotungstates and Oxomolybdates of the Lanthanides and of Yttrium Oxotungstate
  publication-title: Russ. J. Inorg. Chem. (Engl. Transl.)
  contributor:
    fullname: Pokrovskii A. N.
– ident: e_1_2_6_33_1
  doi: 10.1021/ic50005a043
– volume: 32
  start-page: 215
  year: 1987
  ident: e_1_2_6_28_1
  article-title: Polymorphism of Oxytungstates Tr2WO6. Analysis of Structural Type II (Gd2WO6 and Gd2MoO6). Mechanism of Structural Change in Gd2WO6 in the Phase Transition II <‐> V
  publication-title: Sov. Phys. Crystallogr. (Engl. Transl.)
  contributor:
    fullname: Tyulin A. V.
– ident: e_1_2_6_48_1
  doi: 10.1016/0022-4596(78)90071-3
– ident: e_1_2_6_11_1
  doi: 10.1016/j.ssi.2007.01.004
– ident: e_1_2_6_24_1
  doi: 10.1246/bcsj.50.2932
– ident: e_1_2_6_32_1
  doi: 10.1111/j.1151-2916.1980.tb09853.x
– ident: e_1_2_6_31_1
  doi: 10.1016/0025-5408(78)90107-1
– start-page: 313
  volume-title: Mechanical Properties and Properties and Performance on Engineering Ceramics and Composites II
  year: 2006
  ident: e_1_2_6_43_1
  contributor:
    fullname: Sarin P.
– ident: e_1_2_6_2_1
  doi: 10.1016/j.jlumin.2009.11.026
– ident: e_1_2_6_25_1
– ident: e_1_2_6_41_1
– ident: e_1_2_6_23_1
  doi: 10.1016/0022-4596(73)90170-9
– ident: e_1_2_6_3_1
  doi: 10.1016/j.physb.2009.06.007
– ident: e_1_2_6_47_1
  doi: 10.1021/ic980253h
– ident: e_1_2_6_4_1
  doi: 10.1016/j.jallcom.2012.01.010
– ident: e_1_2_6_15_1
  doi: 10.1016/j.mseb.2004.08.015
– ident: e_1_2_6_34_1
  doi: 10.1021/ic50017a005
– ident: e_1_2_6_38_1
  doi: 10.1111/jace.12119
– ident: e_1_2_6_13_1
  doi: 10.1006/jssc.1998.7744
– ident: e_1_2_6_8_1
  doi: 10.1006/jssc.1998.7967
– ident: e_1_2_6_7_1
  doi: 10.1126/science.272.5258.90
– ident: e_1_2_6_22_1
  doi: 10.1063/1.1734285
– ident: e_1_2_6_17_1
  doi: 10.1021/cm900650c
– ident: e_1_2_6_20_1
  doi: 10.1002/zaac.19020320122
– ident: e_1_2_6_21_1
  doi: 10.1039/jr9490002501
– ident: e_1_2_6_36_1
  doi: 10.1111/j.1151-2916.1998.tb02684.x
– volume: 62
  start-page: 309
  year: 1977
  ident: e_1_2_6_46_1
  article-title: Effects of Temperature and Pressure on Interatomic Distances in Oxygen‐Based Minerals
  publication-title: Am. Mineral.
  contributor:
    fullname: Hazen R. M.
– ident: e_1_2_6_10_1
  doi: 10.1021/cm900067k
– ident: e_1_2_6_30_1
  doi: 10.1016/0025-5408(78)90220-9
– ident: e_1_2_6_18_1
  doi: 10.1021/ic50039a012
– volume: 32
  start-page: 210
  year: 1987
  ident: e_1_2_6_29_1
  article-title: Polymorphism of Oxytungstates TR2WO6. Mechanism of Structural Changes of Er2WO6
  publication-title: Sov. Phys. Crystallogr. (Engl. Transl.)
  contributor:
    fullname: Tyulin A. V.
