Nitrogen, Phosphorus, and Sulfur Co-Doped Hollow Carbon Shell as Superior Metal-Free Catalyst for Selective Oxidation of Aromatic Alkanes
Metal‐free heteroatom‐doped carbocatalysts with a high surface area are desirable for catalytic reactions. In this study, we found an efficient strategy to prepare nitrogen, phosphorus, and sulfur co‐doped hollow carbon shells (denote as NPS‐HCS) with a surface area of 1020 m2 g−1. Using a poly(cycl...
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Published in | Angewandte Chemie International Edition Vol. 55; no. 12; pp. 4016 - 4020 |
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Main Authors | , , , , , , |
Format | Journal Article |
Language | English |
Published |
WEINHEIM
Blackwell Publishing Ltd
14.03.2016
Wiley Wiley Subscription Services, Inc |
Edition | International ed. in English |
Subjects | |
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Abstract | Metal‐free heteroatom‐doped carbocatalysts with a high surface area are desirable for catalytic reactions. In this study, we found an efficient strategy to prepare nitrogen, phosphorus, and sulfur co‐doped hollow carbon shells (denote as NPS‐HCS) with a surface area of 1020 m2 g−1. Using a poly(cyclotriphosphazene‐co‐4,4′‐sulfonyldiphenol) (PZS) shell as carbon source and N, P, S‐doping source, and the ZIF‐67 core as structural template as well as extra N‐doping source, NPS‐HCS were obtained with a high surface area and superhydrophilicity. All these features render the prepared NPS‐HCS a superior metal‐free carbocatalyst for the selective oxidation of aromatic alkanes in aqueous solution. This study provides a reliable and facile route to prepare doped carbocatalysts with enhanced catalytic properties.
Highly efficient and selective: A synthetic route was developed to produce nitrogen, phosphorus, and sulfur co‐doped hollow carbon shells which were used as a metal‐free carbocatalyst. The carbocatalyst had a high surface area and showed superior activity in the selective oxidation of aromatic alkanes in aqueous solution. |
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AbstractList | Metal-free heteroatom-doped carbocatalysts with a high surface area are desirable for catalytic reactions. In this study, we found an efficient strategy to prepare nitrogen, phosphorus, and sulfur co-doped hollow carbon shells (denote as NPS-HCS) with a surface area of 1020 m(2) g(-1). Using a poly(cyclotriphosphazene-co-4,4'-sulfonyldiphenol) (PZS) shell as carbon source and N, P, S-doping source, and the ZIF-67 core as structural template as well as extra N-doping source, NPS-HCS were obtained with a high surface area and superhydrophilicity. All these features render the prepared NPS-HCS a superior metal-free carbocatalyst for the selective oxidation of aromatic alkanes in aqueous solution. This study provides a reliable and facile route to prepare doped carbocatalysts with enhanced catalytic properties. Metal‐free heteroatom‐doped carbocatalysts with a high surface area are desirable for catalytic reactions. In this study, we found an efficient strategy to prepare nitrogen, phosphorus, and sulfur co‐doped hollow carbon shells (denote as NPS‐HCS) with a surface area of 1020 m2 g−1. Using a poly(cyclotriphosphazene‐co‐4,4′‐sulfonyldiphenol) (PZS) shell as carbon source and N, P, S‐doping source, and the ZIF‐67 core as structural template as well as extra N‐doping source, NPS‐HCS were obtained with a high surface area and superhydrophilicity. All these features render the prepared NPS‐HCS a superior metal‐free carbocatalyst for the selective oxidation of aromatic alkanes in aqueous solution. This study provides a reliable and facile route to prepare doped carbocatalysts with enhanced catalytic properties. Highly efficient and selective: A synthetic route was developed to produce nitrogen, phosphorus, and sulfur co‐doped hollow carbon shells which were used as a metal‐free carbocatalyst. The carbocatalyst had a high surface area and showed superior activity in the selective oxidation of aromatic alkanes in aqueous solution. Metal-free heteroatom-doped carbocatalysts with a high surface area are desirable for catalytic reactions. In this study, we found an efficient strategy to prepare nitrogen, phosphorus, and sulfur co-doped hollow carbon shells (denote as NPS-HCS) with a surface area of 1020m(2)g(-1). Using a poly(cyclotriphosphazene-co-4,4-sulfonyldiphenol) (PZS) shell as carbon source and N, P, S-doping source, and the ZIF-67 core as structural template as well as extra N-doping source, NPS-HCS were obtained with a high surface area and superhydrophilicity. All these features render the prepared NPS-HCS a superior metal-free carbocatalyst for the selective oxidation of aromatic alkanes in aqueous solution. This study provides a reliable and facile route to prepare doped carbocatalysts with enhanced catalytic properties. Metal-free heteroatom-doped carbocatalysts with a high surface area are desirable for catalytic reactions. In this