A Chemically Triggered and Thermally Switched Dielectric Constant Transition in a Metal Cyanide Based Crystal
A dielectric constant transition is chemically triggered and thermally switched in (HPy)2[Na(H2O)Co(CN)6] (2, HPy=pyridinium cation) by single‐crystal‐to‐single‐crystal transformation and structural phase transition, respectively. Upon dehydration, (HPy)2[Na(H2O)2Co(CN)6] (1) transforms to its semi‐...
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| Published in | Angewandte Chemie International Edition Vol. 54; no. 21; pp. 6206 - 6210 |
|---|---|
| Main Authors | , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Weinheim
WILEY-VCH Verlag
18.05.2015
WILEY‐VCH Verlag Wiley Subscription Services, Inc |
| Edition | International ed. in English |
| Subjects | |
| Online Access | Get full text |
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| Abstract | A dielectric constant transition is chemically triggered and thermally switched in (HPy)2[Na(H2O)Co(CN)6] (2, HPy=pyridinium cation) by single‐crystal‐to‐single‐crystal transformation and structural phase transition, respectively. Upon dehydration, (HPy)2[Na(H2O)2Co(CN)6] (1) transforms to its semi‐hydrated form 2, accompanying a transition from a low‐dielectric state to a high‐dielectric state, and vice versa. This dielectric switch is also realized by a structural phase transition in 2 that occurs between room‐ and low‐temperature phases, and which corresponds to high‐ and low‐dielectric states, respectively. The switching property is due to the variation in the environment surrounding the HPy cation, that is, the hydrogen‐bonding interactions and the crystal packing, which exert predominant influences on the dynamics of the cations that transit between the static and motional states.
A dielectric constant transition is observed in (HPy)2[Na(H2O)Co(CN)6] (HPy=pyridinium cation). This transition is chemically triggered by water in a single‐crystal‐to‐single‐crystal transformation (see picture; right) and thermally switched (left) in a structural phase transition. |
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| AbstractList | A dielectric constant transition is chemically triggered and thermally switched in (HPy) sub(2)[Na(H sub(2)O)Co(CN) sub(6)] (2, HPy=pyridinium cation) by single-crystal-to-single-crystal transformation and structural phase transition, respectively. Upon dehydration, (HPy) sub(2)[Na(H sub(2)O) sub(2)Co(CN) sub(6)] (1) transforms to its semi-hydrated form 2, accompanying a transition from a low-dielectric state to a high-dielectric state, and vice versa. This dielectric switch is also realized by a structural phase transition in 2 that occurs between room- and low-temperature phases, and which corresponds to high- and low-dielectric states, respectively. The switching property is due to the variation in the environment surrounding the HPy cation, that is, the hydrogen-bonding interactions and the crystal packing, which exert predominant influences on the dynamics of the cations that transit between the static and motional states. A dielectric constant transition is observed in (HPy) sub(2)[Na(H sub(2)O)Co(CN) sub(6)] (HPy=pyridinium cation). This transition is chemically triggered by water in a single-crystal-to-single-crystal transformation (see picture; right) and thermally switched (left) in a structural phase transition. A dielectric constant transition is chemically triggered and thermally switched in (HPy)2[Na(H2O)Co(CN)6] (2, HPy=pyridinium cation) by single-crystal-to-single-crystal