– ident: e_1_2_6_6_1
  doi: 10.1016/j.physb.2009.04.016
– ident: e_1_2_6_12_1
  doi: 10.1149/1.2374948
– ident: e_1_2_6_44_1
  doi: 10.1107/S0021889813002938
SSID ssj0001984
Score 2.1574183
Snippet The thermal expansion ( TE ) behavior of cubic and rhombohedral Ln 6 WO 12 (Ln = Y, Ho, Er, Yb) and monoclinic Ln 2 WO 6 (Ln = Gd, Dy, Ho) was investigated by...
SourceID crossref
SourceType Aggregation Database
StartPage 2496
Title Thermal Expansion of Ln 6 WO 12 ( Ln = Y , Ho , Er , Yb ) and Ln 2 WO 6 ( Ln  =  Gd , Dy , Ho ) – an In Situ Synchrotron X‐ray Diffraction Study
Volume 97
hasFullText 1
inHoldings 1
isFullTextHit
isPrint
link http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwnV1Lb9NAEF71cYED4inKSytBJaolUfxa24ceqqQ0oJYiUkhyitbrNQ0Eu3KdSuHUn4CExLm_pT-lv4QZr7MxFKHCZWM7M46S-fTN7ObbMSHPsCVWEqqoIWLXb7gyQREABCSEw8iVAecKNyfvveHd9-7rgTdYWl6tqZamRdSUX_-4r-R_ogrXIK64S_YfImtuChfgGOILI0QYxqvGGHh1gv2KIeNUpd9uymBevs8sG6tHPF13Ogz7ZkOSyZgmv_JlGDFcFMClc7Cy0Ykbn7a9vtUCT33AduLSpTNb3Cdkc6WEA_cApmG9cTFlvVkqD_MMl9jZwGgpcjEDek2SvHo2ec-0tb1cGdd2u6SsrXKB-v1KXmoAeoQdQSbZSfnvykQU2ZdxzjpNs2Ikct0d4a1IP4tPC_R-PNTEqCXlrG88gO5ONAf3xaTIxTRme836oojlGkleneixFaBOcxW3e1bDDvXWzjn5a3FwBfKgzuRuyGtVAVaKf8s4QqomlE5VZvmlrfdv6daIIM30C3xHpe8yWbX90ENlaufdoguaFQbufBaH36nqslsK0szn1uqqWoF0cJPcqOJHtzRMb5Elld4m12v9LuHsw_h4qm2O75AfFXypgS_NErqbUk77-9Sy6XM82aRD-oJ2Mxi2cxiGEd2gAFl8z0ZDru3OzzbPz-hODCadmfbYoBen38GWvkopQpPWoEkHF6ffAJS0BkpagvIu6b3cPmh3G9VjQhoSMnmDyyhxEj_xVRg4QeBBEoo92RJ-wuNERCqO_ZZn-1JZjpLAQFDiB54IYuCoJOS-c4-spFmq7hPKYy4C7ijc3-dK1xKo0PfCKJBQ1HPF18jT-U88OtK9YEaXg_jgSlYPybUFbh-RlSKfqsdQ3hbRkzL4PwEruJRk
link.rule.ids 315,786,790,27955,27956
linkProvider Wiley-Blackwell
openUrl ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=Thermal+Expansion+of+Ln+6+WO+12+%28+Ln+%3D+Y+%2C+Ho+%2C+Er+%2C+Yb+%29+and+Ln+2+WO+6+%28+Ln+%C2%A0%3D%C2%A0+Gd+%2C+Dy+%2C+Ho+%29+%E2%80%93+an+In+Situ+Synchrotron+X%E2%80%90ray+Diffraction+Study&rft.jtitle=Journal+of+the+American+Ceramic+Society&rft.au=Apostolov%2C+Zlatomir+D.&rft.au=Sarin%2C+Pankaj&rft.au=Hughes%2C+Robert+W.&rft.au=Kriven%2C+Waltraud+M.&rft.date=2014-08-01&rft.issn=0002-7820&rft.eissn=1551-2916&rft.volume=97&rft.issue=8&rft.spage=2496&rft.epage=2505&rft_id=info:doi/10.1111%2Fjace.12962&rft.externalDBID=n%2Fa&rft.externalDocID=10_1111_jace_12962
thumbnail_l http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=0002-7820&client=summon
thumbnail_m http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=0002-7820&client=summon
thumbnail_s http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=0002-7820&client=summon