Functionalization of graphitic C 3 N 5 with Pd nanoparticles: An efficient photocatalyst for Suzuki‐Miyaura coupling reaction
Utilizing sunlight as a driving force in chemical reactions is a great benefit for a sustainable future. Metal‐based composites are basic components in various catalytic reactions. However, few researches reported carbon nitride‐supported Pd nanoparticles in photocatalytic coupling reactions. This s...
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| Published in | Applied organometallic chemistry Vol. 37; no. 10 |
|---|---|
| Main Authors | , |
| Format | Journal Article |
| Language | English |
| Published |
01.10.2023
|
| Online Access | Get full text |
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| Abstract | Utilizing sunlight as a driving force in chemical reactions is a great benefit for a sustainable future. Metal‐based composites are basic components in various catalytic reactions. However, few researches reported carbon nitride‐supported Pd nanoparticles in photocatalytic coupling reactions. This study reports the preparation of a graphitic‐carbon nitride system (C
3
N
5
) followed by modification with various amounts of Pd nanoparticles. The C
3
N
5
was synthesized by thermal deammoniation of melem hydrazine precursor and then modified by Pd cations to create a metallic composite. Regarding the N‐rich surface of C
3
N
5
, Pd
2+
cations are rapidly reduced to Pd nanoparticles in mild conditions, which is strongly supported by X‐ray photoelectron spectroscopy (XPS) and X‐ray diffraction (XRD) analyses. Moreover, field emission scanning electron microscopy (FESEM) and high‐resolution transmission electron microscopy (HRTEM) analyses clearly depicted the formation of 20 nm Pd nanoparticles on the surface of C
3
N
5
. The obtained Pd/C
3
N
5
composite exhibited prominent photocatalytic performance for Suzuki‐Miyaura coupling reactions (91% during 25 min at room temperature). This study also compares the effect of various amounts of Pd cation in the progress of Suzuki‐Miyaura coupling reactions. |
|---|---|
| AbstractList | Utilizing sunlight as a driving force in chemical reactions is a great benefit for a sustainable future. Metal‐based composites are basic components in various catalytic reactions. However, few researches reported carbon nitride‐supported Pd nanoparticles in photocatalytic coupling reactions. This study reports the preparation of a graphitic‐carbon nitride system (C
3
N
5
) followed by modification with various amounts of Pd nanoparticles. The C
3
N
5
was synthesized by thermal deammoniation of melem hydrazine precursor and then modified by Pd cations to create a metallic composite. Regarding the N‐rich surface of C
3
N
5
, Pd
2+
cations are rapidly reduced to Pd nanoparticles in mild conditions, which is strongly supported by X‐ray photoelectron spectroscopy (XPS) and X‐ray diffraction (XRD) analyses. Moreover, field emission scanning electron microscopy (FESEM) and high‐resolution transmission electron microscopy (HRTEM) analyses clearly depicted the formation of 20 nm Pd nanoparticles on the surface of C
3
N
5
. The obtained Pd/C
3
N
5
composite exhibited prominent photocatalytic performance for Suzuki‐Miyaura coupling reactions (91% during 25 min at room temperature). This study also compares the effect of various amounts of Pd cation in the progress of Suzuki‐Miyaura coupling reactions. |
| Author | Mohammadikish, Maryam Mosleh, Nazanin |
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| CitedBy_id | crossref_primary_10_1016_j_electacta_2024_144485 crossref_primary_10_1039_D3CP04431A crossref_primary_10_1002_slct_202304147 crossref_primary_10_1039_D3MH02092D |
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| Title | Functionalization of graphitic C 3 N 5 with Pd nanoparticles: An efficient photocatalyst for Suzuki‐Miyaura coupling reaction |
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