transformation and structural phase transition, respectively. Upon dehydration, (HPy)2[Na(H2O)2Co(CN)6] (1) transforms to its semi-hydrated form 2, accompanying a transition from a low-dielectric state to a high-dielectric state, and vice versa. This dielectric switch is also realized by a structural phase transition in 2 that occurs between room- and low-temperature phases, and which corresponds to high- and low-dielectric states, respectively. The switching property is due to the variation in the environment surrounding the HPy cation, that is, the hydrogen-bonding interactions and the crystal packing, which exert predominant influences on the dynamics of the cations that transit between the static and motional states.A dielectric constant transition is chemically triggered and thermally switched in (HPy)2[Na(H2O)Co(CN)6] (2, HPy=pyridinium cation) by single-crystal-to-single-crystal transformation and structural phase transition, respectively. Upon dehydration, (HPy)2[Na(H2O)2Co(CN)6] (1) transforms to its semi-hydrated form 2, accompanying a transition from a low-dielectric state to a high-dielectric state, and vice versa. This dielectric switch is also realized by a structural phase transition in 2 that occurs between room- and low-temperature phases, and which corresponds to high- and low-dielectric states, respectively. The switching property is due to the variation in the environment surrounding the HPy cation, that is, the hydrogen-bonding interactions and the crystal packing, which exert predominant influences on the dynamics of the cations that transit between the static and motional states. A dielectric constant transition is chemically triggered and thermally switched in (HPy)2[Na(H2O)Co(CN)6] (2, HPy=pyridinium cation) by single-crystal-to-single-crystal transformation and structural phase transition, respectively. Upon dehydration, (HPy)2[Na(H2O)2Co(CN)6] (1) transforms to its semi-hydrated form 2, accompanying a transition from a low-dielectric state to a high-dielectric state, and vice versa. This dielectric switch is also realized by a structural phase transition in 2 that occurs between room- and low-temperature phases, and which corresponds to high- and low-dielectric states, respectively. The switching property is due to the variation in the environment surrounding the HPy cation, that is, the hydrogen-bonding interactions and the crystal packing, which exert predominant influences on the dynamics of the cations that transit between the static and motional states. A dielectric constant transition is chemically triggered and thermally switched in (HPy) 2 [Na(H 2 O)Co(CN) 6 ] ( 2 , HPy=pyridinium cation) by single‐crystal‐to‐single‐crystal transformation and structural phase transition, respectively. Upon dehydration, (HPy) 2 [Na(H 2 O) 2 Co(CN) 6 ] ( 1 ) transforms to its semi‐hydrated form 2 , accompanying a transition from a low‐dielectric state to a high‐dielectric state, and vice versa. This dielectric switch is also realized by a structural phase transition in 2 that occurs between room‐ and low‐temperature phases, and which corresponds to high‐ and low‐dielectric states, respectively. The switching property is due to the variation in the environment surrounding the HPy cation, that is, the hydrogen‐bonding interactions and the crystal packing, which exert predominant influences on the dynamics of the cations that transit between the static and motional states. A dielectric constant transition is chemically triggered and thermally switched in (HPy)2[Na(H2O)Co(CN)6] (2, HPy=pyridinium cation) by single‐crystal‐to‐single‐crystal transformation and structural phase transition, respectively. Upon dehydration, (HPy)2[Na(H2O)2Co(CN)6] (1) transforms to its semi‐hydrated form 2, accompanying a transition from a low‐dielectric state to a high‐dielectric state, and vice versa. This dielectric switch is also realized by a structural phase transition in 2 that occurs between room‐ and low‐temperature phases, and which corresponds to high‐ and low‐dielectric states, respectively. The switching property is due to the variation in the environment surrounding the HPy cation, that is, the hydrogen‐bonding interactions and the crystal packing, which exert predominant influences on the dynamics of the cations that transit between the static and motional states. A dielectric constant transition is observed in (HPy)2[Na(H2O)Co(CN)6] (HPy=pyridinium cation). This transition is chemically triggered by water in a single‐crystal‐to‐single‐crystal transformation (see picture; right) and thermally switched (left) in a structural phase transition. |
| Author | Cai, Ying Shi, Chao Zhang, Xi Yao, Ye-Feng Zhang, Wen |
| Author_xml | – sequence: 1 givenname: Chao surname: Shi fullname: Shi, Chao organization: Ordered Matter Science Research Center, Southeast University, Nanjing 211189, Jiangsu (China) – sequence: 2 givenname: Xi surname: Zhang fullname: Zhang, Xi organization: Department of Physics & Shanghai Key Laboratory of Magnetic Resonance, East China Normal University, North Zhongshan Road 3663, Shanghai 200062 (China) – sequence: 3 givenname: Ying surname: Cai fullname: Cai, Ying organization: Ordered Matter Science Research Center, Southeast University, Nanjing 211189, Jiangsu (China) – sequence: 4 givenname: Ye-Feng surname: Yao fullname: Yao, Ye-Feng email: yfyao@phy.ecnu.edu.cn organization: Department of Physics & Shanghai Key Laboratory of Magnetic Resonance, East China Normal University, North Zhongshan Road 3663, Shanghai 200062 (China) – sequence: 5 givenname: Wen surname: Zhang fullname: Zhang, Wen email: zhangwen@seu.edu.cn organization: Ordered Matter Science Research Center, Southeast University, Nanjing 211189, Jiangsu (China) |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/25832506$$D View this record in MEDLINE/PubMed |
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| Cites_doi | 10.1007/978-94-009-1920-4 10.1021/ja4088709 10.1038/nchem.444 10.1021/ja00311a014 10.1002/ange.201103265 10.1038/nmat2614 10.1021/ja801952e 10.1021/ja206228n 10.1002/anie.200502309 10.1039/C4CC08693G 10.1021/ja3047427 10.1021/ja411233p 10.1002/anie.201103265 10.1021/ja904156s 10.1002/ange.200502309 10.1038/nchem.2092 10.1021/ja3110335 10.1002/ange.200602205 10.1002/anie.201411005 10.1007/128_012 10.1126/science.1137975 10.1002/chem.201402892 10.1002/anie.201408491 10.1006/jmre.2002.2503 10.1021/ja206891q 10.1002/ange.200453923 10.1002/anie.200602205 10.1063/1.1750343 10.1002/anie.201001208 10.1002/ange.201411005 10.1038/nmat2137 10.1021/ja407135k 10.1039/C3TC31378F 10.1002/ange.201408491 10.1038/nmat2377 10.1073/pnas.0502816102 10.1021/ja408405f 10.1021/ja304406c 10.1021/cr200174w 10.1073/pnas.1008213107 10.1002/anie.200453923 10.1002/ange.201001208 10.1021/ja407654n 10.1021/ja4044517 |
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| Copyright | 2015 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim |
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| Keywords | phase transitions cyanide single-crystal-to-single-crystal transformations switchable dielectric constant pyridinium |
