Synthesis, Spectral Characterization and Crystals Structure of some Arsane Derivatives of Gold (I) Complexes: A Comparative Density Functional Theory Study

• Published in: PloS one Vol. 10; no. 3; p. e0119620
• Main Authors: Shawkataly, Omar bin, Goh, Chin-Ping, Tariq, Abu, Khan, Imthyaz Ahmad, Fun, Hoong-Kun, Rosli, Mohd Mustaqim
• Format: Journal Article
• Language: English
• Published: United States Public Library of Science 23.03.2015; Public Library of Science (PLoS)
• Subjects: Arsenates - chemistry; Arsenic; Chemical properties; Chemistry; Chlorine; Comparative analysis; Coordination Complexes - chemical synthesis; Crystal structure; Crystallography; Crystallography, X-Ray; Crystals; Density functional theory; Distance learning; Education; Electronegativity; Ethane; Gold; Gold - chemistry; Ligands; Magnetic Resonance Spectroscopy; Models, Molecular; NMR spectroscopy; Nuclear magnetic resonance spectroscopy; Quantum Theory; Relativism; Single crystals; Spectroscopy; Spectroscopy, Fourier Transform Infrared; Structural analysis; Studies; X-ray crystallography; X-Ray Diffraction; Penang Malaysia; Malaysia

A series of complexes of the type LAuCl where L = tris(p-tolylarsane), tris(m-tolylarsane), bis(diphenylarsano)ethane, and tris(naphthyl)arsane have been synthesized. All of the new complexes, 1-4, have been fully characterized by means of ¹H NMR and ¹³C NMR spectroscopy and single crystal X-ray cry...