Atmospheric chemistry of nitrogenous aerosols in northeastern Asia: biological sources and secondary formation

To better understand the sources of nitrogenous aerosols, particularly water-soluble organic nitrogen (WSON) and water-insoluble organic nitrogen (WION), in northeastern Asia, we measured total nitrogen (TN) and water-soluble total nitrogen (WSTN) as well as nitrogen isotope ratios ( delta 15N) of T...

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Published inAtmospheric chemistry and physics Vol. 15; no. 17; pp. 9883 - 9896
Main Authors Pavuluri, C M, Kawamura, K, Fu, P Q
Format Journal Article
LanguageEnglish
Published Katlenburg-Lindau Copernicus GmbH 02.09.2015
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Abstract To better understand the sources of nitrogenous aerosols, particularly water-soluble organic nitrogen (WSON) and water-insoluble organic nitrogen (WION), in northeastern Asia, we measured total nitrogen (TN) and water-soluble total nitrogen (WSTN) as well as nitrogen isotope ratios ( delta 15N) of TN ( delta 15NTN) and WSTN ( delta 15NWSTN) in the total suspended particulate (TSP) samples collected from Sapporo, northern Japan, for a 1-year period. In general, WION was more abundant (126 plus or minus 117 ng m-3), whereas WSON was 89.7 plus or minus 80.6 ng m-3, accounting for 14 plus or minus 11 % and 9.2 plus or minus 7.3 % of TN, respectively. WSON peaked in late autumn to winter (maximum 288 ng m-3) and WION peaked in mid-spring to early summer (454 ng m-3). delta 15NTN (21.9 plus or minus 4.1 ppt) and delta 15NWSTN (25.8 plus or minus 8.2 ppt) showed peaks in summer with relatively high ratios in late autumn. Based on the seasonal variations in WSON and WION together with organic tracers, fossil fuel combustion and biomass burning are found to be two major sources of WSON, whereas emissions of biological particles and secondary formation by reactions of biogenic secondary organic species (carbonyls) with NH3 are suggested as an important source of WION. The seasonality of delta 15NTN and delta 15NWSTN, together with the comparisons to literature values, implies that chemical aging (including gas-particle partitioning) and biomass burning are the causes of the enhanced values in summer and autumn, respectively. This study demonstrates that contributions of aerosol N from fossil fuel combustion and biomass burning dominate in autumn and/or winter, whereas emission of terrestrial biological particles and secondary formation from biogenic hydrocarbons and subsequent chemical aging in the atmosphere are important in spring and/or summer in northeastern Asia.
AbstractList To better understand the sources of nitrogenous aerosols, particularly water-soluble organic nitrogen (WSON) and water-insoluble organic nitrogen (WION), in northeastern Asia, we measured total nitrogen (TN) and water-soluble total nitrogen (WSTN) as well as nitrogen isotope ratios (δ15N) of TN (δ15NTN) and WSTN (δ15NWSTN) in the total suspended particulate (TSP) samples collected from Sapporo, northern Japan, for a 1-year period. In general, WION was more abundant (126 ± 117 ng m-3), whereas WSON was 89.7 ± 80.6 ng m-3, accounting for 14 ± 11 % and 9.2 ± 7.3 % of TN, respectively. WSON peaked in late autumn to winter (maximum 288 ng m-3) and WION peaked in mid-spring to early summer (454 ng m-3). δ15NTN (21.9 ± 4.1 [per thousand]) and δ15NWSTN (25.8 ± 8.2 [per thousand]) showed peaks in summer with relatively high ratios in late autumn. Based on the seasonal variations in WSON and WION together with organic tracers, fossil fuel combustion and biomass burning are found to be two major sources of WSON, whereas emissions of biological particles and secondary formation by reactions of biogenic secondary organic species (carbonyls) with NH3 are suggested as an important source of WION. The seasonality of δ15NTN and δ15NWSTN, together with the comparisons to literature values, implies that chemical aging (including gas-particle partitioning) and biomass burning are the causes of the enhanced values in summer and autumn, respectively. This study demonstrates that contributions of aerosol N from fossil fuel combustion and biomass burning dominate in autumn and/or winter, whereas emission of terrestrial biological particles and secondary formation from biogenic hydrocarbons and subsequent chemical aging in the atmosphere are important in spring and/or summer in northeastern Asia.