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| References | X.-H. Zhao, X.-C. Huang, S.-L. Zhang, D. Shao, H.-Y. Wei, X.-Y. Wang, J. Am. Chem. Soc. 2013, 135, 16006 C. Serre, C. Mellot-Draznieks, S. Surble, N. Audebrand, Y. Filinchuk, G. Férey, Science 2007, 315, 1828 C. R. Murdock, N. W. McNutt, D. J. Keffer, D. M. Jenkins, J. Am. Chem. Soc. 2014, 136, 671. P. Parhami, B. M. Fung, J. Am. Chem. Soc. 1985, 107, 7304. W. Setaka, K. Yamaguchi, J. Am. Chem. Soc. 2013, 135, 14560. Angew. Chem. 2010, 122, 6758 A. K. Jonscher, Dielectric Relaxation in Solids, Chelsea Dielectrics Press, London, 1983. H. Fröhlich, Theory of dielectrics, 2nd ed., Oxford University Press, Oxford, 1965. C. L. Chen, A. M. Goforth, M. D. Smith, C.-Y. Su, H. C. zur Loye, Angew. Chem. Int. Ed. 2005, 44, 6673 R. Shang, Z.-M. Wang, S. Gao, Angew. Chem. Int. Ed. 2015, 54, 2534 C. Lemouchi, K. Iliopoulos, L. Zorina, S. Simonov, P. Wzietek, T. Cauchy, A. Rodríguez-Fortea, E. Canadell, J. Kaleta, J. Michl, D. Gindre, M. Chrysos, P. Batail, J. Am. Chem. Soc. 2013, 135, 9366. D.-W. Fu, W. Zhang, H.-L. Cai, Y. Zhang, J.-Z. Ge, R.-G. Xiong, S. D. Huang, T. Nakamura, Angew. Chem. Int. Ed. 2011, 50, 11947 T. K. Maji, K. Uemura, H.-C. Chang, R. Matsuda, S. Kitagawa, Angew. Chem. Int. Ed. 2004, 43, 3269 W. Zhang, Y. Cai, R.-G. Xiong, H. Yoshikawa, K. Awaga, Angew. Chem. Int. Ed. 2010, 49, 6608 Y. A. Izyumov, V. N. Syromyatnikov, Phase Transitions and Crystal Symmetry, Kluwer, Dordrecht, 1990. E. Coronado, M. Giménez-Marqués, G. M. Espallargas, F. Rey, I. J. Vitórica-Yrezábal, J. Am. Chem. Soc. 2013, 135, 15986. S. D. Karlen, H. Reyes, R. E. Taylor, S. I. Khan, M. F. Hawthorne, M. A. Garcia-Garibay, Proc. Natl. Acad. Sci. USA 2010, 107, 14973. T. Akutagawa, H. Koshinaka, D. Sato, S. Takeda, S. Noro, H. Takahashi, R. Kumai, Y. Tokura, T. Nakamura, Nat. Mater. 2009, 8, 342 Angew. Chem. 2005, 117, 6831 W. Zhang, R. G. Xiong, Chem. Rev. 2012, 112, 1163. S. D. Karlen, M. A. Garcia-Garibay, Top. Curr. Chem. 2005, 262, 179 Z.-Y. Du, T.-T. Xu, B. Huang, Y.-J. Su, W. Xue, C.-T. He, W.-X. Zhang, X.-M. Chen, Angew. Chem. Int. Ed. 2015, 54, 914 S. F. Liu, J. D. Mao, K. Schmidt-Rohr, J. Magn. Reson. 2002, 155, 15 M. A. Garcia-Garibay, Proc. Natl. Acad. Sci. USA 2005, 102, 10771 Angew. Chem. 2015, 127, 928 A. Comotti, S. Bracco, A. Yamamoto, M. Beretta, T. Hirukawa, N. Tohnai, M. Miyata, P. Sozzani, J. Am. Chem. Soc. 2014, 136, 618. J. A. Rodríguez-Velamazán, M. A. González, J. A. Real, M. Castro, M. C. Muñoz, A. B. Gaspar, R. Ohtani, M. Ohba, K. Yoneda, Y. Hijikata, N. Yanai, M. Mizuno, H. Ando, S. Kitagawa, J. Am. Chem. Soc. 2012, 134, 5083. Z.-S. Yao, M. Mito, T. Kamachi, Y. Shiota, K. Yoshizawa, N. Azuma, Y. Miyazaki, K. Takahashi, K. Zhang, T. Nakanishi, S. Kang, S. Kanegawa, O. Sato, Nat. Chem. 2014, 6, 1079. S. Horike, S. Shimomura, S. Kitagawa, Nat. Chem. 2009, 1, 695. J. G. Kirkwood, J. Chem. Phys. 1939, 7, 911. O. Sato, J. Tao, Y.-Z. Zhang, Angew. Chem. Int. Ed. 2007, 46, 2152 W. Zhang, H.-Y. Ye, R. Graf, H. W. Spiess, Y.-F. Yao, R.-Q. Zhu, R.-G. Xiong, J. Am. Chem. Soc. 2013, 135, 5230 Angew. Chem. 2011, 123, 12153 Angew. Chem. 2004, 116, 3331 Y. Zhang, W. Zhang, S.-H. Li, Q. Ye, H.-L. Cai, F. Deng, R.-G. Xiong, S. D. Huang, J. Am. Chem. Soc. 2012, 134, 11044. P. Jain, N. S. Dalal, B. H. Toby, H. W. Kroto, A. K. Cheetham, J. Am. Chem. Soc. 2008, 130, 10450 Angew. Chem. 2007, 119, 2200. B. Wei, R. Shang, X. Zhang, X.-D. Shao, Y.-F. Yao, Z.-M. Wang, R.