Stereoelectronic Chameleons: The Donor–Acceptor Dichotomy of Functional Groups
Stereoelectronic factors account for the apparent reversal of donor–acceptor properties of a variety of functional groups by a simple change of their orientation in space. The new reactivity patterns that arise from spatial anisotropy are associated with chameleonic behavior of common organic functi...
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| Published in | Chemistry : a European journal Vol. 23; no. 14; pp. 3225 - 3245 |
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| Main Authors | , , , |
| Format | Journal Article |
| Language | English |
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08.03.2017
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| Abstract | Stereoelectronic factors account for the apparent reversal of donor–acceptor properties of a variety of functional groups by a simple change of their orientation in space. The new reactivity patterns that arise from spatial anisotropy are associated with chameleonic behavior of common organic functionalities.
CHEMeleon: Stereoelectronic factors account for the apparent reversal of donor–acceptor properties of a variety of functional groups by a simple change of their orientation in space. The new reactivity patterns that arise from spatial anisotropy are associated with chameleonic behavior of common organic functionalities. |
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| AbstractList | Stereoelectronic factors account for the apparent reversal of donor–acceptor properties of a variety of functional groups by a simple change of their orientation in space. The new reactivity patterns that arise from spatial anisotropy are associated with chameleonic behavior of common organic functionalities. Stereoelectronic factors account for the apparent reversal of donor–acceptor properties of a variety of functional groups by a simple change of their orientation in space. The new reactivity patterns that arise from spatial anisotropy are associated with chameleonic behavior of common organic functionalities. CHEMeleon: Stereoelectronic factors account for the apparent reversal of donor–acceptor properties of a variety of functional groups by a simple change of their orientation in space. The new reactivity patterns that arise from spatial anisotropy are associated with chameleonic behavior of common organic functionalities. Stereoelectronic factors account for the apparent reversal of donor-acceptor properties of a variety of functional groups by a simple change of their orientation in space. The new reactivity patterns that arise from spatial anisotropy are associated with chameleonic behavior of common organic functionalities.Stereoelectronic factors account for the apparent reversal of donor-acceptor properties of a variety of functional groups by a simple change of their orientation in space. The new reactivity patterns that arise from spatial anisotropy are associated with chameleonic behavior of common organic functionalities. Stereoelectronic factors account for the apparent reversal of donor-acceptor properties of a variety of functional groups by a simple change of their orientation in space. The new reactivity patterns that arise from spatial anisotropy are associated with chameleonic behavior of common organic functionalities. CHEMeleon: Stereoelectronic factors account for the apparent reversal of donor-acceptor properties of a variety of functional groups by a simple change of their orientation in space. The new reactivity patterns that arise from spatial anisotropy are associated with chameleonic behavior of common organic functionalities. |
| Author | Alabugin, Igor V. Vatsadze, Sergey Z. dos Passos Gomes, Gabriel Loginova, Yulia D. |
| Author_xml | – sequence: 1 givenname: Sergey Z. orcidid: 0000-0001-7884-8579 surname: Vatsadze fullname: Vatsadze, Sergey Z. email: szv@org.chem.msu.ru organization: Lomonosov Moscow State University – sequence: 2 givenname: Yulia D. surname: Loginova fullname: Loginova, Yulia D. organization: Lomonosov Moscow State University – sequence: 3 givenname: Gabriel orcidid: 0000-0002-8235-5969 surname: dos Passos Gomes fullname: dos Passos Gomes, Gabriel organization: Florida State University – sequence: 4 givenname: Igor V. orcidid: 0000-0001-9289-3819 surname: Alabugin fullname: Alabugin, Igor V. email: alabugin@chem.fsu.edu organization: Florida State University |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/27862399$$D View this record in MEDLINE/PubMed |
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| Keywords | donors functional groups stereoelectronic effects reactive intermediates acceptors |
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| Snippet | Stereoelectronic factors account for the apparent reversal of donor–acceptor properties of a variety of functional groups by a simple change of their... Stereoelectronic factors account for the apparent reversal of donor-acceptor properties of a variety of functional groups by a simple change of their... |
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| SubjectTerms | acceptors Anisotropy Chemistry Dichotomies donors Functional groups Orientation reactive intermediates stereoelectronic effects |
| Title | Stereoelectronic Chameleons: The Donor–Acceptor Dichotomy of Functional Groups |
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