Ru@C as a safety‐release RuO 3 @C catalyst precursor for selective oxidative cleavage of alkenes to aldehydes or ketones and alkynes to 1, 2‐diketones

• Published in: Applied organometallic chemistry Vol. 36; no. 10
• Main Authors: Wang, Yuguang, Liu, Hengliang, Cai, Donglin, Zhou, Jinqiu, Wu, Mengjing, Zheng, Huifang, Xie, Deming
• Format: Journal Article
• Language: English
• Published: 01.10.2022

High‐performance and recyclable high valence oxides of ruthenium catalyst had been released safely from commercially available ruthenium carbon catalyst in situ. They could selectively oxidize C=C bonds to corresponding aldehydes or ketones in 78%–99% yields and C ≡ C bonds to α‐diketones in 93%–99%...