-G. Xiong, W. Zhang, Chem. Eur. J. 2014, 20, 8269. G.-C. Xu, W. Zhang, X.-M. Ma, Y.-H. Chen, L. Zhang, H.-L. Cai, Z.-M. Wang, R.-G. Xiong, S. Gao, J. Am. Chem. Soc. 2011, 133, 14948 M. Horie, Y. Suzaki, D. Hashizume, T. Abe, T. Wu, T. Sassa, T. Hosokai, K. Osakada, J. Am. Chem. Soc. 2012, 134, 17932. O. Kahn, Molecular Magnetism, VCH, New York, 1993 P. Jain, V. Ramachandran, R. J. Clark, H. D. Zhou, B. H. Toby, N. S. Dalal, H. W. Kroto, A. K. Cheetham, J. Am. Chem. Soc. 2009, 131, 13625 P. Gütlich, H. A. Goodwin, Top. Curr. Chem. 2004, 233. Angew. Chem. 2015, 127, 2564. X. Zhang, X.-D. Shao, S.-C. Li, Y. Cai, Y.-F. Yao, R.-G. Xiong, W. Zhang, Chem. Commun. 2015, 51, 4568. Handbook of Stimuli-Responsive Materials (Ed.: M. W. Urban), Wiley-VCH, Weinheim, 2011. C.-M. Ji, Z.-H. Sun, S.-Q. Zhang, T.-L. Chen, P. Zhou, J.-H. Luo, J. Mater. Chem. C 2014, 2, 567 S. Horiuchi, Y. Tokura, Nat. Mater. 2008, 7, 357 M. A. C. Stuart, W. T. S. Huck, J. Genzer, M. Müller, C. Ober, M. Stamm, G. B. Sukhorukov, I. Szleifer, V. V. Tsukruk, M. Urban, F. Winnik, S. Zauscher, I. Luzinov, S. Minko, Nat. Mater. 2010, 9, 101. 2004 2004; 43 116 2010; 107 2011 2015; 51 2002; 155 2008; 7 2010 2010; 49 122 1993 2004 1985; 107 2009; 131 2014; 136 2011; 133 2014; 20 2012; 112 2005; 262 2012; 134 2014; 2 2007; 315 1990 2005; 102 2007 2007; 46 119 1965 2015 2015; 54 127 2013; 135 2009; 8 2005 2005; 44 117 1983 2011 2011; 50 123 2009; 1 2014; 6 1939; 7 2008; 130 2010; 9 e_1_2_2_24_2 e_1_2_2_4_2 Fröhlich H. (e_1_2_2_20_2) 1965 e_1_2_2_22_2 e_1_2_2_6_2 e_1_2_2_2_2 e_1_2_2_41_2 e_1_2_2_41_3 e_1_2_2_6_3 e_1_2_2_28_2 e_1_2_2_43_2 e_1_2_2_26_2 e_1_2_2_45_2 e_1_2_2_13_2 e_1_2_2_36_2 e_1_2_2_11_3 e_1_2_2_11_2 e_1_2_2_38_2 e_1_2_2_19_3 e_1_2_2_19_2 e_1_2_2_30_2 Jonscher A. K. (e_1_2_2_47_2) 1983 e_1_2_2_17_2 e_1_2_2_32_2 e_1_2_2_15_2 e_1_2_2_34_2 (e_1_2_2_1_2) 2011 e_1_2_2_3_2 e_1_2_2_23_2 e_1_2_2_48_2 e_1_2_2_5_2 Kahn O. (e_1_2_2_8_2) 1993 e_1_2_2_21_2 e_1_2_2_40_2 e_1_2_2_29_3 e_1_2_2_29_2 e_1_2_2_42_2 e_1_2_2_7_2 e_1_2_2_42_3 e_1_2_2_27_2 e_1_2_2_44_2 e_1_2_2_25_2 e_1_2_2_46_2 Gütlich P. (e_1_2_2_9_2) 2004 e_1_2_2_12_2 e_1_2_2_37_2 e_1_2_2_10_2 e_1_2_2_39_2 e_1_2_2_18_3 e_1_2_2_18_2 e_1_2_2_31_2 e_1_2_2_16_2 e_1_2_2_33_2 e_1_2_2_14_2 e_1_2_2_35_2 |
| References_xml | – reference: S. Horiuchi, Y. Tokura, Nat. Mater. 2008, 7, 357; – reference: M. A. Garcia-Garibay, Proc. Natl. Acad. Sci. USA 2005, 102, 10771; – reference: Angew. Chem. 2004, 116, 3331; – reference: Y. A. Izyumov, V. N. Syromyatnikov, Phase Transitions and Crystal Symmetry, Kluwer, Dordrecht, 1990. – reference: Angew. Chem. 2011, 123, 12153; – reference: O. Sato, J. Tao, Y.-Z. Zhang, Angew. Chem. Int. Ed. 2007, 46, 2152; – reference: M. Horie, Y. Suzaki, D. Hashizume, T. Abe, T. Wu, T. Sassa, T. Hosokai, K. Osakada, J. Am. Chem. Soc. 2012, 134, 17932. – reference: G.-C. Xu, W. Zhang, X.-M. Ma, Y.-H. Chen, L. Zhang, H.-L. Cai, Z.-M. Wang, R.-G. Xiong, S. Gao, J. Am. Chem. Soc. 2011, 133, 14948; – reference: S. Horike, S. Shimomura, S. Kitagawa, Nat. Chem. 2009, 1, 695. – reference: H. Fröhlich, Theory of dielectrics, 2nd ed., Oxford University Press, Oxford, 1965. – reference: M. A. C. Stuart, W. T. S. Huck, J. Genzer, M. Müller, C. Ober, M. Stamm, G. B. Sukhorukov, I. Szleifer, V. V. Tsukruk, M. Urban, F. Winnik, S. Zauscher, I. Luzinov, S. Minko, Nat. Mater. 2010, 9, 101. – reference: B. Wei, R. Shang, X. Zhang, X.-D. Shao, Y.-F. Yao, Z.-M. Wang, R.-G. Xiong, W. Zhang, Chem. Eur. J. 2014, 20, 8269. – reference: Z.