To better understand the sources of nitrogenous aerosols, particularly water-soluble organic nitrogen (WSON) and water-insoluble organic nitrogen (WION), in northeastern Asia, we measured total nitrogen (TN) and water-soluble total nitrogen (WSTN) as well as nitrogen isotope ratios (δ15N) of TN (δ15NTN) and WSTN (δ15NWSTN) in the total suspended particulate (TSP) samples collected from Sapporo, northern Japan, for a 1-year period. In general, WION was more abundant (126±117 ngm-3), whereas WSON was 89.7±80.6 ngm-3, accounting for 14±11 % and 9.2±7.3 % of TN, respectively. WSON peaked in late autumn to winter (maximum 288 ngm-3) and WION peaked in mid-spring to early summer (454 ngm-3). δ15NTN (21.9±4.1 ‰) and δ15NWSTN (25.8±8.2 ‰) showed peaks in summer with relatively high ratios in late autumn. Based on the seasonal variations in WSON and WION together with organic tracers, fossil fuel combustion and biomass burning are found to be two major sources of WSON, whereas emissions of biological particles and secondary formation by reactions of biogenic secondary organic species (carbonyls) with NH3 are suggested as an important source of WION. The seasonality of δ15NTN andδ15NWSTN, together with the comparisons to literature values, implies that chemical aging (including gas–particle partitioning) and biomass burning are the causes of the enhanced values in summer and autumn, respectively. This study demonstrates that contributions of aerosol N from fossil fuel combustion and biomass burning dominate in autumn and/or winter, whereas emission of terrestrial biological particles and secondary formation from biogenic hydrocarbons and subsequent chemical aging in the atmosphere are important in spring and/or summer in northeastern Asia.
To better understand the sources of nitrogenous aerosols, particularly water-soluble organic nitrogen (WSON) and water-insoluble organic nitrogen (WION), in northeastern Asia, we measured total nitrogen (TN) and water-soluble total nitrogen (WSTN) as well as nitrogen isotope ratios (δ15N) of TN (δ15NTN) and WSTN (δ15NWSTN) in the total suspended particulate (TSP) samples collected from Sapporo, northern Japan, for a 1-year period. In general, WION was more abundant (126 ± 117 ng m−3), whereas WSON was 89.7 ± 80.6 ng m−3, accounting for 14 ± 11 % and 9.2 ± 7.3 % of TN, respectively. WSON peaked in late autumn to winter (maximum 288 ng m−3) and WION peaked in mid-spring to early summer (454 ng m−3). δ15NTN (21.9 ± 4.1 ‰) and δ15NWSTN (25.8 ± 8.2 ‰) showed peaks in summer with relatively high ratios in late autumn. Based on the seasonal variations in WSON and WION together with organic tracers, fossil fuel combustion and biomass burning are found to be two major sources of WSON, whereas emissions of biological particles and secondary formation by reactions of biogenic secondary organic species (carbonyls) with NH3 are suggested as an important source of WION. The seasonality of δ15NTN and δ15NWSTN, together with the comparisons to literature values, implies that chemical aging (including gas–particle partitioning) and biomass burning are the causes of the enhanced values in summer and autumn, respectively. This study demonstrates that contributions of aerosol N from fossil fuel combustion and biomass burning dominate in autumn and/or winter, whereas emission of terrestrial biological particles and secondary formation from biogenic hydrocarbons and subsequent chemical aging in the atmosphere are important in spring and/or summer in northeastern Asia.
