Bringing Porous Framework Materials toward Photocatalytic H 2 O 2 Production

Photocatalytic H O production driven by renewable solar energy is a promising and sustainable approach, with porous framework materials such as metal-organic frameworks (MOFs), covalent organic frameworks (COFs), and hydrogen-bonded organic frameworks (HOFs) emerging as highly efficient catalysts. T...

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Published inNano letters Vol. 25; no. 11; pp. 4115 - 4136
Main Authors Bao, Chen-Hao, Li, Lan, Wang, Xiao-Fei, Xia, Sa-Sa, Wang, Xusheng, Jin, Cheng-Chao, Chen, Zhi
Format Journal Article
LanguageEnglish
Published United States 19.03.2025
Subjects
Covalent organic frameworks
Metal−organic frameworks
Hydrogen peroxide production
Hydrogen-bonded organic frameworks
Photocatalyst
Porous framework materials
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Abstract Photocatalytic H O production driven by renewable solar energy is a promising and sustainable approach, with porous framework materials such as metal-organic frameworks (MOFs), covalent organic frameworks (COFs), and hydrogen-bonded organic frameworks (HOFs) emerging as highly efficient catalysts. This Review first presents the current research state of porous framework materials in H O photosynthesis, focusing on the progress in H O production across different porous frameworks and mechanism insights gained through advanced techniques. Furthermore, a systematic categorization of material modifications aimed at enhancing the photocatalytic efficiency is provided, linking structural modifications to improved H O production performance. Key factors such as charge carrier separation and transfer, reaction pathways, and material stability are comprehensively analyzed. Finally, the challenges related to stability, scalability, and cost-effectiveness, are discussed alongside opportunities for future advancements. This Review aims to provide insights into understanding and optimizing porous framework materials for efficient and scalable H O photosynthesis.
AbstractList Photocatalytic H O production driven by renewable solar energy is a promising and sustainable approach, with porous framework materials such as metal-organic frameworks (MOFs), covalent organic frameworks (COFs), and hydrogen-bonded organic frameworks (HOFs) emerging as highly efficient catalysts. This Review first presents the current research state of porous framework materials in H O photosynthesis, focusing on the progress in H O production across different porous frameworks and mechanism insights gained through advanced techniques. Furthermore, a systematic categorization of material modifications aimed at enhancing the photocatalytic efficiency is provided, linking structural modifications to improved H O production performance. Key factors such as charge carrier separation and transfer, reaction pathways, and material stability are comprehensively analyzed. Finally, the challenges related to stability, scalability, and cost-effectiveness, are discussed alongside opportunities for future advancements. This Review aims to provide insights into understanding and optimizing porous framework materials for efficient and scalable H O photosynthesis.