-S. Yao, M. Mito, T. Kamachi, Y. Shiota, K. Yoshizawa, N. Azuma, Y. Miyazaki, K. Takahashi, K. Zhang, T. Nakanishi, S. Kang, S. Kanegawa, O. Sato, Nat. Chem. 2014, 6, 1079. – reference: Z.-Y. Du, T.-T. Xu, B. Huang, Y.-J. Su, W. Xue, C.-T. He, W.-X. Zhang, X.-M. Chen, Angew. Chem. Int. Ed. 2015, 54, 914; – reference: X. Zhang, X.-D. Shao, S.-C. Li, Y. Cai, Y.-F. Yao, R.-G. Xiong, W. Zhang, Chem. Commun. 2015, 51, 4568. – reference: A. K. Jonscher, Dielectric Relaxation in Solids, Chelsea Dielectrics Press, London, 1983. – reference: X.-H. Zhao, X.-C. Huang, S.-L. Zhang, D. Shao, H.-Y. Wei, X.-Y. Wang, J. Am. Chem. Soc. 2013, 135, 16006; – reference: C. Serre, C. Mellot-Draznieks, S. Surble, N. Audebrand, Y. Filinchuk, G. Férey, Science 2007, 315, 1828; – reference: Angew. Chem. 2015, 127, 928; – reference: Angew. Chem. 2007, 119, 2200. – reference: W. Zhang, Y. Cai, R.-G. Xiong, H. Yoshikawa, K. Awaga, Angew. Chem. Int. Ed. 2010, 49, 6608; – reference: A. Comotti, S. Bracco, A. Yamamoto, M. Beretta, T. Hirukawa, N. Tohnai, M. Miyata, P. Sozzani, J. Am. Chem. Soc. 2014, 136, 618. – reference: C. Lemouchi, K. Iliopoulos, L. Zorina, S. Simonov, P. Wzietek, T. Cauchy, A. Rodríguez-Fortea, E. Canadell, J. Kaleta, J. Michl, D. Gindre, M. Chrysos, P. Batail, J. Am. Chem. Soc. 2013, 135, 9366. – reference: W. Setaka, K. Yamaguchi, J. Am. Chem. Soc. 2013, 135, 14560. – reference: W. Zhang, H.-Y. Ye, R. Graf, H. W. Spiess, Y.-F. Yao, R.-Q. Zhu, R.-G. Xiong, J. Am. Chem. Soc. 2013, 135, 5230; – reference: R. Shang, Z.-M. Wang, S. Gao, Angew. Chem. Int. Ed. 2015, 54, 2534; – reference: Y. Zhang, W. Zhang, S.-H. Li, Q. Ye, H.-L. Cai, F. Deng, R.-G. Xiong, S. D. Huang, J. Am. Chem. Soc. 2012, 134, 11044. – reference: S. F. Liu, J. D. Mao, K. Schmidt-Rohr, J. Magn. Reson. 2002, 155, 15; – reference: Angew. Chem. 2010, 122, 6758; – reference: S. D. Karlen, H. Reyes, R. E. Taylor, S. I. Khan, M. F. Hawthorne, M. A. Garcia-Garibay, Proc. Natl. Acad. Sci. USA 2010, 107, 14973. – reference: J. G. Kirkwood, J. Chem. Phys. 1939, 7, 911. – reference: Handbook of Stimuli-Responsive Materials (Ed.: M. W. Urban), Wiley-VCH, Weinheim, 2011. – reference: D.-W. Fu, W. Zhang, H.-L. Cai, Y. Zhang, J.-Z. Ge, R.-G. Xiong, S. D. Huang, T. Nakamura, Angew. Chem. Int. Ed. 2011, 50, 11947; – reference: T. K. Maji, K. Uemura, H.-C. Chang, R. Matsuda, S. Kitagawa, Angew. Chem. Int. Ed. 2004, 43, 3269; – reference: Angew. Chem. 2005, 117, 6831; – reference: C. L. Chen, A. M. Goforth, M. D. Smith, C.-Y. Su, H. C. zur Loye, Angew. Chem. Int. Ed. 2005, 44, 6673; – reference: P. Gütlich, H. A. Goodwin, Top. Curr. Chem. 2004, 233. – reference: C. R. Murdock, N. W. McNutt, D. J. Keffer, D. M. Jenkins, J. Am. Chem. Soc. 2014, 136, 671. – reference: T. Akutagawa, H. Koshinaka, D. Sato, S. Takeda, S. Noro, H. Takahashi, R. Kumai, Y. Tokura, T. Nakamura, Nat. Mater. 2009, 8, 342; – reference: P. Jain, V. Ramachandran, R. J. Clark, H. D. Zhou, B. H. Toby, N. S. Dalal, H. W. Kroto, A. K. Cheetham, J. Am. Chem. Soc. 2009, 131, 13625; – reference: S. D. Karlen, M. A. Garcia-Garibay, Top. Curr. Chem. 2005, 262, 179; – reference: C.-M. Ji, Z.-H. Sun, S.-Q. Zhang, T.-L. Chen, P. Zhou, J.