study, we found an efficient strategy to prepare nitrogen, phosphorus, and sulfur co-doped hollow carbon shells (denote as NPS-HCS) with a surface area of 1020m2g-1. Using a poly(cyclotriphosphazene-co-4,4'-sulfonyldiphenol) (PZS) shell as carbon source and N, P, S-doping source, and the ZIF-67 core as structural template as well as extra N-doping source, NPS-HCS were obtained with a high surface area and superhydrophilicity. All these features render the prepared NPS-HCS a superior metal-free carbocatalyst for the selective oxidation of aromatic alkanes in aqueous solution. This study provides a reliable and facile route to prepare doped carbocatalysts with enhanced catalytic properties. Metal‐free heteroatom‐doped carbocatalysts with a high surface area are desirable for catalytic reactions. In this study, we found an efficient strategy to prepare nitrogen, phosphorus, and sulfur co‐doped hollow carbon shells (denote as NPS‐HCS) with a surface area of 1020 m 2 g −1 . Using a poly(cyclotriphosphazene‐ co ‐4,4′‐sulfonyldiphenol) (PZS) shell as carbon source and N, P, S‐doping source, and the ZIF‐67 core as structural template as well as extra N‐doping source, NPS‐HCS were obtained with a high surface area and superhydrophilicity. All these features render the prepared NPS‐HCS a superior metal‐free carbocatalyst for the selective oxidation of aromatic alkanes in aqueous solution. This study provides a reliable and facile route to prepare doped carbocatalysts with enhanced catalytic properties. |
Author | Sun, Yongbin Wang, Xiaoshi Song, Weiguo Peng, Li Yang, Shuliang Huang, Peipei Cao, Changyan |
Author_xml | – sequence: 1 givenname: Shuliang surname: Yang fullname: Yang, Shuliang organization: Beijing National Laboratory for Molecular Sciences, Laboratory of Molecular Nanostructures and Nanotechnology, Institute of Chemistry, Chinese Academy of Sciences, 100190, Beijing, China – sequence: 2 givenname: Li surname: Peng fullname: Peng, Li organization: Institute of Chemical Sciences and Engineering, École Polytechnique Fédérale de Lausanne (EPFL), EPFL-ISIC-Valais, 1950, Sion, Switzerland – sequence: 3 givenname: Peipei surname: Huang fullname: Huang, Peipei organization: Beijing National Laboratory for Molecular Sciences, Laboratory of Molecular Nanostructures and Nanotechnology, Institute of Chemistry, Chinese Academy of Sciences, 100190, Beijing, China – sequence: 4 givenname: Xiaoshi surname: Wang fullname: Wang, Xiaoshi organization: Beijing National Laboratory for Molecular Sciences, Laboratory of Molecular Nanostructures and Nanotechnology, Institute of Chemistry, Chinese Academy of Sciences, 100190, Beijing, China – sequence: 5 givenname: Yongbin surname: Sun fullname: Sun, Yongbin organization: Beijing National Laboratory for Molecular Sciences, Laboratory of Molecular Nanostructures and Nanotechnology, Institute of Chemistry, Chinese Academy of Sciences, 100190, Beijing, China – sequence: 6 givenname: Changyan surname: Cao fullname: Cao, Changyan email: cycao@iccas.ac.cn organization: Beijing National Laboratory for Molecular Sciences, Laboratory of Molecular Nanostructures and Nanotechnology, Institute of Chemistry, Chinese Academy of Sciences, 100190, Beijing, China – sequence: 7 givenname: Weiguo surname: Song fullname: Song, Weiguo email: wsong@iccas.ac.cn organization: Beijing National Laboratory for Molecular Sciences, Laboratory of Molecular Nanostructures and Nanotechnology, Institute of Chemistry, Chinese Academy of Sciences, 100190, Beijing, China |
BackLink | https://www.ncbi.nlm.nih.gov/pubmed/26890684$$D View this record in MEDLINE/PubMed |
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ContentType | Journal Article |
Copyright | 2016 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim |
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Keywords | MESOPOROUS CARBON heterogeneous catalysis selective oxidation FREE ELECTROCATALYSTS ALKYLATION doping GRAPHENE BOND FORMATION NANOSHEETS POROUS CARBON HIGHLY EFFICIENT OXYGEN REDUCTION carbon metal-free catalysts ORGANIC FRAMEWORK |
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Snippet | Metal‐free heteroatom‐doped carbocatalysts with a high surface area are desirable for catalytic reactions. In this study, we found an efficient strategy to... Metal-free heteroatom-doped carbocatalysts with a high surface area are desirable for catalytic reactions. In this study, we found an efficient strategy to... |
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SubjectTerms | Alkanes Aqueous solutions Carbon Carbon sources Catalysts Chemistry Chemistry, Multidisciplinary Doping EGR-1 protein heterogeneous catalysis Hydrophilicity metal-free catalysts Nitrogen Oxidation Phosphorus Physical Sciences Science & Technology selective oxidation Shells Sulfur Surface area |
Title | Nitrogen, Phosphorus, and Sulfur Co-Doped Hollow Carbon Shell as Superior Metal-Free Catalyst for Selective Oxidation of Aromatic Alkanes |
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