Author Chen, Zhi
Wang, Xusheng
Xia, Sa-Sa
Bao, Chen-Hao
Li, Lan
Wang, Xiao-Fei
Jin, Cheng-Chao
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Cites_doi 10.1039/C8CS00155C
10.1007/s12274-022-4301-y
10.1038/s44160-024-00644-z
10.1002/anie.202403926
10.1038/s41563-019-0398-0
10.1002/anie.202408802
10.1016/j.apcatb.2023.122862
10.1016/j.cej.2022.140121
10.1002/anie.202218868
10.1016/j.arabjc.2020.04.027
10.1002/adfm.202106120
10.1002/adfm.202402920
10.1021/acscatal.6b01187
10.1016/j.watres.2013.07.005
10.1039/C1CS15055C
10.1039/D1TA08036A
10.1073/pnas.0603395103
10.1007/s11426-024-2349-x
10.1039/D3DT03237J
10.1016/j.jmst.2024.02.062
10.1002/anie.202316998
10.1021/jacs.2c09482
10.1002/adfm.202311655
10.1039/D3TA01051A
10.1021/acsnano.4c11606
10.1002/anie.202200413
10.1002/anie.201911609
10.1002/smll.202404139
10.1016/j.jcat.2023.115249
10.1016/j.jcat.2024.115488
10.1021/acsaem.1c00371
10.1021/jacs.1c09979
10.1002/anie.202408186
10.1002/adfm.202411077
10.1002/adfm.202300714
10.1038/s41467-024-47023-y
10.1002/adfm.202419978
10.1016/j.cjsc.2024.100466
10.1039/D0TA10944D
10.1002/anie.202305355
10.1016/j.ccr.2024.216022
10.1016/j.ccr.2023.215597
10.1002/anie.202217565
10.1016/j.apcatb.2023.123271
10.1039/C9TA11120D
10.1039/b817735j
10.1021/acs.nanolett.4c01048
10.1021/acscatal.4c01411
10.1038/s41467-023-41522-0
10.1021/jacs.0c09684
10.1002/anie.202309480
10.1002/anie.201901961
10.1021/acs.chemrev.9b00550
10.1039/D0CS00458H
10.1038/s41467-020-18267-1
10.1039/D4QI01580K
10.1002/anie.202320218
10.1002/ange.202404563
10.1021/acscatal.2c03878
10.1002/anie.202414658
10.1002/anie.202308980
10.1021/jacs.4c00681
10.1039/D1CY02166D
10.1002/anie.202423220
10.1039/D1MH00869B
10.1002/anie.202408041
10.1021/acscatal.2c04940
10.1039/D2CC04454D
10.1007/s12274-024-6897-6
10.1002/ange.202405763
10.1016/j.apcatb.2024.124077
10.1002/adma.201904433
10.1016/j.mser.2024.100858
10.1039/D4QI01706D
10.1016/j.jcis.2024.09.189
10.1039/D0CP01759K
10.1002/smll.202404885
10.1016/j.gee.2022.12.010
10.1002/anie.200503779
10.1021/cs400511q
10.1002/anie.202310556
10.1016/j.gee.2022.03.005
10.1016/j.ccr.2023.215210
10.1016/j.apcatb.2022.121859
10.1039/C8CC02679C
10.1002/anie.202202328
10.1039/D4EE03766A
10.3390/molecules28196850
10.1038/s41467-021-22991-7
10.1016/j.jechem.2023.12.029
10.1016/j.jece.2024.113987
10.31635/ccschem.022.202201777
10.1002/anie.202318562
10.1039/C9CC02380A
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Keywords Covalent organic frameworks
Metal−organic frameworks
Hydrogen peroxide production
Hydrogen-bonded organic frameworks
Photocatalyst
Porous framework materials
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References ref45/cit45
ref99/cit99
ref3/cit3
ref81/cit81
ref16/cit16
ref52/cit52
ref23/cit23
ref2/cit2
ref77/cit77
ref71/cit71
ref20/cit20
ref48/cit48