-H. Luo, J. Mater. Chem. C 2014, 2, 567; – reference: O. Kahn, Molecular Magnetism, VCH, New York, 1993; – reference: P. Parhami, B. M. Fung, J. Am. Chem. Soc. 1985, 107, 7304. – reference: W. Zhang, R. G. Xiong, Chem. Rev. 2012, 112, 1163. – reference: J. A. Rodríguez-Velamazán, M. A. González, J. A. Real, M. Castro, M. C. Muñoz, A. B. Gaspar, R. Ohtani, M. Ohba, K. Yoneda, Y. Hijikata, N. Yanai, M. Mizuno, H. Ando, S. Kitagawa, J. Am. Chem. Soc. 2012, 134, 5083. – reference: E. Coronado, M. Giménez-Marqués, G. M. Espallargas, F. Rey, I. J. Vitórica-Yrezábal, J. Am. Chem. Soc. 2013, 135, 15986. – reference: P. Jain, N. S. Dalal, B. H. Toby, H. W. Kroto, A. K. Cheetham, J. Am. Chem. Soc. 2008, 130, 10450; – reference: Angew. Chem. 2015, 127, 2564. – year: 2011 – volume: 134 start-page: 5083 year: 2012 publication-title: J. Am. Chem. Soc. – volume: 46 119 start-page: 2152 2200 year: 2007 2007 publication-title: Angew. Chem. Int. Ed. Angew. Chem. – volume: 131 start-page: 13625 year: 2009 publication-title: J. Am. Chem. Soc. – volume: 102 start-page: 10771 year: 2005 publication-title: Proc. Natl. Acad. Sci. USA – year: 1983 – volume: 54 127 start-page: 2534 2564 year: 2015 2015 publication-title: Angew. Chem. Int. Ed. Angew. Chem. – volume: 107 start-page: 14973 year: 2010 publication-title: Proc. Natl. Acad. Sci. USA – volume: 8 start-page: 342 year: 2009 publication-title: Nat. Mater. – volume: 6 start-page: 1079 year: 2014 publication-title: Nat. Chem. – volume: 135 start-page: 16006 year: 2013 publication-title: J. Am. Chem. Soc. – volume: 315 start-page: 1828 year: 2007 publication-title: Science – volume: 1 start-page: 695 year: 2009 publication-title: Nat. Chem. – volume: 2 start-page: 567 year: 2014 publication-title: J. Mater. Chem. C – volume: 134 start-page: 17932 year: 2012 publication-title: J. Am. Chem. Soc. – volume: 135 start-page: 15986 year: 2013 publication-title: J. Am. Chem. Soc. – volume: 155 start-page: 15 year: 2002 publication-title: J. Magn. Reson. – volume: 262 start-page: 179 year: 2005 publication-title: Top. Curr. Chem. – volume: 7 start-page: 357 year: 2008 publication-title: Nat. Mater. – volume: 49 122 start-page: 6608 6758 year: 2010 2010 publication-title: Angew. Chem. Int. Ed. Angew. Chem. – volume: 50 123 start-page: 11947 12153 year: 2011 2011 publication-title: Angew. Chem. Int. Ed. Angew. Chem. – volume: 112 start-page: 1163 year: 2012 publication-title: Chem. Rev. – volume: 136 start-page: 618 year: 2014 publication-title: J. Am. Chem. Soc. – year: 1990 – start-page: 233 year: 2004 publication-title: Top. Curr. Chem. – volume: 133 start-page: 14948 year: 2011 publication-title: J. Am. Chem. Soc. – volume: 135 start-page: 5230 year: 2013 publication-title: J. Am. Chem. Soc. – volume: 7 start-page: 911 year: 1939 publication-title: J. Chem. Phys. – volume: 44 117 start-page: 6673 6831 year: 2005 2005 publication-title: Angew. Chem. Int. Ed. Angew. Chem. – volume: 9 start-page: 101 year: 2010 publication-title: Nat. Mater. – volume: 136 start-page: 671 year: 2014 publication-title: J. Am. Chem. Soc. – volume: 20 start-page: 8269 year: 2014 publication-title: Chem. Eur. J. – year: 1965 – volume: 130 start-page: 10450 year: 2008 publication-title: J. Am. Chem. Soc. – volume: 107 start-page: 7304 year: 1985 publication-title: J. Am. Chem. Soc. – volume: 43 116 start-page: 3269 3331 year: 2004 2004 publication-title: Angew. Chem. Int. Ed. Angew. Chem. – volume: 51 start-page: 4568 year: 2015 publication-title: Chem. Commun. – volume: 135 start-page: 9366 year: 2013 publication-title: J. Am. Chem. Soc. – volume: 135 start-page: 14560 year: 2013 publication-title: J. Am. Chem. Soc. – volume: 134 start-page: 11044 year: 2012 publication-title: J. Am. Chem. Soc. – year: 1993 – volume: 54 127 start-page: 914 928 year: 2015 2015 publication-title: Angew. Chem. Int. Ed. Angew. Chem. – ident: e_1_2_2_21_2 doi: 10.1007/978-94-009-1920-4 – ident: e_1_2_2_37_2 doi: 