Nitrogen, Phosphorus, and Sulfur Co-Doped Hollow Carbon Shell as Superior Metal-Free Catalyst for Selective Oxidation of Aromatic Alkanes

Metal‐free heteroatom‐doped carbocatalysts with a high surface area are desirable for catalytic reactions. In this study, we found an efficient strategy to prepare nitrogen, phosphorus, and sulfur co‐doped hollow carbon shells (denote as NPS‐HCS) with a surface area of 1020 m2 g−1. Using a poly(cycl...

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Published inAngewandte Chemie International Edition Vol. 55; no. 12; pp. 4016 - 4020
Main Authors Yang, Shuliang, Peng, Li, Huang, Peipei, Wang, Xiaoshi, Sun, Yongbin, Cao, Changyan, Song, Weiguo
Format Journal Article
LanguageEnglish
Published WEINHEIM Blackwell Publishing Ltd 14.03.2016
Wiley
Wiley Subscription Services, Inc
EditionInternational ed. in English
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Abstract Metal‐free heteroatom‐doped carbocatalysts with a high surface area are desirable for catalytic reactions. In this study, we found an efficient strategy to prepare nitrogen, phosphorus, and sulfur co‐doped hollow carbon shells (denote as NPS‐HCS) with a surface area of 1020 m2 g−1. Using a poly(cyclotriphosphazene‐co‐4,4′‐sulfonyldiphenol) (PZS) shell as carbon source and N, P, S‐doping source, and the ZIF‐67 core as structural template as well as extra N‐doping source, NPS‐HCS were obtained with a high surface area and superhydrophilicity. All these features render the prepared NPS‐HCS a superior metal‐free carbocatalyst for the selective oxidation of aromatic alkanes in aqueous solution. This study provides a reliable and facile route to prepare doped carbocatalysts with enhanced catalytic properties. Highly efficient and selective: A synthetic route was developed to produce nitrogen, phosphorus, and sulfur co‐doped hollow carbon shells which were used as a metal‐free carbocatalyst. The carbocatalyst had a high surface area and showed superior activity in the selective oxidation of aromatic alkanes in aqueous solution.
AbstractList Metal-free heteroatom-doped carbocatalysts with a high surface area are desirable for catalytic reactions. In this study, we found an efficient strategy to prepare nitrogen, phosphorus, and sulfur co-doped hollow carbon shells (denote as NPS-HCS) with a surface area of 1020 m(2)  g(-1). Using a poly(cyclotriphosphazene-co-4,4'-sulfonyldiphenol) (PZS) shell as carbon source and N, P, S-doping source, and the ZIF-67 core as structural template as well as extra N-doping source, NPS-HCS were obtained with a high surface area and superhydrophilicity. All these features render the prepared NPS-HCS a superior metal-free carbocatalyst for the selective oxidation of aromatic alkanes in aqueous solution. This study provides a reliable and facile route to prepare doped carbocatalysts with enhanced catalytic properties.
Metal‐free heteroatom‐doped carbocatalysts with a high surface area are desirable for catalytic reactions. In this study, we found an efficient strategy to prepare nitrogen, phosphorus, and sulfur co‐doped hollow carbon shells (denote as NPS‐HCS) with a surface area of 1020 m2 g−1. Using a poly(cyclotriphosphazene‐co‐4,4′‐sulfonyldiphenol) (PZS) shell as carbon source and N, P, S‐doping source, and the ZIF‐67 core as structural template as well as extra N‐doping source, NPS‐HCS were obtained with a high surface area and superhydrophilicity. All these features render the prepared NPS‐HCS a superior metal‐free carbocatalyst for the selective oxidation of aromatic alkanes in aqueous solution. This study provides a reliable and facile route to prepare doped carbocatalysts with enhanced catalytic properties. Highly efficient and selective: A synthetic route was developed to produce nitrogen, phosphorus, and sulfur co‐doped hollow carbon shells which were used as a metal‐free carbocatalyst. The carbocatalyst had a high surface area and showed superior activity in the selective oxidation of aromatic alkanes in aqueous solution.
Metal-free heteroatom-doped carbocatalysts with a high surface area are desirable for catalytic reactions. In this study, we found an efficient strategy to prepare nitrogen, phosphorus, and sulfur co-doped hollow carbon shells (denote as NPS-HCS) with a surface area of 1020m(2)g(-1). Using a poly(cyclotriphosphazene-co-4,4-sulfonyldiphenol) (PZS) shell as carbon source and N, P, S-doping source, and the ZIF-67 core as structural template as well as extra N-doping source, NPS-HCS were obtained with a high surface area and superhydrophilicity. All these features render the prepared NPS-HCS a superior metal-free carbocatalyst for the selective oxidation of aromatic alkanes in aqueous solution. This study provides a reliable and facile route to prepare doped carbocatalysts with enhanced catalytic properties.
Metal-free heteroatom-doped carbocatalysts with a high surface area are desirable for catalytic reactions. In this study, we found an efficient strategy to prepare nitrogen, phosphorus, and sulfur co-doped hollow carbon shells (denote as NPS-HCS) with a surface area of 1020m2g-1. Using a poly(cyclotriphosphazene-co-4,4'-sulfonyldiphenol) (PZS) shell as carbon source and N, P, S-doping source, and the ZIF-67 core as structural template as well as extra N-doping source, NPS-HCS were obtained with a high surface area and superhydrophilicity. All these features render the prepared NPS-HCS a superior metal-free carbocatalyst for the selective oxidation of aromatic alkanes in aqueous solution. This study provides a reliable and facile route to prepare doped carbocatalysts with enhanced catalytic properties.