ref74/cit74
ref10/cit10
ref35/cit35
ref89/cit89
ref19/cit19
ref93/cit93
ref42/cit42
ref96/cit96
ref13/cit13
ref61/cit61
ref67/cit67
ref38/cit38
ref90/cit90
ref64/cit64
ref54/cit54
ref6/cit6
ref18/cit18
ref65/cit65
ref97/cit97
ref11/cit11
ref29/cit29
ref76/cit76
ref86/cit86
ref32/cit32
ref39/cit39
ref5/cit5
ref43/cit43
ref80/cit80
ref28/cit28
ref91/cit91
ref55/cit55
ref12/cit12
ref66/cit66
ref22/cit22
ref33/cit33
ref87/cit87
ref44/cit44
ref70/cit70
ref98/cit98
ref9/cit9
ref27/cit27
ref63/cit63
ref56/cit56
ref92/cit92
ref8/cit8
ref31/cit31
ref59/cit59
ref85/cit85
ref34/cit34
ref37/cit37
ref60/cit60
ref88/cit88
ref17/cit17
ref82/cit82
ref53/cit53
ref21/cit21
ref46/cit46
ref49/cit49
ref75/cit75
ref24/cit24
ref50/cit50
ref78/cit78
ref36/cit36
ref83/cit83
ref79/cit79
ref25/cit25
ref72/cit72
ref14/cit14
ref57/cit57
ref51/cit51
ref40/cit40
ref68/cit68
ref94/cit94
ref26/cit26
ref73/cit73
ref69/cit69
ref15/cit15
ref41/cit41
ref58/cit58
ref95/cit95
ref4/cit4
ref30/cit30
ref47/cit47
ref84/cit84
ref1/cit1
ref7/cit7
References_xml – ident: ref32/cit32
  doi: 10.1039/C8CS00155C
– ident: ref67/cit67
  doi: 10.1007/s12274-022-4301-y
– ident: ref76/cit76
  doi: 10.1038/s44160-024-00644-z
– ident: ref84/cit84
  doi: 10.1002/anie.202403926
– ident: ref14/cit14
  doi: 10.1038/s41563-019-0398-0
– ident: ref98/cit98
  doi: 10.1002/anie.202408802
– ident: ref40/cit40
  doi: 10.1016/j.apcatb.2023.122862
– ident: ref94/cit94
  doi: 10.1016/j.cej.2022.140121
– ident: ref8/cit8
– ident: ref38/cit38
  doi: 10.1002/anie.202218868
– ident: ref73/cit73
  doi: 10.1016/j.arabjc.2020.04.027
– ident: ref48/cit48
  doi: 10.1002/adfm.202106120
– ident: ref51/cit51
  doi: 10.1002/adfm.202402920
– ident: ref12/cit12
  doi: 10.1021/acscatal.6b01187
– ident: ref4/cit4
  doi: 10.1016/j.watres.2013.07.005
– ident: ref26/cit26
  doi: 10.1039/C1CS15055C
– ident: ref74/cit74
  doi: 10.1039/D1TA08036A
– ident: ref10/cit10
  doi: 10.1073/pnas.0603395103
– ident: ref19/cit19
  doi: 10.1007/s11426-024-2349-x
– ident: ref56/cit56
  doi: 10.1039/D3DT03237J
– ident: ref28/cit28
  doi: 10.1016/j.jmst.2024.02.062
– ident: ref57/cit57
  doi: 10.1002/anie.202316998
– ident: ref92/cit92
  doi: 10.1021/jacs.2c09482
– ident: ref16/cit16
  doi: 10.1002/adfm.202311655
– ident: ref36/cit36
  doi: 10.1039/D3TA01051A
– ident: ref64/cit64
  doi: 10.1021/acsnano.4c11606
– ident: ref53/cit53
  doi: 10.1002/anie.202200413
– ident: ref2/cit2
  doi: 10.1002/anie.201911609
– ident: ref39/cit39
  doi: 10.1002/smll.202404139
– ident: ref75/cit75
  doi: 10.1016/j.jcat.2023.115249
– ident: ref35/cit35
  doi: 10.1016/j.jcat.2024.115488
– ident: ref42/cit42
  doi: 10.1021/acsaem.1c00371
– ident: ref90/cit90
  doi: 10.1021/jacs.1c09979
– ident: ref71/cit71
  doi: 10.1002/anie.202408186
– ident: ref86/cit86
  doi: 10.1002/adfm.202411077
– ident: ref49/cit49
  doi: 10.1002/adfm.202300714
– ident: ref99/cit99
  doi: 10.1038/s41467-024-47023-y
– ident: ref18/cit18
  doi: 10.1002/adfm.202419978
– ident: ref20/cit20
  doi: 10.1016/j.cjsc.2024.100466
– ident: ref43/cit43