10.1021/ja4088709 – ident: e_1_2_2_3_2 doi: 10.1038/nchem.444 – ident: e_1_2_2_46_2 doi: 10.1021/ja00311a014 – ident: e_1_2_2_29_3 doi: 10.1002/ange.201103265 – ident: e_1_2_2_2_2 doi: 10.1038/nmat2614 – ident: e_1_2_2_15_2 doi: 10.1021/ja801952e – ident: e_1_2_2_33_2 doi: 10.1021/ja206228n – ident: e_1_2_2_42_2 doi: 10.1002/anie.200502309 – volume-title: Dielectric Relaxation in Solids year: 1983 ident: e_1_2_2_47_2 – ident: e_1_2_2_14_2 – ident: e_1_2_2_22_2 – ident: e_1_2_2_13_2 doi: 10.1039/C4CC08693G – ident: e_1_2_2_31_2 doi: 10.1021/ja3047427 – ident: e_1_2_2_38_2 doi: 10.1021/ja411233p – ident: e_1_2_2_29_2 doi: 10.1002/anie.201103265 – ident: e_1_2_2_28_2 doi: 10.1021/ja904156s – ident: e_1_2_2_40_2 – ident: e_1_2_2_42_3 doi: 10.1002/ange.200502309 – ident: e_1_2_2_39_2 doi: 10.1038/nchem.2092 – ident: e_1_2_2_12_2 doi: 10.1021/ja3110335 – ident: e_1_2_2_6_3 doi: 10.1002/ange.200602205 – ident: e_1_2_2_19_2 doi: 10.1002/anie.201411005 – ident: e_1_2_2_24_2 doi: 10.1007/128_012 – start-page: 233 year: 2004 ident: e_1_2_2_9_2 publication-title: Top. Curr. Chem. – ident: e_1_2_2_43_2 doi: 10.1126/science.1137975 – ident: e_1_2_2_44_2 doi: 10.1002/chem.201402892 – ident: e_1_2_2_18_2 doi: 10.1002/anie.201408491 – ident: e_1_2_2_45_2 doi: 10.1006/jmre.2002.2503 – ident: e_1_2_2_30_2 doi: 10.1021/ja206891q – ident: e_1_2_2_41_3 doi: 10.1002/ange.200453923 – ident: e_1_2_2_6_2 doi: 10.1002/anie.200602205 – ident: e_1_2_2_48_2 doi: 10.1063/1.1750343 – ident: e_1_2_2_11_2 doi: 10.1002/anie.201001208 – ident: e_1_2_2_19_3 doi: 10.1002/ange.201411005 – ident: e_1_2_2_4_2 doi: 10.1038/nmat2137 – volume-title: Handbook of Stimuli‐Responsive Materials year: 2011 ident: e_1_2_2_1_2 – ident: e_1_2_2_36_2 doi: 10.1021/ja407135k – ident: e_1_2_2_10_2 – ident: e_1_2_2_17_2 doi: 10.1039/C3TC31378F – ident: e_1_2_2_7_2 – ident: e_1_2_2_18_3 doi: 10.1002/ange.201408491 – volume-title: Molecular Magnetism year: 1993 ident: e_1_2_2_8_2 – ident: e_1_2_2_27_2 doi: 10.1038/nmat2377 – ident: e_1_2_2_23_2 doi: 10.1073/pnas.0502816102 – ident: e_1_2_2_35_2 doi: 10.1021/ja408405f – ident: e_1_2_2_32_2 doi: 10.1021/ja304406c – ident: e_1_2_2_5_2 doi: 10.1021/cr200174w – ident: e_1_2_2_25_2 doi: 10.1073/pnas.1008213107 – ident: e_1_2_2_41_2 doi: 10.1002/anie.200453923 – ident: e_1_2_2_11_3 doi: 10.1002/ange.201001208 – ident: e_1_2_2_16_2 doi: 10.1021/ja407654n – ident: e_1_2_2_34_2 doi: 10.1021/ja4044517 – volume-title: Theory of dielectrics, 2nd ed. year: 1965 ident: e_1_2_2_20_2 – ident: e_1_2_2_26_2 |
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| Snippet | A dielectric constant transition is chemically triggered and thermally switched in (HPy)2[Na(H2O)Co(CN)6] (2, HPy=pyridinium cation) by... A dielectric constant transition is chemically triggered and thermally switched in (HPy) 2 [Na(H 2 O)Co(CN) 6 ] ( 2 , HPy=pyridinium cation) by... A dielectric constant transition is chemically triggered and thermally switched in (HPy) sub(2)[Na(H sub(2)O)Co(CN) sub(6)] (2, HPy=pyridinium cation) by... |
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| SubjectTerms | Cations Crystals cyanide Dehydration Dielectric constant Low temperature Phase transformations Phase transitions Pictures pyridinium Single crystals single-crystal-to-single-crystal transformations switchable dielectric constant Transformations Transit Vices |
| Title | A Chemically Triggered and Thermally Switched Dielectric Constant Transition in a Metal Cyanide Based Crystal |
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