Kinetic Analysis of the Solvent Extraction of Cadmium(II) Complexes Using a Cadmium-deposited Recessed Microelectrode and Confocal Fluorescence Microscope

• Published in: Analytical Sciences Vol. 33; no. 9; pp. 1081 - 1084
• Main Authors: NAKATANI, Kiyoharu, SAWADA, Naoki, SATO, Tatsumi
• Format: Journal Article
• Language: English
• Published: Singapore The Japan Society for Analytical Chemistry 2017; Springer Nature Singapore; Japan Science and Technology Agency
• Subjects: Analytical Chemistry; Cadmium; Chemistry; Confocal fluorescence microscope; Fluorescence; liquid–liquid interface; microdroplet; microelectrode; Microelectrodes; pH effects; Solvent extraction; Solvents; solvent extraction; microelectrode; microdroplet; Confocal fluorescence microscope; liquid–liquid interface

Using a Cd-deposited microelectrode, an electrochemically generated Cd(II) ion in a micro-water phase was reacted with 5-octyloxymethyl-8-quinolinol (HC8Q) in 1,6-dichlorohexane. The fluorescence intensity of Cd(C8Q)2 near the water/oil interface (IF) was analyzed under a confocal fluorescence micro...