  doi: 10.1039/D0TA10944D
– ident: ref7/cit7
– ident: ref81/cit81
  doi: 10.1002/anie.202305355
– ident: ref21/cit21
  doi: 10.1016/j.ccr.2024.216022
– ident: ref15/cit15
  doi: 10.1016/j.ccr.2023.215597
– ident: ref27/cit27
  doi: 10.1002/anie.202217565
– ident: ref87/cit87
  doi: 10.1016/j.apcatb.2023.123271
– ident: ref70/cit70
  doi: 10.1039/C9TA11120D
– ident: ref25/cit25
  doi: 10.1039/b817735j
– ident: ref78/cit78
  doi: 10.1021/acs.nanolett.4c01048
– ident: ref96/cit96
  doi: 10.1021/acscatal.4c01411
– ident: ref13/cit13
  doi: 10.1038/s41467-023-41522-0
– ident: ref89/cit89
  doi: 10.1021/jacs.0c09684
– ident: ref82/cit82
  doi: 10.1002/anie.202309480
– ident: ref61/cit61
  doi: 10.1002/anie.201901961
– ident: ref29/cit29
  doi: 10.1021/acs.chemrev.9b00550
– ident: ref3/cit3
  doi: 10.1039/D0CS00458H
– ident: ref6/cit6
  doi: 10.1038/s41467-020-18267-1
– ident: ref65/cit65
  doi: 10.1039/D4QI01580K
– ident: ref77/cit77
  doi: 10.1002/anie.202320218
– ident: ref97/cit97
  doi: 10.1002/ange.202404563
– ident: ref79/cit79
  doi: 10.1021/acscatal.2c03878
– ident: ref83/cit83
  doi: 10.1002/anie.202414658
– ident: ref9/cit9
  doi: 10.1002/anie.202308980
– ident: ref59/cit59
  doi: 10.1021/jacs.4c00681
– ident: ref66/cit66
  doi: 10.1039/D1CY02166D
– ident: ref47/cit47
  doi: 10.1002/anie.202423220
– ident: ref60/cit60
  doi: 10.1039/D1MH00869B
– ident: ref46/cit46
  doi: 10.1002/anie.202408041
– ident: ref68/cit68
  doi: 10.1021/acscatal.2c04940
– ident: ref34/cit34
  doi: 10.1039/D2CC04454D
– ident: ref95/cit95
  doi: 10.1007/s12274-024-6897-6
– ident: ref85/cit85
  doi: 10.1002/ange.202405763
– ident: ref52/cit52
  doi: 10.1016/j.apcatb.2024.124077
– ident: ref88/cit88
  doi: 10.1002/adma.201904433
– ident: ref23/cit23
  doi: 10.1016/j.mser.2024.100858
– ident: ref37/cit37
  doi: 10.1021/jacs.0c09684
– ident: ref45/cit45
  doi: 10.1039/D4QI01706D
– ident: ref54/cit54
  doi: 10.1016/j.jcis.2024.09.189
– ident: ref44/cit44
  doi: 10.1039/D0CP01759K
– ident: ref55/cit55
  doi: 10.1002/smll.202404885
– ident: ref24/cit24
  doi: 10.1016/j.gee.2022.12.010
– ident: ref1/cit1
  doi: 10.1002/anie.200503779
– ident: ref11/cit11
  doi: 10.1021/cs400511q
– ident: ref93/cit93
  doi: 10.1002/anie.202310556
– ident: ref5/cit5
  doi: 10.1016/j.gee.2022.03.005
– ident: ref30/cit30
  doi: 10.1016/j.ccr.2023.215210
– ident: ref58/cit58
  doi: 10.1016/j.apcatb.2022.121859
– ident: ref33/cit33
  doi: 10.1039/C8CC02679C
– ident: ref80/cit80
  doi: 10.1002/anie.202202328
– ident: ref17/cit17
  doi: 10.1039/D4EE03766A
– ident: ref41/cit41
  doi: 10.3390/molecules28196850
– ident: ref69/cit69
  doi: 10.1038/s41467-021-22991-7
– ident: ref72/cit72
  doi: 10.1039/D2CC04454D
– ident: ref22/cit22
  doi: 10.1016/j.jechem.2023.12.029
– ident: ref31/cit31
  doi: 10.1016/j.jece.2024.113987
– ident: ref91/cit91
  doi: 10.31635/ccschem.022.202201777
– ident: ref50/cit50
  doi: 10.1002/anie.202318562
– ident: ref63/cit63
  doi: 10.1039/C9CC02380A
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