To better understand the sources of nitrogenous aerosols, particularly water-soluble organic nitrogen (WSON) and water-insoluble organic nitrogen (WION), in northeastern Asia, we measured total nitrogen (TN) and water-soluble total nitrogen (WSTN) as well as nitrogen isotope ratios ( delta 15N) of TN ( delta 15NTN) and WSTN ( delta 15NWSTN) in the total suspended particulate (TSP) samples collected from Sapporo, northern Japan, for a 1-year period. In general, WION was more abundant (126 plus or minus 117 ng m-3), whereas WSON was 89.7 plus or minus 80.6 ng m-3, accounting for 14 plus or minus 11 % and 9.2 plus or minus 7.3 % of TN, respectively. WSON peaked in late autumn to winter (maximum 288 ng m-3) and WION peaked in mid-spring to early summer (454 ng m-3). delta 15NTN (21.9 plus or minus 4.1 ppt) and delta 15NWSTN (25.8 plus or minus 8.2 ppt) showed peaks in summer with relatively high ratios in late autumn. Based on the seasonal variations in WSON and WION together with organic tracers, fossil fuel combustion and biomass burning are found to be two major sources of WSON, whereas emissions of biological particles and secondary formation by reactions of biogenic secondary organic species (carbonyls) with NH3 are suggested as an important source of WION. The seasonality of delta 15NTN and delta 15NWSTN, together with the comparisons to literature values, implies that chemical aging (including gas-particle partitioning) and biomass burning are the causes of the enhanced values in summer and autumn, respectively. This study demonstrates that contributions of aerosol N from fossil fuel combustion and biomass burning dominate in autumn and/or winter, whereas emission of terrestrial biological particles and secondary formation from biogenic hydrocarbons and subsequent chemical aging in the atmosphere are important in spring and/or summer in northeastern Asia.
To better understand the sources of nitrogenous aerosols, particularly water-soluble organic nitrogen (WSON) and water-insoluble organic nitrogen (WION), in northeastern Asia, we measured total nitrogen (TN) and water-soluble total nitrogen (WSTN) as well as nitrogen isotope ratios ([delta].sup.15 N) of TN ([delta].sup.15 N.sub.TN) and WSTN (δ.sup.15 N.sub.WSTN) in the total suspended particulate (TSP) samples collected from Sapporo, northern Japan, for a 1-year period. In general, WION was more abundant (126 ± 117 ng m.sup.−3 ), whereas WSON was 89.7 ± 80.6 ng m.sup.−3, accounting for 14 ± 11 % and 9.2 ± 7.3 % of TN, respectively. WSON peaked in late autumn to winter (maximum 288 ng m.sup.−3) and WION peaked in mid-spring to early summer (454 ng m.sup.−3). [delta].sup.15 N.sub.TN (21.9 ± 4.1 ‰) and [delta].sup.15 N.sub.WSTN (25.8 ± 8.2 ‰) showed peaks in summer with relatively high ratios in late autumn. Based on the seasonal variations in WSON and WION together with organic tracers, fossil fuel combustion and biomass burning are found to be two major sources of WSON, whereas emissions of biological particles and secondary formation by reactions of biogenic secondary organic species (carbonyls) with NH.sub.3 are suggested as an important source of WION. The seasonality of [delta].sup.15 N.sub.TN and [delta].sup.15 N.sub.WSTN, together with the comparisons to literature values, implies that chemical aging (including gas-particle partitioning) and biomass burning are the causes of the enhanced values in summer and autumn, respectively. This study demonstrates that contributions of aerosol N from fossil fuel combustion and biomass burning dominate in autumn and/or winter, whereas emission of terrestrial biological particles and secondary formation from biogenic hydrocarbons and subsequent chemical aging in the atmosphere are important in spring and/or summer in northeastern Asia.
Audience Academic
Author Fu, P Q
Kawamura, K
Pavuluri, C M
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Snippet To better understand the sources of nitrogenous aerosols, particularly water-soluble organic nitrogen (WSON) and water-insoluble organic nitrogen (WION), in...
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SubjectTerms Aerosols
Ageing
Aging
Air pollution
Atmospheric chemistry
Autumn
Biogeochemistry
Biological
Biomass
Biomass burning
Burning
Carbon
Carbonyl compounds
Carbonyls
Combustion
Emissions
Formations
Fossil fuels
Fuel combustion
Gases
Hydrocarbons
Isotope ratios
Nitrates
Nitrogen
Nitrogen (Chemical element)
Nitrogen isotopes
Organic nitrogen
Pollution sources
Ratios
Seasonal variation
Seasonal variations
Seasonality
Spring
Spring (season)
Summer
Suspended particulate matter
Terrestrial environments
Tracers
Water chemistry
Winter
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Title Atmospheric chemistry of nitrogenous aerosols in northeastern Asia: biological sources and secondary formation
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