Metal‐free heteroatom‐doped carbocatalysts with a high surface area are desirable for catalytic reactions. In this study, we found an efficient strategy to prepare nitrogen, phosphorus, and sulfur co‐doped hollow carbon shells (denote as NPS‐HCS) with a surface area of 1020 m 2  g −1 . Using a poly(cyclotriphosphazene‐ co ‐4,4′‐sulfonyldiphenol) (PZS) shell as carbon source and N, P, S‐doping source, and the ZIF‐67 core as structural template as well as extra N‐doping source, NPS‐HCS were obtained with a high surface area and superhydrophilicity. All these features render the prepared NPS‐HCS a superior metal‐free carbocatalyst for the selective oxidation of aromatic alkanes in aqueous solution. This study provides a reliable and facile route to prepare doped carbocatalysts with enhanced catalytic properties.
Author Sun, Yongbin
Wang, Xiaoshi
Song, Weiguo
Peng, Li
Yang, Shuliang
Huang, Peipei
Cao, Changyan
Author_xml – sequence: 1
  givenname: Shuliang
  surname: Yang
  fullname: Yang, Shuliang
  organization: Beijing National Laboratory for Molecular Sciences, Laboratory of Molecular Nanostructures and Nanotechnology, Institute of Chemistry, Chinese Academy of Sciences, 100190, Beijing, China
– sequence: 2
  givenname: Li
  surname: Peng
  fullname: Peng, Li
  organization: Institute of Chemical Sciences and Engineering, École Polytechnique Fédérale de Lausanne (EPFL), EPFL-ISIC-Valais, 1950, Sion, Switzerland
– sequence: 3
  givenname: Peipei
  surname: Huang
  fullname: Huang, Peipei
  organization: Beijing National Laboratory for Molecular Sciences, Laboratory of Molecular Nanostructures and Nanotechnology, Institute of Chemistry, Chinese Academy of Sciences, 100190, Beijing, China
– sequence: 4
  givenname: Xiaoshi
  surname: Wang
  fullname: Wang, Xiaoshi
  organization: Beijing National Laboratory for Molecular Sciences, Laboratory of Molecular Nanostructures and Nanotechnology, Institute of Chemistry, Chinese Academy of Sciences, 100190, Beijing, China
– sequence: 5
  givenname: Yongbin
  surname: Sun
  fullname: Sun, Yongbin
  organization: Beijing National Laboratory for Molecular Sciences, Laboratory of Molecular Nanostructures and Nanotechnology, Institute of Chemistry, Chinese Academy of Sciences, 100190, Beijing, China
– sequence: 6
  givenname: Changyan
  surname: Cao
  fullname: Cao, Changyan
  email: cycao@iccas.ac.cn
  organization: Beijing National Laboratory for Molecular Sciences, Laboratory of Molecular Nanostructures and Nanotechnology, Institute of Chemistry, Chinese Academy of Sciences, 100190, Beijing, China
– sequence: 7
  givenname: Weiguo
  surname: Song
  fullname: Song, Weiguo
  email: wsong@iccas.ac.cn
  organization: Beijing National Laboratory for Molecular Sciences, Laboratory of Molecular Nanostructures and Nanotechnology, Institute of Chemistry, Chinese Academy of Sciences, 100190, Beijing, China
BackLink https://www.ncbi.nlm.nih.gov/pubmed/26890684$$D View this record in MEDLINE/PubMed
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Issue 12
Keywords MESOPOROUS CARBON
heterogeneous catalysis
selective oxidation
FREE ELECTROCATALYSTS
ALKYLATION
doping
GRAPHENE
BOND FORMATION
NANOSHEETS
POROUS CARBON
HIGHLY EFFICIENT
OXYGEN REDUCTION
carbon
metal-free catalysts
ORGANIC FRAMEWORK
Language English
License http://onlinelibrary.wiley.com/termsAndConditions#vor
2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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Notes Chinese Academy of Sciences
National Natural Science Foundation of China
NSFC - No. 21333009; No. 21573244; No. 21573245
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PublicationTitle Angewandte Chemie International Edition
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SSID ssj0028806
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Snippet Metal‐free heteroatom‐doped carbocatalysts with a high surface area are desirable for catalytic reactions. In this study, we found an efficient strategy to...
Metal-free heteroatom-doped carbocatalysts with a high surface area are desirable for catalytic reactions. In this study, we found an efficient strategy to...
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wiley
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StartPage 4016
SubjectTerms Alkanes
Aqueous solutions
Carbon
Carbon sources
Catalysts
Chemistry
Chemistry, Multidisciplinary
Doping
EGR-1 protein
heterogeneous catalysis
Hydrophilicity
metal-free catalysts
Nitrogen
Oxidation
Phosphorus
Physical Sciences
Science & Technology
selective oxidation
Shells
Sulfur
Surface area
Title Nitrogen, Phosphorus, and Sulfur Co-Doped Hollow Carbon Shell as Superior Metal-Free Catalyst for Selective Oxidation of Aromatic Alkanes
URI https://api.istex.fr/ark:/67375/WNG-CS3X2JZ7-P/fulltext.pdf
https://onlinelibrary.wiley.com/doi/abs/10.1002%2Fanie.201600455
http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=Summon&SrcAuth=ProQuest&DestApp=WOS&DestLinkType=FullRecord&UT=000372660400027
https://www.ncbi.nlm.nih.gov/pubmed/26890684
https://www.proquest.com/docview/1772533716
https://www.proquest.com/docview/1906644948
Volume 55
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